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Effect of Ni, Mn, Sc, and Zr Addition on the Tensile Properties of 354-Type Alloys at Ambient Temperature

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Abstract

The present study was carried out to investigate the effects of Ni (high and low), Mn, Zr, and Sc additions, individually or in combination with other additives, on the microstructure and tensile properties of 354 casting alloy (Al–9 wt% Si–1.8 wt% Cu–0.5 wt% Mg) at ambient temperature following aging in the temperature range 155–300 °C for different aging times. Solution heat treatment of the studied alloys improves the tensile properties and alloy quality of all alloys. The presence of Ni and Zr (with no Cu), and Sc and Zr provides improvement as these alloys show the best YS values. Multiple aging peaks are observed in the age-hardening curves of all studied alloys, related to the precipitation sequence which occurs in each alloy. The best combination of properties is achieved after aging at 190 °C/2 h for all alloys studied, with the exception of the alloy containing 2 % Ni + 0.25 % Zr that showed the best combination at 190 °C/4 h. These conditions may therefore be considered as the appropriate T6 heat treatment parameters for these alloys. Under the experimental conditions of the present study, aging at 190 °C (for 2 or 4 h) introduces a technologically useful strategy for this particular alloy system as it provides a significant economic benefit in the form of a noticeable reduction in the aging time required to reach peak strength.

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References

  1. T. Tanaka, T. Akasawa, Machinability of hypereutectic silicon–aluminum alloys. J. Mater. Eng. Perform. 8(4), 463–468 (1999)

    Article  Google Scholar 

  2. M.E. Fine, Precipitation hardening of aluminum alloys. Metall. Trans. A 6(4), 625–630 (1975)

    Article  Google Scholar 

  3. Y.W. Kim, W.M. Griffith (eds.), Dispersion Strengthened Aluminum Alloys (TMS, Warrendale, 1988), pp. 217–242

    Google Scholar 

  4. J.D. Robson, P.B. Pragnell, Modeling Al3Zr dispersoid precipitation in multicomponent aluminum alloys. Mater. Sci. Eng. A 352, 240–250 (2003)

    Article  Google Scholar 

  5. K.E. Knipling, Development of a Nanoscale Precipitation-Strengthened Creep-Resistant Aluminum Alloy Containing Trialuminide Precipitates, PhD Thesis (Northwestern University, Evanston, 2006)

  6. Z. Asghar, G. Requena, E. Boller, Three-dimensional rigid multiphase networks providing high-temperature strength to cast AlSi10Cu5Ni1–2 piston alloy. Acta Mater. 59(16), 6420–6432 (2011)

    Article  Google Scholar 

  7. H. Ammar, Influence of Metallurgical Parameters on the Mechanical Properties and Quality Indices of Al–Si–Cu–Mg and Al–Si–Mg Casting Alloys, PhD. Thesis (Université du Québec à Chicoutimi, Chicoutimi, 2010)

  8. A.M. Gokhale, M.D. Dighe, M. Horstemeyer, Effect of temperature on silicon particle damage in A356 alloy. Metall. Mater. Trans. A 29A, 905–907 (1998)

    Article  Google Scholar 

  9. J. Hernandez-Sandoval, G.H. Garza-Elizondo, A.M. Samuel, S. Valtierra, F.H. Samuel, The ambient and high temperature deformation behavior of Al–Si–Cu–Mg alloy with minor, Ti, Zr, Ni additions. Mater. Des. 58, 89–101 (2014)

    Article  Google Scholar 

  10. J. Hernandez, Improving the Performance of 354 Type Alloy, PhD. Thesis (Université du Québec à Chicoutimi, Chicoutimi, 2010)

  11. R. Li, Solution heat treatment of 354 and 355 cast alloys. AFS Trans. 104, 777–783 (1996)

    Google Scholar 

  12. C.H. Cáceres, Transient environmental effects of light alloy substitutions in transport vehicles. Mater. Des. 30(8), 2813–2822 (2009)

