Abstract
A medium-carbon low-alloy steel with designed chemical composition was investigated. The steel exhibits an excellent product of strength and elongation value of 31,832 MPa% through quenching and partitioning treatment, with a tensile strength of 1413 MPa and elongation of 22%. X-ray diffraction analysis and transmission electron microscopy characterizations confirm that the retained austenite in the specimens undergoes stress-induced phase transformation to the martensite and hexagonal phases, namely the transformation-induced plasticity (TRIP) effect is triggered. This TRIP effect, triggered by the stress-induced phase transition of retained austenite, is responsible for the excellent mechanical properties obtained in the steel. For further investigating the stress-induced phase transition mechanism, thermodynamic methods are applied. Gibbs free energy of face-centered cubic-Fe, ε-Fe, ω-Fe and body-centered cubic-Fe associated with the stress-induced phase transition was calculated using molecular dynamics simulations, and a calculation method of strain energy in thermodynamic units for the stress-induced martensitic transformation is presented. The final results reveal the process and thermodynamic mechanism of stress-induced martensitic transformation in medium-carbon steels, in which the hexagonal phase can participate in the process as an intermediate product.
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G. Jha, S. Das, S. Sinha, A. Lodh, A. Haldar, Mater. Sci. Eng. A 561 (2013) 394–402.
R. Xu, J. Liu, Y. Zhang, R. Guo, W. Liu, Mater. Sci. Eng. A 438–440 (2006) 459–463.
J. Gao, S. Jiang, H. Zhang, Y. Huang, D. Guan, Y. Xu, S. Guan, L.A. Bendersky, A.V. Davydov, Y. Wu, H. Zhu, Y. Wang, Z. Lu, W.M. Rainforth, Nature 590 (2021) 262–267.
R. Ding, Y. Yao, B. Sun, G. Liu, J. He, T. Li, X. Wan, Z. Dai, D. Ponge, D. Raabe, C. Zhang, A. Godfrey, G. Miyamoto, T. Furuhara, Z. Yang, S. van der Zwaag, H. Chen, Sci. Adv. 6 (2020) eaay1430.
L. Liu, Q. Yu, Z. Wang, J. Ell, M.X. Huang, R.O. Ritchie, Science 368 (2020) 1347–1352.
J. Zhang, Y. Cui, X. Zuo, J. Wan, Y. Rong, N. Chen, J. Lu, Sci. Bull. 66 (2021) 1058–1062.
J. Xu, F. Yan, X. Wan, Y. Li, Q. Zhu, Processes 11 (2023) 641.
Y. Wang, K. Zhang, Z. Guo, N. Chen, Y. Rong, Mater. Sci. Eng. A 552 (2012) 288–294.
K. Zhang, M. Zhang, Z. Guo, N. Chen, Y. Rong, Mater. Sci. Eng. A 528 (2011) 8486–8491.
X.C. Xiong, B. Chen, M.X. Huang, J.F. Wang, L. Wang, Scripta Mater. 68 (2013) 321–324.
G. Liu, T. Li, Z. Yang, C. Zhang, J. Li, H. Chen, Acta Mater. 201 (2020) 266–277.
Q. Li, X. Huang, W. Huang, Mater. Sci. Eng. A 662 (2016) 129–135.
R. Kuziak, R. Kawalla, S. Waengler, Arch. Civ. Mech. Eng. 8 (2008) 103–117.
P. Jacques, Q. Furnémont, A. Mertens, F. Delannay, Philos. Mag. A 81 (2001) 1789–1812.
K.I. Sugimoto, Mater. Sci. Technol. 25 (2009) 1108–1117.
C. Song, H. Yu, L. Li, T. Zhou, J. Lu, X. Liu, Mater. Sci. Eng. A 670 (2016) 326–334.
X. Tan, H. He, W. Lu, L. Yang, B. Tang, J. Yan, Y. Xu, D. Wu, Mater. Sci. Eng. A 771 (2020) 138629.
X.X. Dong, Y.F. Shen, Mater. Sci. Eng. A 852 (2022) 143737.
