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Multifunctional devices based on planar microsupercapacitors: Progress and challenges

基于平面微型超级电容器的多功能器件: 进展与挑战

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Abstract

With the boom of portable, wearable, and implantable smart electronics in the last decade, the demand for multifunctional microscale electrochemical energy storage devices has increased. Owing to their excellent rate performance, high power density, long cycling lifetime, easy fabrication, and integration, multifunctional planar microsupercapacitors (PMSCs) are deemed as one of the ideal micropower sources for next-generation flexible on-chip electronics. Therefore, we offer a comprehensive overview of the recent progress regarding multifunctional devices based on PMSCs, including stretchable, self-healing, stimulus-responsive, thermosensitive, biodegradable, and temperature-tolerant microdevices. We also emphasize the unique applications of multifunctionally integrated PMSCs in the construction of self-powered and sensor-integrated systems in terms of multifunctional operation modes. Finally, the key challenges and future prospects related to these multifunctional devices are discussed to stimulate further research in this flourishing field.

摘要

在过去十年, 随着便携式、可穿戴和可植入智能电子产品的蓬 勃发展, 对多功能微型电化学储能器件的需求不断增加. 由于优异的倍 率性能、高功率密度、长循环寿命、易于制造和集成等特点, 多功能 平面微型超级电容器(PMSCs)被认为是下一代柔性芯片上电子器件的 理想微电源之一. 在这篇综述中, 我们全面概述了基于PMSCs的多功能 器件的最新进展, 包括具有可拉伸性、自愈合性、刺激响应性、热敏 性、可生物降解性以及耐温性的微型器件. 此外, 在多功能运行模式方 面, 还强调了PMSCs多功能性集成在构建自供电集成系统和传感器集 成系统方面的独特应用. 最后, 讨论了关于基于PMSCs的多功能器件目 前存在的主要挑战以及未来前景. 我们希望本综述可以促进这一领域 的深入研究.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (NSFC, 22109009, 21975027, 22035005, and 52073159), China Postdoctoral Science Foundation (2020M680376), the National Key R&D Program of China (2017YFB1104300), and the NSFC-STINT (21911530143).

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Authors and Affiliations

  1. Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

    Li Song  (宋丽), Xuting Jin  (靳绪庭), Chunlong Dai  (代春龙), Yuyang Han  (韩雨洋), Jiatao Zhang  (张加涛) & Zhipan Zhang  (张志攀)

  2. School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China

    Xuting Jin  (靳绪庭) & Jiatao Zhang  (张加涛)

  3. Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing, 100084, China

    Liangti Qu  (曲良体)

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  1. Li Song  (宋丽)
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  2. Xuting Jin  (靳绪庭)
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  3. Chunlong Dai  (代春龙)
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  4. Yuyang Han  (韩雨洋)
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  5. Jiatao Zhang  (张加涛)
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  6. Zhipan Zhang  (张志攀)
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  7. Liangti Qu  (曲良体)
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Contributions

Song L, Jin X, Zhang Z and Qu L wrote and revised the manuscript. Song L, Dai C and Han Y collected and summarized the literature and Zhang J contributed to the manuscript writing. Jin X, Zhang Z and Qu L revised the manuscript and offered creative proposal for improving the depth and coverage of the review. All authors contributed to the general discussion.

Corresponding authors

Correspondence to Xuting Jin  (靳绪庭), Zhipan Zhang  (张志攀) or Liangti Qu  (曲良体).

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Conflict of interest

The authors declare that they have no conflict of interest.

Li Song received her PhD degree in 2019 from Tianjin University, China. She is currently a postdoctor under the supervision of Prof. Liangti Qu at the School of Chemistry and Chemical Engineering, Beijing Institute of Technology (BIT). Her interests focus on flexible energy storage devices.

Xuting Jin received his PhD degree in 2020 from BIT, China. He is currently a postdoctor under the supervision of Prof. Jiatao Zhang at the School of Materials Science and Engineering, BIT. His research interests in energy storage mainly focus on supercapacitors, zinc ion batteries, micro-batteries, and their functionalization.

Zhipan Zhang received his doctorate degree from École Polytechnique Fédérale de Lausanne (Swiss federal Institute of Technology in Lausanne) in 2008. After working at Dysol Ltd., Monash University, and the University of Calgary, he is now a professor at BIT. His research focuses on nano-functional materials and new energy conversion and storage devices.

Liangti Qu received his PhD degree in chemistry from Tsinghua University (Beijing, China) in 2004. He is now a professor at the Department of Chemistry, Tsinghua University and leads the nanocarbon research group. His research interests in materials chemistry mainly focus on the synthesis, functionalization, and application of nano-materials with carbon-carbon conjugated structures, including carbon nanotubes, graphene, and conducting polymers.

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Song, L., Jin, X., Dai, C. et al. Multifunctional devices based on planar microsupercapacitors: Progress and challenges. Sci. China Mater. 65, 3202–3228 (2022). https://doi.org/10.1007/s40843-022-2175-y

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