    Article  Google Scholar 

  13. J.E. Hatch (ed.), Aluminum: Properties and Physical Metallurgy (American Society for Metals, Metals Park, 1993), pp. 135–160

    Google Scholar 

  14. D. Emadi, L.V. Whiting, M. Sahoo, J.H. Sokolowski, P. Burke, M. Hart, in Light Metals 2003, ed. by P.N. Crepeau. Optimal heat treatment of A356.2 alloy, (The Minerals, Metals, and Materials Society, Warrendale, 2003), pp. 983–989

    Google Scholar 

  15. D. Apelian, S. Shivkumar, G. Sigworth, Fundamental aspects of heat treatment of cast Al–Si–Mg alloys. AFS Trans. 97, 727–742 (1989)

    Google Scholar 

  16. F.H. Samuel, A.M. Samuel, H.W. Doty, Factors controlling the type and morphology of Cu-containing phases in 319 Al alloy. AFS Trans. 104, 893–901 (1996)

    Google Scholar 

  17. H.R. Ammar, A.M. Samuel, F.H. Samuel, E. Simielli, G.K. Sigworth, J.C. Lin, Influence of aging parameters on the tensile properties and quality index of Al–9 Pct Si–1.8 Pct Cu–0.5 Pct Mg 354-type casting alloys. Metall. Mater. Trans. A 43A, 61–73 (2012)

    Article  Google Scholar 

  18. ASM Handbook Vol. 2, Properties and Selection: Nonferrous Alloys and Special-Purpose Materials (ASM International, Materials Information Society, USA, 1990)

  19. L. Heusler, W. Schneider, Influence of alloying elements on the thermal analysis results of Al–Si cast alloys. J. Light Met. 2, 17–26 (2002)

    Article  Google Scholar 

  20. S. Seifeddine, The influence of iron and Mn content on the microstructure and tensile properties of cast Al–Si–Mg alloys, in Vilmer Project-5.2 Casting (The School of Engineering Component Technology, Sweden, 2007)

  21. H.R. Ammar, C. Moreau, A.M. Samuel, F.H. Samuel, H.W. Doty, Influences of alloying elements, solution treatment time and quenching media on quality indices of 413-type Al–Si casting alloys. Mater. Sci. Eng. A 489(1–2), 426–438 (2008)

    Article  Google Scholar 

  22. H.R. Ammar, C. Moreau, A.M. Samuel, F.H. Samuel, H.W. Doty, Effects of aging parameters on the quality of 413-type commercial alloys. Mater. Des. 30, 1014–1025 (2009)

    Article  Google Scholar 

  23. A.T. Joenoes, The Role of Magnesium on Eutectic Silicon Microstructure, Master’s Thesis (McGill University, Montreal, 1991)

  24. Q.G. Wang, Microstructural effects on the tensile and fracture behavior of aluminum casting alloys A356/357. Metall. Mater. Trans. A 34A, 2887–2891 (2003)

    Article  Google Scholar 

  25. J.H. Sokolowski, X.C. Sun, A. Esseltine, The removal of copper-phase segregation and the subsequent improvement in mechanical properties of cast 319 aluminum alloys by a two-stage solution heat treatment. J. Mater. Process. Technol. 53, 385–392 (1995)

    Article  Google Scholar 

  26. D.L. Zhang, L.H. Zheng, D.H. StJohn, Effect of a short solution treatment time on microstructure and mechanical properties of modified Al–7 wt% Si–0.3 wt% Mg alloy. J. Light Met. 2, 27–36 (2002)

    Article  Google Scholar 

  27. C.H. Cáceres, I.L. Svensson, J.A. Taylor, Strength-ductility behaviour of Al–Si–Cu–Mg casting alloys in T6 temper. Int. J. Cast Met. Res. 15, 531–543 (2003)