T. Liu, D. Zhang, Q. Liu, Y. Zheng, Y. Su, X. Zhao, J. Yin, M. Song, D. Ping, Sci. Rep. 5 (2015) 15331.
D. Ping, T. Liu, M. Ohnuma, T. Ohmura, T. Abe, H. Onodera, ISIJ Int. 57 (2017) 1233–1240.
D.H. Ping, M. Ohnuma, J. Mater. Sci. 53 (2018) 5339–5355.
K. Zhai, K. Zhao, Y. Zhang, J. Yue, P. Zhu, S. Li, C. Wang, C. Cui, D. Ping, Cryst. Growth Des. 23 (2023) 539–547.
S.K. Sikka, Y.K. Vohra, R. Chidambaram, Prog. Mater. Sci. 27 (1982) 245–310.
Y. Chen, D. Ping, Y. Wang, X. Zhao, J. Alloy. Compd. 767 (2018) 68–72.
W. Zhang, Z. Liu, Z. Zhang, G. Wang, Mater. Lett. 91 (2013) 158–160.
J. Li, H. Yang, P. Yang, Mater. Lett. 134 (2014) 180–183.
Q. Ye, G. Han, J. Xu, Z. Cao, L. Qiao, Y. Yan, Mater. Sci. Eng. A 831 (2022) 142244.
T. Bhattacharyya, S.B. Singh, S. Das, A. Haldar, D. Bhattacharjee, Mater. Sci. Eng. A 528 (2011) 2394–2400.
C.G. Lee, S.J. Kim, T.H. Lee, C.S. Oh, ISIJ Int. 44 (2004) 737–743.
A. Dumay, J.P. Chateau, S. Allain, S. Migot, O. Bouaziz, Mater. Sci. Eng. A 483-484 (2008) 184–187.
Z. Dai, H. Chen, R. Ding, Q. Lu, C. Zhang, Z. Yang, S. van der Zwaag, Mater. Sci. Eng. 143 (2021) 100590.
J. Speer, D.K. Matlock, B.C. De Cooman, J.G. Schroth, Acta Mater. 51 (2003) 2611–2622.
J.G. Speer, D.V. Edmonds, F.C. Rizzo, D.K. Matlock, Curr. Opin. Solid State Mater. Sci. 8 (2004) 219–237.
M.M. Ahmmad, Y. Sumi, J. Mar. Sci. Technol. 15 (2010) 1–15.
A.K. De, D.C. Murdock, M.C. Mataya, J.G. Speer, D.K. Matlock, Scripta Mater. 50 (2004) 1445–1449.
S. Kruijver, L. Zhao, J. Sietsma, E. Offerman, N. van Dijk, L. Margulies, E. Lauridsen, S. Grigull, H. Poulsen, S. van der Zwaag, Steel Res. 73 (2002) 236–241.
M.J. Santofimia, L. Zhao, R. Petrov, C. Kwakernaak, W.G. Sloof, J. Sietsma, Acta Mater. 59 (2011) 6059–6068.
R. Freitas, M. Asta, M. de Koning, Comput. Mater. Sci. 112 (2016) 333–341.
B.J. Lee, Acta Mater. 54 (2006) 701–711.
D.H. Ping, Acta Metall. Sin. (Engl. Lett.) 28 (2015) 663–670.
J. Kobayashi, D. Ina, A. Futamura, K.I. Sugimoto, ISIJ Int. 54 (2014) 955–962.
W.Y. Yang, L.F. Li, Y.Y. Yin, Z.Q. Sun, X.T. Wang, Mater. Sci. Forum 654-656 (2010) 250–253.
J. Sun, H. Yu, Mater. Sci. Eng. A 586 (2013) 100–107.
Z.G. Jia, J. Hu, N. Xu, C. Liu, L.Y. Wang, C.C. Wang, W.H. Sun, W. Xu, Metall. Mater. Trans. A 52 (2021) 3140–3151.
