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Preparation and Characterization of Al-doped Tantalum Nitride Thin Films: Effect of Dopant Content and Film Thickness

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Abstract

Current research addresses the electrical, mechanical, and tribological characteristics of sputter-deposited un-doped and Al-doped tantalum nitride thin films that can be used for the development of thin-film resistors (TFRs). Ta and TaAl alloy targets were used to deposit the samples with different Al contents and film thicknesses on the unheated Si and SiO2/Si substrates. X-ray diffraction technique was employed to characterize the crystallographic structure while the resistivity was measured using a four-point probe instrument. Indentation and scratch tests were used to consider the mechanical and tribological properties. Different characteristics of the samples showed a strong dependence on Al content and film thickness. The samples with the lowest thickness (80 nm) showed the highest resistivity values, the best resistance to plastic deformation and abrasion damage, and a near-zero temperature coefficient of resistance (TCR). An increase in Al content also developed the compressive strain in the film structure and improved the mechanical and tribological characteristics of the samples.

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References

  1. C.M. Wang, J.H. Hsieh, C. Li, Thin Solid Films 469–470, 455 (2004)

    Article  ADS  Google Scholar 

  2. K.Y. Wang, T.C. Chang, W.C. Chen, Y.C. Zhang, Y.T. Tseng, C.C. Yang, C.C. Lin, P.Y. Wu, Y.F. Tan, T.M. Tsai, Vac. 197, 11079 (2022)

