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Fabrication of porous molecularly imprinted polymer using halloysite nanotube as template for selective recognition and separation of chloramphenicol

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Abstract

In this research, porous molecularly imprinted polymers (PMIPs) with thin wall were prepared using halloysite nanotube (HNT) hard template, which has a unique hollow tubular structure, for selective recognition and removal of the chloramphenicol (CAP) antibiotic frequently detected in water environment. PMIPs had the good porous structure replicated from the HNT template. The adsorption equilibrium, kinetics, selectivity and regeneration properties of CAP by PMIPs were systematically studied by static adsorption experiments. The maximum adsorption capacity of PMIPs toward CAP increased from 91.26 μmol g−1 at 25 °C to 102.5 μmol g−1 45 °C. The adsorption was in accordance with Freundlich isothermal model, indicating the multi-molecular layer adsorption. The adsorption could reach equilibrium basically within 80 min with a quick kinetic property and was confirmed by the pseudo-second-order kinetics model, indicating the chemical adsorption was rate-controlling step. The high contact temperature was beneficial to the CAP adsorption, thus which was belonged to the endothermic process. Importantly, adsorption selectivity experiments showed PMIPs had the high recognition ability for template molecule CAP whether in one- or two- component antibiotic solutions. Besides, PMIPs exhibited good thermal and chemical stability and reproducibility for practical application in further.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 51608226, 21676127 and 21776110), Natural Science Foundation of Jiangsu Province (BK20170532, BK20160568 and BK20160501), China Postdoctoral Science Foundation (2017M620194), Jiangsu Planned Projects for Postdoctoral Research Funds (1701023A) and Natural Science Foundation of the Higher Education Institutions of Jiangsu Province, China (17KJB430011).

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Authors and Affiliations

  1. Institute of Green Chemistry and Chemical Technology, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, China

    Yue Ma, Jiangdong Dai, Lulu Wang, Yongsheng Yan & Ming Gao

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  1. Yue Ma
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  2. Jiangdong Dai
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  3. Lulu Wang
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  4. Yongsheng Yan
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  5. Ming Gao
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Correspondence to Jiangdong Dai.

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Ma, Y., Dai, J., Wang, L. et al. Fabrication of porous molecularly imprinted polymer using halloysite nanotube as template for selective recognition and separation of chloramphenicol. J IRAN CHEM SOC 17, 555–565 (2020). https://doi.org/10.1007/s13738-019-01792-2

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  • DOI: https://doi.org/10.1007/s13738-019-01792-2

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