Skip to main content
SpringerLink
Log in

Structural investigation of salts containing ions [Pd(NH3)4]2+ and [IrF6]2–

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Double complex salts (DCS) α-[Pd(NH3)4][IrF6]·H2O (P21/m, a = 6.3181(3) Å, b = 10.8718(5) Å, с = 7.4526(4) Å, β = 103.568(2)°), β-[Pd(NH3)4][IrF6]·H2O (P21/с, a = 8.5773(3) Å, b = 10.8791(4) Å, с = = 12.6741(3) Å, β = 122.497(2)°), [Pd(NH3)4]3[IrF6]2Cl2·H2O (P-1, a = 7.6080(2) Å, b = 7.6274(2) Å, с = 11.8070(3) Å, β = 122.497(2)°), and [Pd(NH3)4]2[IrF6]NO3 (Fm-3m, a = 11.21210(10) Å) have been synthesized and structurally characterized for the first time. The existence of polymorphs for the DCS has been revealed. The influence of the chemical composition of the initial reagents on the reaction course and, respectively, the products, has been demonstrated. A hypothesis on the influence of the second coordination sphere on the formation of one or the other polymorph of the DCS has been suggested. It has been shown that the series α-[Pd(NH3)4][МF6]·H2O (M = Pt, Pd) exhibits isostructurality.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. I. Potemkin, E. Y. Semitut, Y. V. Shubin, P. E. Plyusnin, P. V. Snytnikov, E. V. Makotchenko, D. Y. Osadchii, D. A. Svintsitskiy, S. A. Venyaminov, S. V. Korenev, and V. A. Sobyanin, Catal. Today, 235, 103 (2014).

    Article  CAS  Google Scholar 

  2. S. V. Komogortsev, R. S. Iskhakov, and A. A. Zimin, Appl. Phys. Lett., 103, 152404 (2013).

    Article  Google Scholar 

  3. N. V. Kuratieva and A. I. Gubanov, Acta Crystallogr., C63, i83 (2007).

    Google Scholar 

  4. S. A. Martynova, E. Y. Filatov, and S. V. Korenev, J. Solid State Chem., 212, 42 (2014).

    Article  CAS  Google Scholar 

  5. T. I. Asanova, I. P. Asanov, and M.-G. Kim, J. Nanopart. Res., 15, 1994 (2013).

    Article  Google Scholar 

  6. S. V. Zemskov, Extended Abstract of Doctoral (Chem.) Dissertation, NIIC SB USSR AS, Novosibirsk, Russia (1978).

    Google Scholar 

  7. S. V. Korenev, S. F. Solodovnikov, and S. V. Filatov, Zh. Neorg. Khim., 45, No. 1, 261 (2000).

    Google Scholar 

  8. T. Dahmen and P. Rittner, J. Alloys Compd., 216, 11 (1994).

    Article  CAS  Google Scholar 

  9. A. I. Smolentsev, A. I. Gubanov, A. V. Zadesenets, P. E. Plyusnin, I. A. Baidina, and S. V. Korenev, J. Struct. Chem., 51, No. 4, 709–713 (2010).

    Article  CAS  Google Scholar 

  10. Bruker. APEX2 (Version 2012.2-0), SAINT (Version 8.18c), and SADABS (Version 2008/1), Bruker Advanced X-Ray Solutions, Madison, Wisconsin, USA (2000-2012).

  11. G. M. Sheldrick, Acta Crystallogr., A64, 112 (2008).

    Article  Google Scholar 

  12. K. V. Yusenko, S. A. Gromilov, I. V. Korol’kov, I. A. Baidina, G. V. Romanenko, and S. V. Korenev., Zh. Neorg. Khim., 49, No. 4, 511 (2004).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. I. Gubanov, A. M. Danilenko, A. I. Smolentsev, N. V. Kuratieva, A. B. Venediktov & S. V. Korenev

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    A. I. Gubanov, A. I. Smolentsev, N. V. Kuratieva & S. V. Korenev

Authors
  1. A. I. Gubanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. M. Danilenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. I. Smolentsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. V. Kuratieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. B. Venediktov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. V. Korenev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. I. Gubanov.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 8, pp. 1701–1707, November–December, 2016.

Original Russian Text © 2016 A. I. Gubanov, A. M. Danilenko, A. I. Smolentsev, N. V. Kuratieva, A. B. Venediktov, S. V. Korenev.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gubanov, A.I., Danilenko, A.M., Smolentsev, A.I. et al. Structural investigation of salts containing ions [Pd(NH3)4]2+ and [IrF6]2– . J Struct Chem 57, 1606–1612 (2016). https://doi.org/10.1134/S0022476616080175

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476616080175

Keywords

Search

Navigation