    Google Scholar 

  3. M. Alishahi, F. Mahboubi, S.M.M. Khoie, M. Aparicio, E. Lopez-Elvira, J. Mendez, R. Gago, RSC Adv. 6, 89061 (2016)

    Article  ADS  Google Scholar 

  4. J.F. Flores, B. Valdez, M. Schorr, J.J. Olaya, Anti-Corros Methods Mater 53, 88 (2006)

    Article  Google Scholar 

  5. G.J. Ma, G.Q. Lin, S.L. Gong, X. Liu, G. Sun, H.C. Wu, Vac. 89, 244 (2013)

    Article  Google Scholar 

  6. I.S. Park, S.Y. Park, G.H. Jeong, S.M. Na, S.J. Suh, Thin Solid Films 516, 5409 (2008)

    Article  ADS  Google Scholar 

  7. N.D. Cuong, D.J. Kim, B.D. Kang, C.S. Kim, K.M. Yu, S.G. Yoon, J. Vac. Sci. Technol. B 24, 1398 (2006)

    Article  Google Scholar 

  8. S. Xu, P. Munroe, J. Xu, Z.H. Xie, Surf. Coat. Technol. 307, 470 (2016)

    Article  Google Scholar 

  9. M.H. Tsai, S.C. Sun, C.E. Tsai, S.H. Chuang, H.T. Chiu, J. Appl. Phys. 79, 6932 (1996)

    Article  ADS  Google Scholar 

  10. N.D. Cuong, D.J. Kim, B.D. Kang, C.S. Kim, K.M. Yu, S.G. Yoon, J. Electrochem. Soc. 153, G164 (2006)

    Article  Google Scholar 

  11. C.L. Au, W.A. Anderson, D.A. Schmitz, J.C. Flassayer, F.M. Collins, J. Mater. Res. 5, 1224 (1990)

    Article  ADS  Google Scholar 

  12. C.M. Wang, J.H. Hsieh, C. Li, Y.Q. Fu, T.P. Chen, U.T. Lam, Surf. Coat. Technol. 193, 173 (2005)

    Article  Google Scholar 

  13. C.M. Wang, J.H. Hsieh, Y.Q. Fu, C. Li, T.P. Chen, U.T. Lam, Ceram. Int. 30, 1879 (2004)

    Article  Google Scholar 

  14. S. Mardani, D. Primetzhofer, L. Liljeholm, Ö. Vallin, H. Norström, J. Olsson, Microelectron. Eng. 120, 257 (2014)

    Article  Google Scholar 

  15. M. Gholami, K. Khojier, M. Monsefi, S.M. Borghei, Brazilian. J. Phys. 52, 171 (2022)

    Google Scholar 

  16. M. Gholami, K. Khojier, M. Monsefi, S.M. Borghei, Int. J. Bio-inorg. Hybr. Nanomater. 11, In press (2022)

  17. N. Al-Hardan, M.J. Abdullah, A. Abdul Aziz, Appl. Surf. Sci. 255, 7794 (2009)

    Article  ADS  Google Scholar 

  18. K. Khojier, H. Savaloni, N. Habashi, M.H. Sadi, Mater. Sci. Semicond. Process. 41, 177 (2016)

    Article  Google Scholar 

  19. B.E. Warren, X-ray diffraction (Addison Wesley Publishing Co., London, 1969)

    Google Scholar 

  20. F.H. Chung, D.K. Smith, Industrial applications of X-ray diffraction (Marcel Dekker Publisher, New York, 1999)

    Google Scholar 

  21. K. Khojier, H. Savaloni, Z. Ashkabusi, N.Z. Dehnavi, Appl. Surf. Sci. 284, 489 (2013)

    Article  ADS  Google Scholar 

  22. L. Eckertova, Physics of thin films (Springer, US, 1977)

    Book  Google Scholar 

  23. F. Angay, S. Camelio, D. Eyidi, B. Krause, G. Abadias, J. Appl. Phys. 131, 105303 (2022)

    Article  ADS  Google Scholar 

  24. J.J. Van Den Broek, J.J.T.M. Honkers, R.A.F. Van Der Rijt, J.T.M. Janssen, Philips J. Res. 51, 429 (1998)

    Article  Google Scholar 

  25. N.R. Moody, R.Q. Hwang, S.V. Taraman, J.E. Angelo, D.P. Norwood, W.W. Gerberich, Acta Mater. 46, 585 (1998)

    Article  ADS  Google Scholar 

  26. R. Westergard, M. Bromark, M. Larsson, P. Hedenqvist, S. Hogmark, Surf. Coat. Technol. 97, 779 (1997)

    Article  Google Scholar 

  27. H.B. Nie, S.Y. Xu, S.J. Wang, L.P. You, Z. Yang, C.K. Ong, J. Li, T.Y.F. Liew, Appl. Phys. A: Mater. Sci. Process. 73, 229 (2001)

    Article  ADS  Google Scholar 

  28. D. Bernoulli, U. Müller, M. Schwarzenberger, R. Hauert, R. Spolenak, Thin Solid Films 548, 157 (2013)

    Article  ADS  Google Scholar 

  29. V. Zin, F. Montagner, S.M. Deambrosis, C. Mortalo, L. Litti, M. Meneghetti, E. Miorin, Mater. 15, 3354 (2022)

    Article  Google Scholar 

  30. T.Z.H. Ting, M.E. Rahman, H.H. Lau, M.Z.Y. Ting, V. Pakrashi, Encycl. Renew. Sustain. Mater. 3, 137 (2020)

    Article  Google Scholar 

  31. K. Khojier, G. Moradi, Surf. Coat. Technol. 425, 127673 (2021)

    Article  Google Scholar 

  32. K. Khojier, H. Savaloni, S. Zolghadr, E. Amani, J. Mater. Eng. Perform. 23, 3444 (2014)

    Article  Google Scholar 

  33. T.G. Wang, D. Jeong, Y. Liu, Q. Wang, S. Iyengar, S. Melin, K.H. Kim, Surf. Coat. Technol. 206, 2638 (2012)

    Article  Google Scholar 

  34. S.V. Hainsworth, W.C. Soh, Surf. Coat. Technol. 163–164, 515 (2003)

    Article  Google Scholar 

  35. P. Patsalas, C. Charitidis, S. Logothetidis, Surf. Coat. Technol. 125, 335 (2000)

    Article  Google Scholar 

  36. H. Holleck, J. Vac. Sci. Technol. A 4, 2661 (1986)

    Article  Google Scholar 

  37. Z. Gong, W. Zhao, K. Guan, P. Rao, Q. Zeng, J. Liu, Z. Feng, J. Am. Ceram. Soc. 103, 5900 (2020)

    Article  Google Scholar 

  38. X. Liu, F. Yuan, Y. Wei, Appl. Surf. Sci. 279, 159 (2013)

    Article  ADS  Google Scholar 

  39. B.B. Jung, H.K. Lee, H.C. Park, Int. J. Solids Struct. 50, 2719 (2013)

    Article  Google Scholar 

  40. H. Zegtouf, N. Saoula, M. Azibi, L. Bait, N. Madaoui, M.R. Khelladi, M. Kechouane, Surf. Coat. Technol. 393, 125821 (2020)

    Article  Google Scholar 

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Acknowledgements

This work was carried out with the support of the Islamic Azad University, Karaj and Chalous branches.

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Contributions

M. Golami: part of the experimental process and software. K. Khojier: supervision, conceptualization, part of the experimental process, writing, and editing. M. Monsefi: methodology, supervision, and editing. S. M. Borghei: software and investigation.

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Correspondence to K. Khojier.

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Gholami, M., Khojier, K., Monsefi, M. et al. Preparation and Characterization of Al-doped Tantalum Nitride Thin Films: Effect of Dopant Content and Film Thickness. Braz J Phys 53, 76 (2023). https://doi.org/10.1007/s13538-023-01277-x

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