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Sulfonated chitosan encapsulated magnetically Fe3O4 nanoparticles as effective and reusable catalyst for ultrasound-promoted rapid, three-component synthesis of spiro-4H-pyrans

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Abstract

A facile one-pot protocol for synthesis of spiro-4H-pyrans using sulfonated chitosan-coated Fe3O4 nanoparticles (Fe3O4@CS-SO3H NPs) as an efficient catalyst under ultrasonic condition has been developed. First, the Fe3O4@CS NPs were prepared from the reaction of chitosan with Fe3O4 NPs. Then, the treatment of Fe3O4@CS NPs with chlorosulfonic acid leads to the formation of Fe3O4@CS-SO3H NPs which exerts excellent catalytic activity toward one-pot, three-component synthesis of spiro-4H-pyran derivatives. The core–shell structure and the composition of produced magnetic nanocatalyst were characterized by FT-IR, XRD, VSM, SEM and EDX techniques.

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Acknowledgements

The authors are grateful to University of Kashan for supporting this work by Grant no. 159148/73.

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Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, 87317-51167, Islamic Republic of Iran

    Hossein Naeimi & Sepideh Lahouti

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  1. Hossein Naeimi
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  2. Sepideh Lahouti
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Correspondence to Hossein Naeimi.

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Naeimi, H., Lahouti, S. Sulfonated chitosan encapsulated magnetically Fe3O4 nanoparticles as effective and reusable catalyst for ultrasound-promoted rapid, three-component synthesis of spiro-4H-pyrans. J IRAN CHEM SOC 15, 2017–2031 (2018). https://doi.org/10.1007/s13738-018-1399-7

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  • DOI: https://doi.org/10.1007/s13738-018-1399-7

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