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Suzuki–Miyaura cross-coupling reaction by palladium immobilized on functionalized magnetic nanoparticles with NNN and NNS Schiff base ligands in a mild reaction condition

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Abstract

Two new palladium catalysts immobilized on modified magnetic nanoparticles containing NNN and NNS Schiff base ligands were synthesized and characterized by FT-IR spectroscopy, thermogravimetric analysis, X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, CHNS and ICP. These catalytic systems, containing Pd nanoparticles, showed high activity in the Suzuki–Miyaura cross-coupling of phenylboronic acid with aryl halides. The activity, Pd loading, reusability and Pd leaching of these catalysts were compared. The supported catalysts have the advantage to be completely recoverable with the simple application of an external magnetic field. The immobilized palladium catalysts could be reused several times without significant loss of their catalytic activities.

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Acknowledgment

We are thankful to the Research Council of the University of Isfahan for financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Catalysis Division, University of Isfahan Institution, Isfahan, 81746-73441, Iran

    Hossein Khojasteh, Valiollah Mirkhani, Majid Moghadam, Shahram Tangestaninejad & Iraj Mohammadpoor-Baltork

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  1. Hossein Khojasteh
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  2. Valiollah Mirkhani
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  3. Majid Moghadam
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  4. Shahram Tangestaninejad
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  5. Iraj Mohammadpoor-Baltork
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Correspondence to Hossein Khojasteh.

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Khojasteh, H., Mirkhani, V., Moghadam, M. et al. Suzuki–Miyaura cross-coupling reaction by palladium immobilized on functionalized magnetic nanoparticles with NNN and NNS Schiff base ligands in a mild reaction condition. J IRAN CHEM SOC 14, 1139–1150 (2017). https://doi.org/10.1007/s13738-017-1064-6

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  • DOI: https://doi.org/10.1007/s13738-017-1064-6

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