Abstract
A newly synthesized Schiff base 3,3′-dihydroxy-4,4′-[4,4′-diphenylmethanebis(nitrilomethylidyne)]-bisphenol is characterized experimentally. Also, the geometry optimization for the tautomers, tautomerism and assignment of the IR bands and NMR chemical shifts of the Schiff base were performed using the DFT method. Good consistency between the theoretical and experimental results confirms the validity of the optimized geometry. Geometries of four possible tautomers are fully optimized. None of them has a planar structure, but each of the benzene rings is in a separate plane. In the most stable tautomer L1, the phenolic protons are engaged in the intramolecular-hydrogen bond with the azomethine nitrogen atoms. Tautomerization of L1 can occur in two different pathways which are computationally studied using DFT and the Atoms In Molecules (AIM) analysis. Both pathways have the same barrier energy.
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R. Sevvel, S. Rajagopal, C. Srinivasan, N. Ismail Alhaji, and A. Chellamani, J. Org. Chem., 65, 3334–3340 (2000).
B. Meunier, Chem. Rev., 92, 1411–1456 (1992).
D. Ostovic and T. C. Bruice, Acc. Chem. Res., 25, 314–320 (1992).
L. Canali and D. C. Sherrington, Chem. Soc. Rev., 28, 85–93 (1999).
B. Bahramian, V. Mirkhani, M. Moghadam, and A. H. Amin, Appl. Catal., A, 315, 52–57 (2006).
M. Palucki, G. J. McCormick, and E. N. Jacobsen, Tetrahedron Lett., 36, 5457–5460 (1995).
R. Irie, N. Hosoya, and T. Katsuki, Synlett, 255/256 (1994).
T. Linker, Angew. Chem., Int. Ed. Engl., 36, 2060–2062 (1997).
T. Hamada, H. Fukuda, and T. Katsuki, Tetrahedron, 52, 515–530 (1996).
D. J. Gravert and J. H. Griffin, Inorg. Chem., 35, 4837–4847 (1996).
S. E. Routier, J. L. Bernier, M. J. Warninig, P. Colson, and C. Bailly, J. Org. Chem., 61, 2326–2331 (1996).
H. Eshtiagh-Hosseini, M. R. Housaindokht, S. A. Beyramabadi, S. Beheshti, A. A. Esmaeili, M. Javan-Khoshkholgh, and A. Morsali, Spectrochim. Acta, Part A, 71, 1341–1347 (2008).
H. Eshtiagh-Hosseini, M. Mirzaei, H. Aghabozorg, S. A. Beyramabadi, H. Eshghi, A. Morsali, A. Shokrollahi, and R. Aghaei, Spectrochim. Acta, Part A, 78, 1392–1396 (2011).
H. Eshtiagh-Hosseini, M. R. Housaindokht, S. A. Beyramabadi, S. H. Mir Tabatabaei, A. A. Esmaeili, M. Javan-Khoshkholgh, Spectrochim. Acta, Part A, 78, 1046–1050 (2011).
S. A. Beyramabadi, A. Morsali, M. Javan-Khoshkholgh, and A. A. Esmaeili, Spectrochim. Acta, Part A, 83, 467–471 (2011).
S. A. Beyramabadi, A. Morsali, M. Javan-Khoshkholgh, and A. A. Esmaeili, J. Struct. Chem., 53, 460–467 (2012).
S. A. Beyramabadi, A. Morsali, and A. R. Shams, J. Struct. Chem., 56, No. 2, 243–249 (2015).
H. Eshtiagh-Hosseini, S. A. Beyramabadi, A. Morsali, M. Mirzaei, A. R. Salimi, and M. A. Naseri, J. Struct. Chem., 54, 1063–1069 (2013).
C. Lee, W. Yang, and R. G. Parr, Phys. Rev. B, 37, 785–789 (1988).
M. J. Frisch et al., Gaussian 03, Revision B.03, Gaussian Inc., Pittsburgh, PA (2003).
R. Ditchfield, Mol. Phys., 27, 789–807 (1974).
D. C. Young, Computational Chemistry: A Practical Guide for Applying Techniques to Real-World Problems, John Wiley & Sons Inc. (2001).
