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Igneous rock powder as a heterogeneous multi-oxide nano-catalyst for the synthesis of 5-substituted-1H-tetrazoles in polyethylene glycol

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Abstract

The use of igneous rock nano-powder as a heterogeneous and recyclable multi-oxide nano-catalyst synthesizing of 5-substituted-1H-tetrazoles is reported. The igneous rock nano-powder was initially prepared by using the ball-milling method. Then, the structure, morphology, and magnetic properties of the prepared igneous rock nano-powder were characterized with some different spectroscopic, microscopic, and thermogravimetric techniques, such as FTIR, FESEM, XRF, XRD, Histogram, and EDS. The instrumental analyses showed that the prepared igneous rock powder is a mixture of metal oxides, such as Si, Al, Ca, Mg, Fe, Na, Mn, and Sr. It showed an excellent catalytic performance in synthesizing of 5-substituted-1H-tetrazoles through [3 + 2] cycloaddition reaction between sodium azide and nitrile compounds. Various aliphatic and aromatic nitriles and sodium azide were reacted in the presence of a catalytic amount of igneous rock nano-powder at 80 o C temperature in PEG-400. The protocol was simple and rapid, with suitable yields of the obtained tetrazoles. The igneous rock nano-powder is readily accessible, reusable, and holds potential for further application in acid-catalyzed organic syntheses and industrial requirements.

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Acknowledgements

This study was supported by the committee grant of the Shahid Chamran University of Ahvaz No. SCU.SC99.440. The authors gratefully thank this support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran

    Parviz Movaheditabar, Mohammad Javaherian & Valiollah Nobakht

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  1. Parviz Movaheditabar
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  2. Mohammad Javaherian
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  3. Valiollah Nobakht
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Correspondence to Mohammad Javaherian.

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Conflict of interest

All of authors have been received research grants from Department of Chemistry, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran. On behalf of all authors, the corresponding author states that there is no conflict of interest.

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Movaheditabar, P., Javaherian, M. & Nobakht, V. Igneous rock powder as a heterogeneous multi-oxide nano-catalyst for the synthesis of 5-substituted-1H-tetrazoles in polyethylene glycol. J IRAN CHEM SOC 19, 1805–1816 (2022). https://doi.org/10.1007/s13738-021-02421-7

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