K. Kim, S.J. Lee, Mater. Sci. Eng. A 698 (2017) 183–190.
Y. Li, F. Zhang, C. Chen, B. Lv, Z. Yang, C. Zheng, Mater. Sci. Eng. A 651 (2016) 945–950.
X. Wan, G. Liu, Z. Yang, H. Chen, Scripta Mater. 198 (2021) 113819.
C. Huang, M. Zou, L. Qi, O.A. Ojo, Z. Wang, J. Mater. Res. Technol. 12 (2021) 1080–1090.
S. Das, A. Haldar, Metall. Mater. Trans. A 45 (2014) 1844–1854.
S.M. Hasan, A. Ghosh, D. Chakrabarti, S.B. Singh, Metall. Mater. Trans. A 51 (2020) 2053–2063.
T. Zhang, J. Hu, C. Wang, Y. Wang, W. Zhang, H. Di, W. Xu, Mater. Charact. 178 (2021) 111247.
J. Du, W.Z. Zhang, F.Z. Dai, Z.Z. Shi, J. Appl. Crystallogr. 49 (2016) 40–46.
K.I. Sugimoto, M. Misu, M. Kobayashi, H. Shirasawa, ISIJ Int. 33 (1993) 775–782.
T. Zhang, L. Wang, Y. Wang, J. Hu, H. Di, W. Xu, Mater. Sci. Eng. A 852 (2022) 143677.
B.V. Narasimha Rao, Metall. Trans. A 10 (1979) 645–648.
D. Ping, Acta Metall. Sin. (Engl. Lett.) 27 (2014) 1–11.
G. Gao, B. Gao, X. Gui, J. Hu, J. He, Z. Tan, B. Bai, Mater. Sci. Eng. A 753 (2019) 1–10.
C.H. Young, H.K.D.H. Bhadeshia, Mater. Sci. Technol. 10 (1994) 209–214.
P. Jacques, Acta Mater. 49 (2001) 139–152.
S.M. Hasan, A. Mandal, S.B. Singh, D. Chakrabarti, Mater. Sci. Eng. A 751 (2019) 142–153.
J. Zhang, H. Ding, R.D.K. Misra, C. Wang, Mater. Sci. Eng. A 611 (2014) 252–256.
Z. Tang, J. Huang, X. Lu, H. Ding, D. Zhang, D. Misra, Metals 8 (2018) 872.
H.L. Yi, P. Chen, H.K.D.H. Bhadeshia, Metall. Mater. Trans. A 45 (2014) 3512–3518.
Z. Li, C.C. Tasan, K.G. Pradeep, D. Raabe, Acta Mater. 131 (2017) 323–335.
T. Ogawa, M. Koyama, C.C. Tasan, K. Tsuzaki, H. Noguchi, J. Mater. Sci. 52 (2017) 7868–7882.
H.X. Yin, A.M. Zhao, Z.Z. Zhao, X. Li, S.J. Li, H.J. Hu, W.G. Xia, Int. J. Miner. Metall. Mater. 22 (2015) 262–271.
S.C. van Bohemen, Mater. Sci. Technol. 28 (2012) 487–495.
S.B. Zhou, F. Hu, W. Zhou, L. Cheng, C.Y. Hu, K.M. Wu, J. Mater. Res. Technol. 14 (2021) 1021–1034.
Y. Zhang, Y.T. Cheng, D.S. Grummon, J. Appl. Phys. 98 (2005) 033505.
H.Y. Wang, C. Li, C. Zhao, T. Zeng, Z.M. Wang, Y. Huang, Acta Metall. Sin. 59 (2023) 679–692.
S.Q. Wu, D.H. Ping, Y. Yamabe-Mitarai, W.L. Xiao, Y. Yang, Q.M. Hu, G.P. Li, R. Yang, Acta Mater. 62 (2014) 122–128.
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This work was supported by the National Key Research and Development Program of China (Grant No. 2018YFB0703904).
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Lu, Mw., Chen, X., Liu, Wx. et al. Mechanisms of strength–plasticity enhancement and stress-induced phase transition in a medium-carbon low-alloy steel. J. Iron Steel Res. Int. (2024). https://doi.org/10.1007/s42243-023-01153-7
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DOI: https://doi.org/10.1007/s42243-023-01153-7