R. F. W. Bader, Atoms in Molecules: A Quantum Theory, Clarendon Press, Oxford, UK (1994).
F. Biegler-König, J. Schönbohm, and D. Bayles, J. Comput. Chem., 22, 545–559 (2001).
K. Srinivasan, P. Michaud, and J. K. Kochi, J. Am. Chem. Soc., 108, 2309–2320 (1986).
C.-B. Ma, F. Chen, C.-N. Chen, and Q.-T. Liu, Acta Crystallogr., C59, m516–m518 (2003).
D.-G. Huang, X.-F. Zhang, H.-P. Zhu, C.-N. Chen, and Q.-T. Liu, Acta Crystallogr., E57, m441–m443 (2001).
R. J. Butcher and W. Towns, Acta Crystallogr., E61, m2618–m2620 (2005).
D. Martínez, M. Motevalli, and M. Watkinson, Acta Crystallogr., C58, m258–m260 (2002).
Z.-H. Ni, H.-Z. Kou, L.-F. Zhang, Y.-B. Jiang, and A.-L. Cui, Acta Crystallogr., E61, m796–m798 (2005).
N. S. Gwaram, H. Khaledi, and H. M. Ali, Acta Crystallogr., E66, m813 (2010).
A. Pui, C. Policar, and J.-P. Mahy, Inorg. Chim. Acta, 360, 2139–2144 (2007).
R. Takjoo, R. Centore, M. Hakimi, S. A. Beyramabadi, and A. Morsali, Inorg. Chim. Acta, 371, 36–41 (2011).
P. Leyton, C. Paipa, A. Berrios, A. Zárate, M. V. Castillo, and S. A. Brandán, J. Mol. Struct., 1031, 110–118 (2013).
F. D. Proft and P. Geerlings, Chem. Rev., 101, 1451–1464 (2001).
J. Sanmartín, A. M. García-Deibe, M. Fondo, D. Navarro, and M. R. Bermejo, Polyhedron, 23, 963–967 (2004).
D. C. Ware, D. S. Mackie, P. J. Brothers, and W. A. Denny, Polyhedron, 14, 1641–1646 (1995).
X. Y. Li, Y. Wang, S. J. Zheng, and L. P. Meng, Struct. Chem., 23, 1233–1240 (2012).
R. Bader, Atoms in Molecules: A Quantum Theory, Clarendon, Oxford, UK (1990).
A. Filarowski and I. Majerz, J. Phys. Chem. A, 112, 3119–3126 (2008).
E. Espinosa, M. Souhassou, H. Lachekar, and C. Lecomte, Acta Crystallogr., Sect. B: Struct. Sci., 55, 563–572 (1999).
S. J. Grabowski, J. Phys. Chem. A, 104, 5551–5557 (2000).
S. Jenkins and I. Morrison, Chem. Phys. Lett., 317, 97–102 (2000).
Y. H. Mariam and R. N. Musin, J. Phys. Chem. A, 112, 134–145 (2008).
M. T. Carroll and R. F. Bader, Mol. Phys., 65, 695–722 (1988).
J. G. Ángyán, M. Loos, and I. Mayer, J. Phys. Chem., 98, 5244–5248 (1994).
P. Kolandaivel and V. Nirmala, J. Mol. Struct., 694, 33–38 (2004).
C. Gatti, V. R. Saunders, and C. Roetti, J. Chem. Phys., 101, 10686–10696 (1994).
S. J. Grabowski, J. Mol. Struct.: THEOCHEM, 811, 61–67 (2007).
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Original Russian Text © 2015 H. Eshtiagh-Hosseini, S. A. Beyramabadi, M. Mirzaei, A. Morsali, M. A. Naseri, H. Chegini, M. Elahi.
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 5, pp. 902–913, September–October, 2015.
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Eshtiagh-Hosseini, H., Beyramabadi, S.A., Mirzaei, M. et al. Intramolecular-proton transfer, experimental and theoretical characterization of 3,3′-dihydroxy-4,4′-[4,4′-diphenylmethanebis (nitrilomethylidyne)]-bis-phenol. J Struct Chem 56, 845–856 (2015). https://doi.org/10.1134/S0022476615050054
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DOI: https://doi.org/10.1134/S0022476615050054