Abstract
The carbon/boron co-doped TiO2 (CBCT) photocatalyst was produced through the gel-hydrothermal process in this study. Its properties were then analyzed by using XRD, FE-SEM, EDX, FTIR, BET and Raman techniques, according to which the CBCT had the dominant anatase phase, whereas its specific surface area (46.1 m2/g) and porosity (0.101) made it a suitable photocatalyst. The response surface methodology (RSM) was then employed to design an experiment to study the effects of pH, initial 4-nitrophenol concentration, irradiation time, irradiation intensity, and nanocatalyst concentration on the 4-nitrophenol removal efficiency. Based on the proposed experiments by the RSM, the highest removal efficiency (99.8%) was reported at a pH of 3.6, an initial 4-nitrophenol concentration of 20 mg/L, an irradiation time of 50 min, an irradiation intensity of 60 W, and a nanocatalyst concentration of 0.4 g/L. Increasing pH and pollutant concentration decreased removal efficiency; similarly, increasing nanocatalyst concentration, irradiation time, and intensity reduced removal efficiency. The photocatalytic removal of 4-nitrophenol was performed in the presence of 1% v/v of H2O2. Finally, the 4-nitrophenol removal efficiency was modeled based on the five designated parameters.
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References
Abazari R, Mahjoub AR, Salehi G (2019) Preparation of amine functionalized g-C3N4@H/SMOF NCs with visible light photocatalytic characteristic for 4-nitrophenol degradation from aqueous solution. J Hazard Mater 365:921–931. https://doi.org/10.1016/j.jhazmat.2018.11.087
Al Subhi A, Valizadeh Kiamahalleh M, Firouzi M, Yousefi F, Htet Kyaw H, Al Abri M, Firouzi A, Valizadeh Kiamahalleh M (2020) Self-assembled graphene hydrogel composites for selective dye removal. Adv Sustain Syst. https://doi.org/10.1002/adsu.202000055
Asadi P, Amini RH, Qaderi F (2019) Comparison of Chlorella vulgaris and Chlorella sorokiniana pa.91 in post treatment of dairy wastewater treatment plant effluents. Environ Sci Pollut Res 26:29473–29489. https://doi.org/10.1007/s11356-019-06051-8
Asadi P, Amini RH, Qaderi F (2020) Lipid and biodiesel production by cultivation isolated strain Chlorella sorokiniana pa.91 and Chlorella vulgaris in dairy wastewater treatment plant effluents. J Environ Health Sci Eng 18:573–585. https://doi.org/10.1007/s40201-020-00483-y
Azizpour F, Qaderi F (2019) Optimization, modeling and uncertainty investigation of phenolic wastewater treatment by photocatalytic process in cascade reactor. Environ Dev Sustain 22:6315–6342. https://doi.org/10.1007/s10668-019-00480-8
Babanezhad E, Amini RH, Hosseini Karimi SS, Qaderi F (2017) Investigating nitrogen removal using simultaneous nitrification-denitrification in transferring wastewater through collection networks with small-diameter pipes. Water Pract Technol 12:396–405. https://doi.org/10.2166/wpt.2017.044
Babanezhad E, Qaderi F, Salehi ZM (2018) Spatial modeling of groundwater quality based on using Schoeller diagram in GIS base: a case study of Khorramabad. Iran Environ Earth Sci 77:339. https://doi.org/10.1007/s12665-018-7541-0
Cavalcante RP, Dantas RF, Bayarri B, González O, Giménez J, Esplugas S, Machulek A (2015) Synthesis and characterization of B-doped TiO2 and their performance for the degradation of metoprolol. Catal Today 252:27–34. https://doi.org/10.1016/j.cattod.2014.09.030
Ebrahimi M, Qaderi F (2021) Determination of the most effective control methods of SO2 pollution in Tehran based on adaptive neuro-fuzzy inference system. Chemosphere 263:128002. https://doi.org/10.1016/j.chemosphere.2020.128002
Faghih Nasiri E, Yousefi Kebria D, Qaderi F (2018) An experimental study on the simultaneous phenol and chromium removal from water using titanium dioxide photocatalyst. Civ Eng J 4(3):585–593. https://doi.org/10.28991/cej-0309117
Girish CR, Murty VR (2012) Review of various treatment methods for the abatement of phenolic compounds from wastewater. J Environ Sci Eng 54(2):306–316
Jafarikojour M, Mohammadi MM, Sohrabi M, Royaee SJ (2015) Evaluation and modeling of a newly designed impinging stream photoreactor equipped with a TiO2 coated fiberglass cloth. RSC Adv 5:9019–9027. https://doi.org/10.1039/c4ra13670e
