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Selective oxidation of benzylic alcohols using Mo(VI) Schiff base complex supported on magnetic nanoparticles as a new recoverable heterogeneous catalyst

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Abstract

In the present study, magnetic nanoparticles were functionalized with a dioxomolybdenum(VI) complex containing the tridentate ONO Schiff base ligand obtained from the condensation reaction of 3-ethoxysalicylaldehyde with 4-aminobenzohydrazide. The supported Mo(VI) complex was then characterized by various physicochemical techniques such as Fourier transform infrared (FT-IR), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), vibrating-sample magnetometer (VSM) and X-ray diffraction (XRD) analyses. Moreover, selective oxidation of the various benzylic alcohols was carried out in the presence of the resultant heterogeneous nanocatalyst using H2O2 as a safe oxidizing agent in ethanol as a green solvent under reflux conditions. The nanocatalyst can be recovered magnetically and can be reused several times without a remarkable loss of activity.

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Acknowledgements

The authors acknowledge the Research Council of Payame Noor University and Ardakan University for financial support.

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, Ardakan University, P.O. Box 184, Ardakan, Iran

    Ali Bovand & Hadi Kargar

  2. Department of Chemistry, Payame Noor University (PNU), 19395-4697, Tehran, Iran

    Mehdi Fallah-Mehrjardi

Authors
  1. Ali Bovand
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  2. Hadi Kargar
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  3. Mehdi Fallah-Mehrjardi
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Correspondence to Hadi Kargar.

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Bovand, A., Kargar, H. & Fallah-Mehrjardi, M. Selective oxidation of benzylic alcohols using Mo(VI) Schiff base complex supported on magnetic nanoparticles as a new recoverable heterogeneous catalyst. J IRAN CHEM SOC 19, 3463–3471 (2022). https://doi.org/10.1007/s13738-022-02539-2

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  • DOI: https://doi.org/10.1007/s13738-022-02539-2

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