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Structures Of Tetraammine Salts [Pt(NH3)4](N03)2, [Pd(NH3)4](N03)2, and [Pd(NH3)4]F2 H20

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Abstract

This contribution presents the results of a single crystal X-ray diffraction study of three ammine complexes of bivalent platinum and palladium: [Pt(NH3)4](N03)2, [Pd(NH3)4](N03)2 and [Pd(NH3)4]F2H2O. The first two compounds are isostructural; metal atoms are located on inversion centers, all other atoms are in general positions. A three-dimensional framework is built from planar-square complex cations and nitrate ions joined by N-H...O hydrogen bonds. In [Pd(NH3)4]F2H2O, palladium atoms, as in the previous cases, are located on inversion centers, while oxygen atoms of water molecules are on the two-fold symmetry axis. A network of strong N-H...F and O-H...F hydrogen bonds linking the cations, anions, and crystallization water molecules is present in the structure.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Division, Novosibirsk, Russia

    A. I. Smolentsev, A. I. Gubanov, A. V. Zadesenets, P. E. Plyusnin, I. A. Baidina & S. V. Korenev

  2. Novosibirsk State University, Novosibirsk, Russia

    A. I. Gubanov, A. V. Zadesenets, P. E. Plyusnin & S. V. Korenev

Authors
  1. A. I. Smolentsev
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  2. A. I. Gubanov
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  3. A. V. Zadesenets
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  4. P. E. Plyusnin
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  5. I. A. Baidina
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  6. S. V. Korenev
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Corresponding author

Correspondence to A. I. Smolentsev.

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Original Russian Text Copyright © 2010 by A. I. Smolentsev, A. I. Gubanov, A. V. Zadesenets, P. E. Plyusnin, I. A. Baidina, andS. V. Korenev

Translated from Zhurnal Strukturnoi Khimii, Vol. 51, No. 4, pp. 736–741, July–August, 2010.

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Smolentsev, A.I., Gubanov, A.I., Zadesenets, A.V. et al. Structures Of Tetraammine Salts [Pt(NH3)4](N03)2, [Pd(NH3)4](N03)2, and [Pd(NH3)4]F2 H20. J Struct Chem 51, 709–713 (2010). https://doi.org/10.1007/s10947-010-0104-1

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  • DOI: https://doi.org/10.1007/s10947-010-0104-1

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