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Synthesis of 5-substituted-1H-tetrazoles using zinc zirconium phosphate and copper zirconium phosphate as reusable heterogeneous catalysts

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Abstract

Zinc zirconium phosphate and copper zirconium phosphate were used as reusable and efficient heterogeneous catalysts for the synthesis of 5-substituted-1H-tetrazoles through the [3 + 2] cycloaddition between various nitriles and sodium azide in N,N- dimethylformamide as solvent at 120 °C. This synthetic pathway has significant benefits, such as simple methodology, easy work-up procedure, and high yields. In addition, these nanocatalysts have no toxic metals and can be efficiently recycled up to several consecutive runs.

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Authors and Affiliations

  1. Faculty of Chemistry and Chemical Engineering, Malek-Ashtar University of Technology, Tehran, Iran

    Fatemeh Abrishami & Fatemeh Nakhaei

  2. Estahban Higher Education Center - Shiraz University, Estahban, Iran

    Marzieh Daryanavard

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  1. Fatemeh Abrishami
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  2. Marzieh Daryanavard
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  3. Fatemeh Nakhaei
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Correspondence to Fatemeh Abrishami or Marzieh Daryanavard.

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Abrishami, F., Daryanavard, M. & Nakhaei, F. Synthesis of 5-substituted-1H-tetrazoles using zinc zirconium phosphate and copper zirconium phosphate as reusable heterogeneous catalysts. J IRAN CHEM SOC 20, 1821–1829 (2023). https://doi.org/10.1007/s13738-023-02799-6

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