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Bio-reticulation of Pd nanorods enables catalytic treatment of various cloth dyes

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Abstract

A sustainable approach for the manufacture of palladium (Pd) nanoparticles utilizing Morinda citrifolia leaf extract was established. The topological, crystallographic, and composition and structure of a UV–Vis spectrophotometer have been utilized to evaluate the generated nanoparticles, TEM, XRD, and FTIR investigations. The created nanoparticles underwent additional testing to see how well they removed the dyes rhodamine 6G (Rh-6 G), methyl orange, and Congo red. The generated Pd nanorods fully decolored nearly 99.9% of the Rh-6G dye in about 10 min. Greener fabrication for metallic nanoparticles has regularly been established, and cleaner and more effective nanorods for pollutant remediation have also been created. This study reveals the environmentally friendly synthesis of Pd NRs and its uses in environmental remediation.

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References

  • Ajitha B, Reddy YAK, Reddy PS (2015) Biosynthesis of silver nanoparticles using Momordica charantia leaf broth: evaluation of their innate antimicrobial and catalytic activities. J Photochem Photobiol B 146:1–9

    Article  CAS  PubMed  Google Scholar 

  • Akintelu SA, Olugbeko SC, Folorunso AS (2020) A review on synthesis, optimization, characterization and antibacterial application of gold nanoparticles synthesized from plants. Int Nano Lett 10:237–242

    Article  CAS  Google Scholar 

  • Amrutham S, Maragoni V, Guttena V (2020) One-step green synthesis of palladium nanoparticles using neem gum (Azadirachta indica): characterization, reduction of Rhodamine 6G dye and free radical scavenging activity. Appl Nanosci 10:4505–4511

    Article  CAS  Google Scholar 

  • Anand K, Kaviyarasu K, Muniyasamy S, Roopan SM, Gengan R, Chuturgoon A (2017) Biosynthesis of silver nanoparticles using agroforestry residue and their catalytic degradation for sustainable waste management. J Clust Sci 28:2279–2291

    Article  CAS  Google Scholar 

  • Arsiya F, Sayadi MH, Sobhani S (2017) Green synthesis of palladium nanoparticles using Chlorella vulgaris. Mat Lett 186:113–115

    Article  CAS  Google Scholar 

  • Atarod M, Nasrollahzadeh M, Sajadi SM (2016) Euphorbia heterophylla leaf extract mediated green synthesis of Ag/TiO2 nanocomposite and investigation of its excellent catalytic activity for reduction of variety of dyes in water. J Colloid Interf Sci 462:272

    Article  CAS  Google Scholar 

  • Attar A, AltikatogluYapaoz M (2018) Biosynthesis of palladium nanoparticles using Diospyros kaki leaf extract and determination of antibacterial efficacy. Prep Biochem Biotechnol 48(7):629–634

    Article  CAS  PubMed  Google Scholar 

  • Bonyadinejad G, Amin M, Mohammadi H, Nateghi R (2012) Decolorization of synthetic wastewaters by nickel oxide nanoparticle. Int J Environ Health Eng 1:25

    Article  Google Scholar 

  • Chen Xu GP, Rangaiahand X, Zhao S (2014) Photocatalytic degradation of methylene blue by titanium dioxide: experimental and modeling study. Ind Eng Chem Res 53:14641

    Article  Google Scholar 

  • Chen J, Wei D, Liu L, Nai J, Liu Y, Xiong Y et al (2021) Green synthesis of Konjac glucomannan templated palladium nanoparticles for catalytic reduction of azo compounds and hexavalent chromium. Mat Chem Phys 267:124651

    Article  CAS  Google Scholar 

  • Christina B, Thanigaimani K, Sudhakaran R, Mohan S, Arumugam N (2024) Pyto-Architechture of Ag, Au and Ag–Au bi-metallic nanoparticles using waste orange peel extract for enable carcinogenic Congo red dye degradation. Environ Res 242:117625

    Article  PubMed  Google Scholar 

  • Deepa T, Mohan S, Manimaran P (2022) A crucial role of selenium nanoparticles for future perspectives. Results Chem 4:100367

    Article  CAS  Google Scholar 

  • Dong P, Wang Y, Cao B, Xin S, Guo L, Zhang J et al (2013) Synthesis of Ag3PO4/Ag/g-C3N4 composite for enhanced photocatalytic degradation of methyl orange. Appl Catal B Environ 132:45

    Article  Google Scholar 

  • Elango G, Roopan SM (2015) Green synthesis, spectroscopic investigation and photocatalytic activity of lead nanoparticles. Spectrochim Acta Part A Mol Biomol Spectrosc 139:367–373

    Article  CAS  Google Scholar 

  • Francis S, Joseph S, Koshy EP, Mathew B (2017) Green synthesis and characterization of gold and silver nanoparticles using Mussaenda glabrata leaf extract and their environmental applications to dye degradation. Environ Sci Pollut Res 24(21):17347–17357

    Article  CAS  Google Scholar 

  • Gomathi M, Prakasam A, Rajkumar PV (2019) Green synthesis, characterization and antibacterial activity of silver nanoparticles using Amorphophallus paeoniifolius leaf extract. J Cluster Sci 30:995–1001

