Abstract
It is a challenge to develop a biodegradable toughener to toughen polylactic acid (PLA) with both high strength and high toughness, since toughness and strength are mutually exclusive. Here, a series of supertough polyester thermoplastic elastomers (TPEs), poly(L/D-lactide)-b-poly(ε-caprolactone-co-δ-valerolactone)-b-poly (L/D-lactide)s (PLLA-PCVL-PLLA, L-TPEs or PDLA-PCVL-PDLA, D-TPEs), were prepared and blended with a PLLA matrix to toughen PLLA. The mechanical properties of PLLA could be regulated in a wide range by changing blending ratios and TPE structures. For PLLA blends toughened by L-TPEs, the highest elongation at break is up to 425% with the tensile strength of 33.1 MPa and the toughness of 104 MJ/m3. By the stereocomplex crystallization of PLA (sc-PLA), the tensile strength of the PLLA/D-TPE blends further increased to 41.8 MPa with a similar elongation at break (418%) and the toughness up to 128 MJ/m3. The detailed characterizations revealed a toughening mechanism: (I) the added soft segments increased the ductility of the PLLA matrix, (II) the PLLA segments of L-TPEs increased the compatibility between TPEs and PLLA matrix, and (III) the formation of sc-PLA between the PDLA segments in D-TPE and PLLA provided higher tensile strength by enhancing the strength of the crystal skeleton. The toughened PLA using TPEs can maintain original non-toxic and degradable properties, and be applied potentially in surgical sutures, and 3D-printed scaffolds.
Similar content being viewed by others
References
Moradi S., Yeganeh J. K., Polym. Test., 2020, 91, 106735
Zhou X., Deng J., Fang C., Leia W., Song Y., Zhang Z., Huang Z., Li Y., J. Mater. Sci. Technol., 2021, 60, 27
Izraylit V., Heuchel M., Gould O. E. C., Kratz K., Lendlein A., Polymer, 2020, 209, 122984
Cao X., Wang Y., Chen H., Hu J., Cui L., Composites Part B, 2021, 217, 108934
Jing Z., Huang X., Liu X., Liao M., Zhang Z., Li Y., RSC Adv., 2022, 12, 13180
Yang J., Pan H., Li X., Sun S., Zhang H., Dong L., RSC Adv., 2017, 7, 46183
Hirata M., Masutani K., Kimura Y., Biomacromolecules, 2013, 14, 2154
Ma P., Spoelstra A. B., Schmit P., Lemstra P. J., Eur. Polym. J., 2013, 49, 1523
Tan B. H., Muiruri J. K., Li Z., He C., ACS Sustain. Chem. Eng., 2016, 4, 5370
Ma P., Hristova-Bogaerds D. G., Goossens J. G. P., Spoelstra A. B., Zhang Y., Lemstra P. J., Eur. Polym. J., 2012, 48, 146
Yeo J. C. C., Muiruri J. K., Thitsartarn W., Lib Z., He C., Mater. Sci. Eng. C, 2018, 92, 1092
Sun Y., Yang L., Lu X., He C., J. Mater. Chem. A, 2015, 3, 3699
Lebarbé T., Grau É., Cramail H., Eur. Polym. J., 2015, 65, 276
Sun Fan X., Lu X., He C., Macromol. Rapid Commun., 2019, 40, 1800047
Wen J., Yi L., Su J., Han J., Int. J. Biol. Macromol., 2023, 231, 123419
Srisuwan Y., Baimark Y., Suttiruengwong S., Int. J. Biomater., 2018, 2018, 1294397
Rathi S. R., Coughlin E. B., Hsu S. L., Golub C. S., Ling G. H., Tzivanis M. J., Polymer, 2012, 53, 3008
Grijpma D. W., Pennings A. J., Polym. Bull., 1991, 25, 335
Zhao X., Hu H., Wang X., Yu X., Zhou W., Peng S., RSC Adv., 2020, 10, 13316
Lin J.-O., Chen W., Shen Z., Ling J., Macromolecules, 2013, 46, 7769
Wang M., Wu Y., Li Y.-D., Zeng J.-B., Polym. Rev., 2017, 57, 557