Khalegh R, Qaderi F (2019) Optimization of the effect of nanoparticle morphologies on the cost of dye wastewater treatment via ultrasonic/photocatalytic hybrid process. Appl Nanosci 9:1869–1889. https://doi.org/10.1007/s13204-019-00984-9
Kumar SG, Devi LG (2011) Review on modified TiO2 photocatalysis under UV/visible light: selected results and related mechanisms on interfacial charge carrier transfer dynamics. J Phys Chem A. https://doi.org/10.1021/jp204364a
Lu X, Tian B, Chen F, Zhang J (2010) Preparation of boron-doped TiO2 films by autoclaved-sol method at low temperature and study on their photocatalytic activity. Thin Solid Films 519:111–116. https://doi.org/10.1016/j.tsf.2010.07.071
Madadi S, Sohrabi M, Royaee SJ (2015) Performance evaluation of a novel multi-stage axial radial impinging flow photo-reactor for degradation of p-nitrophenol. J Taiwan Inst Chem Eng 55:101–111. https://doi.org/10.1016/j.jtice.2015.03.029
Mohammadi S, Kargari A, Sanaeepur H, Abbassian K, Najafi A, Mofarrah E (2015) Phenol removal from industrial wastewaters: a short review. Desalin Water Treat 53:2215–2234. https://doi.org/10.1080/19443994.2014.883327
Pajoum Shariati F, Qaderi F, Haeri H (2018) Using moving bed biofilm reactor including Kaldness media in treatment of wastewater containing light component petroleum. J Civ Environ Eng. https://doi.org/10.22034/JCEE.2020.25824.1621
Pouretedal HR, Sohrabi AM (2016) Photosensitization of TiO2 by ZnS and bromo thymol blue and its application in photodegradation of para-nitrophenol. J Iran Chem Soc 13:73–79. https://doi.org/10.1007/s13738-015-0712-y
Qaderi F, Babanezhad E (2017) Prediction of the groundwater remediation costs for drinking use based on quality of water resource, using artificial neural network. J Clean Prod 161:840–849. https://doi.org/10.1016/j.jclepro.2017.05.187
Qaderi F, Ayati B, Ganjidoust H (2011) Role of moving bed biofilm reactor and sequencing batch reactor in biological degradation of formaldehyde wastewater. J Environ Health Sci Eng 8:295–306
Qaderi F, Ayati B, Ganjidoust H (2012) Comparing the efficiency of MBBR and SBR in treating wastewater containing formaldehyde. Amirkabir J Civ Eng 43(2):43–50. https://doi.org/10.22060/CEEJ.2012.139
Qaderi F, Asadi P, Tamadoni A, Azizi M (2018a) Evaluation of sustainability of development in Zone of Tehran by ecological footprint method. Geogr Dev Iran J 16(50):231–245. https://doi.org/10.22111/gdij.2018.3575
Qaderi F, Sayahzadeh AH, Azizi M (2018b) Efficiency optimization of petroleum wastewater treatment by using of serial moving bed biofilm reactors. J Clean Prod 192:665–677. https://doi.org/10.1016/j.jclepro.2018.04.257
Qaderi F, Sayahzadeh AH, Azizpour F, Vosughi P (2018c) Efficiency modeling of serial stabilization ponds in treatment of phenolic wastewater by response surface methodology. Int j Environ Sci Technol 16(8):4193–4202. https://doi.org/10.1007/s13762-018-1816-6
Rezaei-Vahidian H, Zarei AR, Soleymani AR (2017) Degradation of nitro-aromatic explosives using recyclable magnetic photocatalyst: catalyst synthesis and process optimization. J Hazard Mater 325:310–318. https://doi.org/10.1016/j.jhazmat.2016.12.001
Rouzafzay F, Shidpour R, Al-Abri MZM, Qaderi F, Ahmadi A, Myint MTZ (2020) Graphene@ZnO nanocompound for short-time water treatment under sun-simulated irradiation: effect of shear exfoliation of graphene using kitchen blender on photocatalytic degradation. J Alloys Compd 829:154614. https://doi.org/10.1016/j.jallcom.2020.154614
Setviń M, Aschauer U, Scheiber P, Li YF, Hou W, Schmid M, Selloni A, Diebold U (2013) Reaction of O2 with subsurface oxygen vacancies on TiO2 anatase (101). Science 341(6149):988–991. https://doi.org/10.1126/science.1239879
Sheikholeslami Z, Yousefi KD, Qaderi F (2018) Nanoparticle for degradation of BTEX in produced water; an experimental procedure. J Mol Liq 246:476–482. https://doi.org/10.1016/j.molliq.2018.05.096
Sheikholeslami Z, Yousefi KD, Qaderi F (2019) Investigation of photocatalytic degradation of BTEX in produced water using γ-Fe2O3 nanoparticle. J Therm Anal Calorim 135(3):1617–1627. https://doi.org/10.1007/s10973-018-7381-x
