Abstract
The synthesis and characterization of cobalt hydroxides generated from cobalt chloride precursors at various concentrations (0.1 to 0.5 M) by using cathodic electrochemical deposition technique for prospective energy storage application. The Co(OH)2 thin films were discovered to have a crystalline structure with a crystallite size of ~ 40 nanometers, particle size of 180 nm, and a leaf-like morphology via XRD (X-ray Diffraction) and SEM (Scanning Electron Microscopy) respectively. Further properties were investigated by EDS (Energy-Dispersive X-ray Spectroscopy), FTIR (Fourier Transform Infrared Spectroscopy), and UV Vis Spectra (Ultraviolet-Visible Spectroscopy) analysis. The presence of cobalt hydroxide was confirmed by EDS, verifying the purity of the substance. Electrochemical characteristics, such as CV (Cyclic Voltammetry), GCD (Galvanostatic Charge-Discharge), and EIS (Electrochemical Impedance Spectroscopy) analysis, indicated capacitive behavior, confirming their feasibility for energy storage. The specific capacitances from 450 to 1250 F/g were measured from the GCD curve. The MATLAB study gave quantitative data on critical electrode characteristics which improved the understanding of the performance and a framework for further investigation in the development of sustainable energy solutions.
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R. Waseem, A. Faizan, R. Nadeem, L. Yiwei, K. Ki-Hyun, Y. Jianhua, K. Sandeep, M. Andleeb, E. Eilhann, Recent advancements in supercapacitor technology. Nano Energy Volume. 52, 441–473 (October 2018)
S. Zaharaddeen, C. ubramani, S. Dash, A brief review on Electrode materials for Supercapacitor. Int. J. Electrochem. Sci. 11, 10628–10643 (2016)
Y. Jing, L. Hongwei, N. Wayde, L. Ray, Synthesis and characterization of Cobalt Hydroxide, Cobalt Oxyhydroxide, and Cobalt Oxide Nanodisc. J. Phys. Chem. C 114(1), 111–119 (2010)
R. Jayashree, K. Vishnu, Electrochemical synthesis of α-cobalt hydroxide. J. Mater. Chem. 9, 961–963 (1999)
M.S.M. Gadwal, S.D. Sartale, V.L. Mathe, H.M. Pathan, Substrate assisted electrochemical deposition of patterned cobalt thin films. Electrochem. Commun. 11(8), 1711–1713 (2009)
W.-J. Zhou, M.-W. Xu, D.-D. Zhao, C.-L. Xu, H.L. Li, Electrodeposition and characterization of ordered mesoporous cobalt hydroxide films on different substrates for supercapacitors. Microporous Mesoporous Mater. 117(1–2), 55–60 (2009)
T. Deng, W. Zhang, O. Arcelus et al., Atomic-level energy storage mechanism of cobalt hydroxide electrode for pseudocapacitors. Nat. Commun., 8, 1, Article ID 15194, 2017
E. Hosono, S. Fujihara, I. Honma, Fabrication of morphology and crystal structure controlled nanorod and nanosheet cobalt hydroxide based on the difference of oxygen-solubility between water and methanol, and conversion into Co3O4. J. Mater. Chem. 15, 1938–1945 (2005)
R.S. Jayashree, P.V. Kamath, Electrochemical synthesis of α-cobalt hydroxide. J. Mater. Chem. 9(4), 961–963 (1999)
P. Jeevanan, Y. Koltypin, A. Gedanken, Y. Masatai, Synthesis of α-cobalt(II) hydroxide using ultrasound radiation. J. Mater. Chem. 9(2), 511–514 (1999)
P.V. Kamath, M. Dixit, L. Indira, Stabilized α - ni(OH)2 as Electrode Material for Alkaline secondary cells. J. Electrochem. Soc. 141(11), 2956–2959 (1994)
Z. Sun, Y. Zhai, L. Zheng, W. Guo, W. Dong, Z. Fang, J. Tang, Cobalt-phthalocyanine-modified two-dimensional cobalt hydroxide complexes for highly selective electrocatalytic reduction of CO 2 to CO. J. Mater. Chem. A 11(3), 1123–1128 (2023)
W. Hu, H. Fu, L. Chen, X. Wu, B. Geng, Y. Huang, Q. Zheng, Synthesis of amorphous nickel-cobalt hydroxides with high areal capacitance by one-step electrodeposition using polymeric additive. Chem. Eng. J. 451, 138613 (2023)
J. Lee, J. Jang, T. Yu, A facile aqueous-phase synthesis of co-based nanostructures composed of cobalt hydroxide and cobalt oxide for enhanced photocatalytic activity of dye-sensitized H2 production. J. Alloys Compd. 942, 169078 (2023)