Zhao T.-H., Yuan W.-Q., Li Y.-D., Weng Y.-X., Zeng J.-B., Macromolecules, 2018, 51, 2027
Xiu H., Bai H. W., Huang C. M., Xu C. L., Li X. Y., Fu Q., Express Polym. Lett., 2013, 7, 261
Zhang X., Koranteng E., Wu Z., Wu Q., J. Appl. Polym. Sci., 2016, 133, 42983
Yu R.-L., Zhang L.-S., Feng Y.-H., Zhang R.-Y., Zhu J., Chin. J. Polym. Sci., 2014, 32, 1099
Kasyapi N., Bhowmick A. K., RSC Adv., 2014, 4, 27439
Mulchandani N., Masutani K., Kumar S., Yamane H., Sakurai S., Kimura Y., Katiyar V., Polym. Chem., 2021, 12, 3806
Kim J.-H., Lee J. H., Polym. J., 2002, 34, 203
Liu G.-C., He Y.-S., Zeng J.-B., Li Q.-T., Wang Y.-Z., Biomacromolecules, 2014, 15, 4260
Li T.-T., Zhang H., Huang S.-Y., Pei X., Lin Q., Tian S., Ma Z., Lin J.-H., J. Polym. Res., 2021, 28, 156
Pez-Rodríguez N. L., Pez-Arraiza A. L. E. Meaurio J. R. S., Polym. Eng. Sci., 2006, 46, 1299
Jiang L., Wolcott M. P., Zhang J., Biomacromolecules, 2006, 7, 199
Al-Itry R., Lamnawar K., Maazouz A., Polym. Degrad. Stab., 2012, 97, 1898
Lebarbé T., Grau E., Gadenne B., Alfos C., Cramail H., ACS Sustainable Chem. Eng., 2015, 3, 283
Xiang S., Feng L., Bian X., Zhang B., Sun B., Liu Y., Li G., Chen X., Polym. Adv. Technol., 2019, 30, 963
Yang S., Madbouly S. A., Schrader J. A., Srinivasan G., Grewell D., McCabe K. G., Kesslere M. R., Gravesc W. R., Green Chem., 2015, 17, 380
Chen W., Qi C., Li Y., Tao H., Radiat. Phys. Chem., 2021, 180, 109239
Hu X., Su T., Li P., Wang Z., Polym. Bull., 2018, 75, 533
Harada M., Iida K., Okamoto K., Hayashi H., Hirano K., Polym. Eng. Sci., 2008, 48, 1359
Lin S., Guo W., Chen C., Ma J., Wang B., Mater. Des., 2012, 36, 604
Bian Y., Han C., Han L., Lin H., Zhang H., Biana J., Dong L., RSC Adv., 2014, 4, 41722
Yang X., Clénet J., Xu H., Odelius K., Hakkarainen M., Macromolecules, 2015, 48, 2509
Wang R., Wang S., Zhang Y., J. Appl. Polym. Sci., 2010, 113, 3630
Zhao W., Li C., Yang X., He J., Pang X., Zhang Y., Men Y., Chen X., CCS Chem., 2022, 4, 1263
Liu Y., Shao J., Sun J., Bian X., Feng L., Xiang S., Sun B., Chen Z., Li G., Chen X., Polym. Degrad. Stab., 2014, 101, 10
Xiao X., Chevali V. S., Song P., Yu B., Yang Y., Wang H., Compos. Commun., 2020, 21, 100385
Feng L., Bian X., Li G., Chen X., Macromolecules, 2021, 54, 10163
Shi X., Qin J., Wang L., Ren L., Rong F., Li D., Wang R., Zhang G., RSC Adv., 2018, 8, 11850
Meredith J. C., Amis E. J., Macromol. Chem. Phys., 2000, 201, 733
Acknowledgements
This work was supported by the National Key Research and Development Program of China (No.2022YFB3704900), the National Natural Science Foundation of China (Nos. 22225104, 22071077, 21871107, 21975102) and the China Postdoctoral Science Foundation (Nos. 2022TQ0115 and 2022M711297).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
The authors declare no conflicts of interest.
Rights and permissions
About this article
Cite this article
Feng, S., Zhao, W., He, J. et al. High Performance Polylactide Toughened by Supertough Polyester Thermoplastic Elastomers: Properties and Mechanism. Chem. Res. Chin. Univ. 39, 750–756 (2023). https://doi.org/10.1007/s40242-023-3160-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40242-023-3160-8