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Preparation of piperazine-grafted amine-functionalized UiO-66 metal organic framework and its application for CO2 over CH4 separation

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Abstract

UiO-66 amine functionalized was synthesized by solvothermal method. Post-synthetic modification of UiO-66-NH2 with piperazine, a known promoter to enhance the chemisorption rate of CO2 uptake, was carried out and analyzed to understand its crystalline structure, morphology and porous structure. Results show that piperazine is an effective agent for enhancing the capacity of absorption of CO2. This porous product exhibits an improved CO2 uptake at pressures up to 3000 kPa via physisorption and chemisorption mechanisms. The CH4 adsorption and desorption isotherms on UiO-66, UiO-66-NH2 and pip-UiO-66-NH2 at temperature of 298.15 K and pressures ranging from 0 to 5000 kPa were carried out. IAS theory for a mixture of 0.05 bar CO2, 0.85 bar CH4 and 0.1 bar other gas revealed a selectivity factor of 19.09 for CO2/CH4 from pip-UiO-66-NH2. Results show that these materials are effective adsorbents for CO2 and CH4 uptakes.

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References

  1. Z. Zhang, Z. Li, J. Li, Langmuir 28, 12122 (2012)

    Article  CAS  Google Scholar 

  2. A.L. Kohl, R.B. Nielsen, Gas Purification, 5th edn. (TX, Gulf Professional Publishing, Houston, 1997)

    Google Scholar 

  3. P.D. Vaidya, E.Y. Kenig, Chem. Eng. Technol. 30, 1467 (2007)

    Article  CAS  Google Scholar 

  4. A. Das, P.D. Southon, M. Zhao, C.J. Kepert, A.T. Harris, D.M. D’Alessandro, Dalton Trans. 41, 11739 (2012)

    Article  CAS  Google Scholar 

  5. J.T. Yeh, K.P. Resnik, K. Rygle, H.W. Pennline, Fuel Process. Technol. 86, 1533 (2005)

    Article  CAS  Google Scholar 

  6. Y. Liu, Z.U. Wang, H.C. Zhou, Greenhouse Gas. Sci. Technol. 2, 239 (2012)

    CAS  Google Scholar 

  7. J. Zhang, P.A. Webley, P. Xiao, Energ. Convers. Manage. 49, 346 (2008)

    CAS  Google Scholar 

  8. H. Jasuja, J. Zang, D.S. Sholl, K.S. Walton, J. Phys. Chem. C 116, 23526 (2012)

    Article  CAS  Google Scholar 

  9. O.M. Yaghi, Q. Li, MRS Bull. 34, 682 (2009)

    Article  CAS  Google Scholar 

  10. L.J. Murray, M. Dinca, J.R. Long, Chem. Soc. Rev. 38, 1294 (2009)

    Article  CAS  Google Scholar 

  11. J.R. Li, R.J. Kuppler, H.C. Zhou, Chem. Soc. Rev. 38, 1477 (2009)

    Article  CAS  Google Scholar 

  12. J. Lee, O.K. Farha, J. Roberts, K.A. Scheidt, S.T. Nguyen, J.T. Hupp, Chem. Soc. Rev. 38, 1450 (2009)

    Article  CAS  Google Scholar 

  13. R. Zou, A.I. Abdel-Fattah, H. Xu, Y. Zhao, D.D. Hickmott, Cryst. Eng. Comm. 12, 1337 (2010)

    Article  CAS  Google Scholar 

  14. G. Ferey, C. Serre, T. Devic, G. Maurin, H. Jobic, P.L. Llewellyn, G.D. Weireld, A. Vimont, M. Daturi, J.S. Chang, Chem. Soc. Rev. 40, 550 (2011)

    Article  CAS  Google Scholar 

  15. K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.H. Bae, J.R. Long, Chem. Rev. 112(724), 10 (2012)

    Google Scholar 

  16. J.R. Li, Y. Ma, M.C. McCarthy, J. Sculley, J. Yu, H.K. Jeong, P.B. Balbuena, H.C. Zhou, Coord. Chem. Rev. 255, 1791 (2011)

    Article  CAS  Google Scholar 

  17. J.R. Li, J. Sculley, H.C. Zhou, Chem. Rev. 112, 869 (2012)

    Article  CAS  Google Scholar 

  18. H. Li, M. Eddaoudi, T.L. Groy, O.M. Yaghi, J. Am. Chem. Soc. 120, 8571 (1998)

    Article  CAS  Google Scholar 

  19. A.R. Millward, O.M. Yaghi, J. Am. Chem. Soc. 127, 17998 (2005)

    Article  CAS  Google Scholar 

  20. A. Das, M. Choucair, P.D. Southon, J.A. Mason, M. Zhao, C.J. Kepert, A.T. Harris, D.M. D’Alessandro, Micro. Meso. Mater. 174, 74 (2013)