Sheikholeslami Z, Yousefi KD, Qaderi F (2020) Application of γ-Fe2O3 nanoparticles for pollution removal from water with visible light. J Mol Liq 299:112118. https://doi.org/10.1016/j.molliq.2019.112118
Shokri A, Mahanpoor K, Soodbar D (2016) Evaluation of a modified TiO2 (GO-B-TiO2) photo catalyst for degradation of 4-nitrophenol in petrochemical wastewater by response surface methodology based on the central composite design. J Environ Chem Eng 4:585–598. https://doi.org/10.1016/j.jece.2015.11.007
Stamate M, Lazar G (2007) Application of titanium dioxide photocatalysis to create self-cleaning materials. Lacer 3:280–285
Taghizadeh M, Yousefi D, Qaderi F (2019) Benzene and toluene removal from saline water with coupled membrane process and nanophotocatalyst. J Pet Res 28(102):45–48. https://doi.org/10.22078/pr.2018.3132.2445
Taghizadeh M, Yousefi KD, Qaderi F (2020) Effect of bio surfactant as a novel draw solution on photocatalytic treatment and desalination of produced water by different forward osmosis membranes. Water Sci Tech-W Sup. https://doi.org/10.2166/ws.2019.154
Tamadoni A, Qaderi F (2019) Optimization of soil remediation by ozonation for PAHs contaminatedsoils. Ozone Sci Eng 41(5):454–472. https://doi.org/10.1080/01919512.2019.1615865
Tamadoni A, Qaderi F (2020) Environmental-economical assessment of the use of ultrasonication for pre-treatment of the soils contaminated by phenanthrene. J Environ Manage 259:109991. https://doi.org/10.1016/j.jenvman.2019.109991
Tavakoli MM, Qaderi F (2019) Modeling of petroleum wastewater treatment by Fe/Zn nanoparticles using the response surface methodology and enhancing the efficiency by scavenger. Results Phys 15:102566–102576. https://doi.org/10.1016/j.rinp.2019.102566
Wang H, Lewis JP (2006) Second-generation photocatalytic materials: anion-doped TiO2. J Phys Condens Matter 18:421–434. https://doi.org/10.1088/0953-8984/18/2/006
Wu Y, Xing M, Zhang J (2011) Gel-hydrothermal synthesis of carbon and boron co-doped TiO2 and evaluating its photocatalytic activity. J Hazard Mater 192:368–373. https://doi.org/10.1016/j.jhazmat.2011.05.037
Yang Y, Lu X, Wang W (2017) A tough polyurethane elastomer with self-healing ability. Mater Des 127:30–36. https://doi.org/10.1016/j.matdes.2017.04.015
Yang Q, Guo E, Liu H, Lu Q (2019) Engineering of Z-scheme 2D/3D architectures with Bi2MoO6 on TiO2 nanosphere for enhanced photocatalytic 4-nitrophenol degradation. J Taiwan Inst Chem Eng 105:65–74. https://doi.org/10.1016/j.jtice.2019.09.024
Yavari SM, Qaderi F (2020) Determination of thermal pollution of water resources caused by Neka power plant through processing satellite imagery. Environ Dev Sustain 22:1953–1975. https://doi.org/10.1007/s10668-018-0272-2
Yu JC, Yu J, Ho W, Jiang Z, Zhang L (2002) Effects of F- doping on the photocatalytic activity and microstructures of nanocrystalline TiO2 powders. Chem Mater 14:3808–3816. https://doi.org/10.1021/cm020027c
Zhang P, Shao C, Zhang Z, Zhang M, Mu J, Liu Y (2011) TiO2@carbon core/shell nanofibers: controllable preparation and enhanced visible photocatalytic properties. Nanoscale 3(7):2943–2949. https://doi.org/10.1039/c1nr10269a
Zhang W, Li G, Wang W, Qin Y, An T, Xiao X, Choi W (2018) Enhanced photocatalytic mechanism of Ag3PO4 nano-sheets using MS2 (M = Mo, W)/rGO hybrids as co-catalysts for 4-nitrophenol degradation in water. Appl Catal B Environ 232:11–18. https://doi.org/10.1016/j.apcatb.2018.03.006
Zheng J, Liu Z, Liu X, Yan X, Li D, Chu W (2011) Facile hydrothermal synthesis and characteristics of B-doped TiO2 hybrid hollow microspheres with higher photo-catalytic activity. J Alloys Compd 509:3771–3776. https://doi.org/10.1016/j.jallcom.2010.12.152
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The authors would like to thank Habib Pourdelan and Morteza jafarikojour for their contributions to this work.
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Azizi, M., Ebadi, T. & Qaderi, F. A novel method of co-doping TiO2 with carbon and boron for enhancing photocatalytic degradation of 4-nitrophenol. Int. J. Environ. Sci. Technol. 19, 2619–2634 (2022). https://doi.org/10.1007/s13762-021-03386-z
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DOI: https://doi.org/10.1007/s13762-021-03386-z