M.B. Poudel, A.A. Kim, P.C. Lohani, D.J. Yoo, H.J. Kim, Assembling zinc cobalt hydroxide/ternary sulfides heterostructure and iron oxide nanorods on three-dimensional hollow porous carbon nanofiber as high energy density hybrid supercapacitor. J. Energy Storage. 60, 106713 (2023)
X. Cheng, Y. Tong, Interface coupling of cobalt hydroxide/molybdenum disulfide heterostructured nanosheet arrays for highly efficient hydrazine-assisted hydrogen generation. ACS Sustain. Chem. Eng. 11(8), 3219–3227 (2023)
R. Mehdizadeh, L.A. Saghatforoush, S. Sanati, Synthesis and characterization of ZnO and CuO and Co(OH)2 nanostructures by the solvothermal method without any additive. J. Chin. Chem. Soc. 60(3), 339–344 (2013)
J.M. Miller, B. Dunn, T.D. Tran, R.W. Pekala, Electrochemical capacitors for energy management. J. Electrochem. Soc. 144(5889), 89–107 (1997)
M. Min, K. Machida, J.H. Jang, K. Naoi, Hydrous RuO2/carbon black nanocomposites with 3D porous structure by novel incipient wetness method for supercapacitors. J. Electrochem. Soc. 153(2), A334–338 (2006)
C. Niu, E.K. Sichel, R. Hoch, D. Moy, H. Tennent, High-power electrochemical capacitors based on carbon nanotube electrodes. Appl. Phys. Lett. 70, 1480–1482 (1997)
H.R. Oswald, R. Asper, Preparation and Crystal Growth of materials with layered structures edited by Reidel D (Publishing Company. Holand). 1, 71–103 (1977)
A.G. Pandolfo, A.F. Hollenkamp, Carbon properties and their role in supercapacitors. J. Power Sources. 157(1), 11–27 (2006)
T.N. Ramesh, P.V. Kamath, C. Shivakumara, Correlation of structural disorder with the reversible discharge capacity of nickel hydroxide electrode. J. Electrochem. Soc. 152(4), A806–810 (2005)
Y.Z. Shao, J. Sun, L. Gao, Hydrothermal synthesis of hierarchical nanocolumns of cobalt hydroxide and cobalt oxide. J. Phys. Chem. C 113(16), 6566–6572 (2009)
P. Simon, Y. Gogotsi, Materials for electrochemical capacitors. Nat. Mater. 7(5), 845–854 (2008)
H. Wang, Y. Liang, T. Mirfakhrai, Z. Chen, H.S. Casalongue, H. Dai, Advanced Asymmetrical Supercapacitors based on Graphene Hybrid materials. Nano Res. 4(8), 729–736 (2011)
X.-F. Wang, Y. Zheng, D.-B. Ruan, A hybrid metal oxide supercapacitor in aqueous KOH Electrolyte. Chin. J. Chem. 24(9), 1126–1132 (2006)
Y. Wang, W. Yang, C. Chen, R. Ding, C. Ron, Fabrication and electrochemical characterization of cobalt-based layered double hydroxide nanosheet thin-film electrodes. J. Power Sources. 184(2), 682–690 (2008)
M.S. Whittingham, Lithium batteries and cathode materials. Chem. Rev. 104(10), 4271–4301 (2004)
N.-L. Wu, Nanocrystalline oxide supercapacitors. Mater. Chem. Phys. 75(1), 6–11 (2006)
X. Xia, J. Tu, Y. Mai, R. Chen, X. Wang, C. Gu, X. Zhao, Graphene sheet/porous NiO hybrid film for supercapacitor applications. Chem. Eur. J. 17(39), 10898–10905 (2011)
W. Xiaobo, Z. Bai, Z. Dong, Z. Fuyan, Friction behavior of Mg–Al–CO3 layered double hydroxide prepared by magnesite. Lubr. Eng. 57, 36–39 (2001)
M.S. Yarger, E.M. Steinmiller, K.S. Choi, Electrochemical synthesis of cobalt hydroxide films with tunable interlayer spacings. Chem. Commun. 14, 159–161 (2007)
T. Zhao, H. Jiang, J. Ma, Surfactant-assisted electrochemical deposition of α-cobalt hydroxide for supercapacitors. J. Power Sources. 196(2), 860–864 (2011)
Y.A. Shardt, (2023). Introduction to MATLAB®. Using MATLAB to Solve Statistical Problems: A Practical Guide to the Book Statistics for Chemical and Process Engineers (1–7). Cham: Springer Nature Switzerland
Acknowledgements
I would like to thank Dr. Aqueel Ahmad Shah (Principal, Maulana Mukhtar Ahmad Nadvi Technical Campus) for providing lab facilities to perform the experiments. I am also thankful to Dr. Dilawar Husain (Associate Professor, MMANTC) for his motivation and valuable guidance in writing, publishing, and presenting the research work.
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Naeem, S. Electrodeposited Cobalt Hydroxide Thin Films: A Comprehensive Investigation from Synthesis to Advanced Electrochemical Behavior for High-Performance Energy Storage. Trans. Electr. Electron. Mater. (2024). https://doi.org/10.1007/s42341-024-00542-3
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DOI: https://doi.org/10.1007/s42341-024-00542-3