    Article  CAS  Google Scholar 

  21. W.W. Xu, S. Pramanik, Z. Zhang, T.J. Emge, J. Li, J. Solid State Chem. 200, 1 (2013)

    Article  CAS  Google Scholar 

  22. S. Xiang, Y. He, Z. Zhang, H. Wu, W. Zhou, R. Krishna, B. Chen, Nat. Commun. 3, 954 (2012)

    Article  Google Scholar 

  23. D.L. Seo, W.H. Hong, Ind. Eng. Chem. Res. 39, 2062 (2000)

    Article  CAS  Google Scholar 

  24. M.J. Katz, Z.J. Brown, Y.J. Colo´n, P.W. Siu, K.A. Scheidt, R.Q. Snurr, J.T. Hupp, O.K. Farha. Chem. Commun. 49, 9449 (2013)

    Article  CAS  Google Scholar 

  25. M. Vahidi, A. Tavasoli, A.M. Rashidi, J. Natural Gas Sci. Eng. 28, 651 (2016)

    Article  CAS  Google Scholar 

  26. L.C. Loc, N.T.T. Van, N.V. My, N. Tri, H.T. Cuong, N.V. Hoang, The 4th Int. Workshop on Nanotechnol Appl IWNA Vung Tau, Vietnam, 14–16 Nov (2013)

  27. M. Kandiah, M.H. Nilsen, S. Usseglio, S. Jakobsen, U. Olsbye, M. Tilset, C. Larabi, E.A. Quadrelli, F. Bonino, K.P. Lillerud, Chem. Mater. 22, 6632 (2010)

    Article  CAS  Google Scholar 

  28. C.G. Silva, I. Luz, F.X.L. Xamena, A. Corma, H. Garcia, Chem. Eur. J. 16, 11133 (2010)

    Article  CAS  Google Scholar 

  29. C.L. Luu, T.T.V. Nguyen, T. Nguyen, T.C. Hoang, Adv. Nat. Sci.: Nanosci. Nanotechnol. 6, 025004 (2015)

  30. A. Monshi, M.R. Foroughi, M.R. Monshi, World J. Nano Sci. Eng. 2, 154 (2012)

    Article  Google Scholar 

  31. L. Valenzano, B. Civalleri, S. Chavan, S. Bordiga, M.H. Nilsen, S. Jakobsen, K.P. Lillerud, C. Lamberti, Chem. Mater. 23, 1700 (2011)

    Article  CAS  Google Scholar 

  32. H.R. Abid, J. Shang, H.M. Ang, S. Wang, Int. J. Smart Nano Gas PurificationMater. 4, 72 (2013)

    Article  CAS  Google Scholar 

  33. S. Bauer, C. Serre, T. Devic, P. Horcajada, J. Marrot, G. Frey, N. Stock, Inorg. Chem. 47, 7568 (2008)

    Article  CAS  Google Scholar 

  34. A.I. Myers, J.M. Prausnitz, AIChE J. 11(121), 11 (1965)

    Google Scholar 

  35. Q. Yang, C. Zhong, J. Phys. Chem. B 110, 17776 (2006)

    Article  CAS  Google Scholar 

  36. J.M. Simmons, H. Wu, W. Zhou, T. Yildrim, Energy Environ. Sci. 4, 2177 (2011)

    Article  CAS  Google Scholar 

  37. H. Wu, J.M. Simmons, M. Zhao, Y. Liu, C.M. Brown, X.S. Wang, S. Ma, V.K. Peterson, P.D. Southon, C.J. Kepert, H.C. Zhou, T. Yildirim, W. Zhou, Chem. Eur. J. 16, 5205 (2010)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. School of Chemistry, University College of Science, University of Tehran, 11155-4563, Tehran, Iran

    Mehdi Vahidi & Ahmad Tavasoli

  2. Nanotechnology Research Center, Research Institute of Petroleum Industry (R.I.P.I.), 14665-137, Tehran, Iran

    Mehdi Vahidi & Ali Morad Rashidi

Authors
  1. Mehdi Vahidi
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  2. Ali Morad Rashidi
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  3. Ahmad Tavasoli
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Correspondence to Mehdi Vahidi.

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Vahidi, M., Rashidi, A.M. & Tavasoli, A. Preparation of piperazine-grafted amine-functionalized UiO-66 metal organic framework and its application for CO2 over CH4 separation. J IRAN CHEM SOC 14, 2247–2253 (2017). https://doi.org/10.1007/s13738-017-1161-6

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  • DOI: https://doi.org/10.1007/s13738-017-1161-6

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