    Article  Google Scholar 

  28. C.H. Cáceres, B. Johannesson, J.A. Taylor, A. Canales-Nuñez, M. Cardoso, J. Talamantes, The Effect of Si content on the size and morphology of Fe-rich and Cu-rich intermetallics in Al–Si–Cu–Mg Alloys, in Shape Casting: 2nd International Symposium, ed. by P.N. Crepaeu, M. Tiryakioglu, J. Campbell. (The Minerals, Metals, and Materials Society, Warrendale, 2007), pp. 1–7

  29. J.G. Kaufman, E.L. Rooy, Aluminum Alloy Castings: Properties, Processing, and Applications (ASM International, Materials Park, 2004)

    Google Scholar 

  30. A.M.A. Mohamed, Effect of Additives on the Microstructure and Mechanical Properties of Aluminum–Silicon Alloys, PhD. Thesis (Université du Québec à Chicoutimi, Chicoutimi, 2008)

  31. J. Barresi, M.J. Kerr, H. Wang, M.J. Couper, Effect of magnesium, iron, and cooling rate on mechanical properties of Al–7Si–Mg foundry alloys. AFS Trans. 108, 63–70 (2000)

    Google Scholar 

  32. T.O. Mbuya, B.O. Odera, Influence of iron on castability and properties of aluminum silicon alloys: literature review. Int. J. Cast Met. Res. 16, 451–465 (2003)

    Article  Google Scholar 

  33. G.E. Dieter, Mechanical Metallurgy, SI Metric Edition (McGraw-Hill, London, 1988)

    Google Scholar 

  34. N.A. Belov, A.N. Alabin, D.G. Eskin, V.V. Istomin-Kastrovskii, Optimization of hardening of Al–Zr–Sc cast alloys. J. Mater. Sci. 41, 5890–5899 (2006)

    Article  Google Scholar 

  35. D.Y. Lee, J.G. Park, D.-H. Cho, High-temperature properties of dispersion-strengthened 7075-T6 aluminium alloy. J. Mater. Sci. Lett. 16, 158–160 (1997)

    Article  Google Scholar 

  36. J.A. Catherall, R.F. Smart, The effect of nickel in aluminum–silicon eutectic alloys. Metallurgia 79, 247–250 (1969)

    Google Scholar 

  37. A.M. Nabawy, Influence of Zirconium and Scandium on the Microstructure, Tensile Properties, and Hot-Tearing Susceptibility of Al–2 wt% Cu-Based Alloys, PhD. Thesis (Université du Québec à Chicoutimi, Chicoutimi, 2010)

  38. S. Iwamura, Y. Miura, Loss in coherency and coarsening behavior of Al3Sc precipitates. Acta Mater. 52, 591–600 (2004)

    Article  Google Scholar 

  39. L.S. Toropova, D.G. Eskin, M.L. Kharaktrova, T.V. Dobakina, Advanced Aluminum Alloys Containing Scandium: Structure and Properties (Gordon and Breach, Canada, 1998)

    Google Scholar 

  40. C.B. Fuller, J.L. Murray, D.N. Seidman, Temporal evolution of the nanostructure of Al(Sc, Zr) alloys: part 1—chemical compositions of Al3(Sc1–xZrx) precipitates. Acta Mater. 53, 5401–5413 (2005)

    Article  Google Scholar 

Download references

Acknowledgments

The authors would like to thank Ms. Amal Samuel for enhancing the art work used in the present study.

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Authors and Affiliations

  1. Université du Québec a Chicoutimi, Chicoutimi, QC, Canada

    G. H. Garza-Elizondo, A. M. Samuel & F. H. Samuel

  2. Nemak, S.A., Garza Garcia, N.L., Mexico

    S. Valtierra

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  1. G. H. Garza-Elizondo
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  2. A. M. Samuel
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  3. S. Valtierra
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  4. F. H. Samuel
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Correspondence to F. H. Samuel.

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Garza-Elizondo, G.H., Samuel, A.M., Valtierra, S. et al. Effect of Ni, Mn, Sc, and Zr Addition on the Tensile Properties of 354-Type Alloys at Ambient Temperature. Inter Metalcast 11, 396–412 (2017). https://doi.org/10.1007/s40962-016-0072-0

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