    Article  CAS  Google Scholar 

  • Gopalakrishnan R, Loganathan B, Dinesh S, Raghu K (2017) Strategic green synthesis, characterization and catalytic application to 4-nitrophenol reduction of palladium nanoparticles. J Clust Sci 28(4):2123–2131

    Article  CAS  Google Scholar 

  • Han Z, Dong L, Zhang J, Cui T, Chen S, Ma G et al (2019) Green synthesis of palladium nanoparticles using lentinan for catalytic activity and biological applications. RSC Adv 9(65):38265–38270

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Hatamifard A, Nasrollahzadeh M, Lipkowski J (2015) Green synthesis of a natrolite zeolite/palladium nanocomposite and its application as a reusable catalyst for the reduction of organic dyes in a very short time. RSC Adv 5(111):91372–91381

    Article  CAS  Google Scholar 

  • Hekmati M, Bonyasi F, Javaheri H, Hemmati S (2017) Green synthesis of palladium nanoparticles using Hibiscus sabdariffa L. flower extract: heterogeneous and reusable nanocatalyst in Suzuki coupling reactions. Appl Organomet Chem 31(11):e3757

    Article  Google Scholar 

  • Hong Y, Jing X, Huang J, Sun D, Odoom-Wubah T, Yang F et al (2014) Biosynthesized bimetallic Au–Pd nanoparticles supported on TiO2 for solvent-free oxidation of benzyl alcohol. ACS Sustain Chem Eng 2(7):1752–1759

    Article  CAS  Google Scholar 

  • Ismail E, Khenfouch M, Dhlamini M, Dube S, Maaza M (2017) Green palladium and palladium oxide nanoparticles synthesized via Aspalathus linearis natural extract. J Alloys Compd 695:3632–3638

    Article  CAS  Google Scholar 

  • Jeevanantham V, Tamilselvi D, Bavaji SR, Mohan S (2023) Green formulation of gold nanoparticles and their antioxidative assays, antimicrobial activity and photocatalytic colour decay. Bull Mater Sci 46(1):32

    Article  CAS  Google Scholar 

  • Kalaiselvi A, Roopan SM, Madhumitha G, Ramalingam C, Elango G (2015) Synthesis and characterization of palladium nanoparticles using Catharanthus roseus leaf extract and its application in the photo-catalytic degradation. Spectrochim Acta Part A Mol Biomol Spectrosc 135:116–119

    Article  CAS  Google Scholar 

  • Khodadadi B, Bordbar M, Nasrollahzadeh M (2017) Enhanced colloidal stability, solubility and rapid dissolution of resveratrol by nanocomplexation with soy protein isolate. J Colloid Interf Sci 493:85

    Article  CAS  Google Scholar 

  • Lakshmipathy R, Reddy BP, Sarada N, Chidambaram K, Pasha SK (2015) Watermelon rindmediated green synthesis of noble palladium nanoparticles: catalytic application. Appl Nanosci 5:223–228

    Article  CAS  Google Scholar 

  • Luo Y, Li J, Huang J (2016) A silver-nanoparticle/cellulose-nanofiber composite as a highly effective substrate for surface-enhanced Raman spectroscopy. Langmuir 32:123

    Google Scholar 

  • Mahalakshmi G, Elangovan K, Mohan S, Senthilkumar R (2022) A facile approach of pyto-synthesized Ag NPs on removal of organic pollutants for water remediation. J Iran Chem Soc 19(12):4601–4611

    Article  CAS  Google Scholar 

  • Mohan S, Devan MV (2019) Photocatalytic activity of Ag/Ni bi-metallic nanoparticles on textile dye removal. Green Process Synth 8(1):895–900

    Article  CAS  Google Scholar 

  • Nasrollahzadeh M, Sajadi SM, Maham M (2015) Green synthesis of palladium nanoparticles using Hippophaerhamnoides Linn. leaf extract and their catalytic activity for the Suzuki-Miyaura coupling in water. J Mol Catal A Chem 396:297–303

    Article  CAS  Google Scholar 

  • Nawahwi MZ, Ibrahim Z, Yahya A (2013) Degradation of the azo dye reactive red 195 by Paenibacillus spp. R2 J Bioremediat Biodegrad 4:174

    Google Scholar 

  • Perez-Rodriguez P, Maqueira Gonzalez C, Bennani Y, Rietveld LC, Zeman M, Smets AHM et al (2018) Green synthesis of Ag and Pd nanoparticles for water pollutants treatment. ACS Omega 3:14392

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Safari-Amiri M, Mortazavi-Derazkola S, Salavati-Niasari M, Ghoreishi SM (2017) Humidity sensor characteristics and electrical properties of Ni–Zn–Dy ferrite material prepared using different chelating-fuel agents. J Mater Sci Mater Electron 28:6467

    Article  CAS  Google Scholar 

  • Seku K, Gangapuram BR, Pejjai B, Kadimpati KK, Golla N (2018) Microwave-assisted synthesis of silver nanoparticles and their application in catalytic, antibacterial and antioxidant activities. J Nanostruct Chem 8:179–188

    Article  CAS  Google Scholar 

  • Selim A, Kaur S, Dar AH, Sartaliya S, Jayamurugan G (2020) Synergistic efects of carbon dots and palladium nanoparticles enhance the sonocatalytic performance for rhodamine B degradation in the absence of light. ACS Omega 5:22603–22613

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Shaik MR, Ali ZJQ, Khan M, Kuniyil M, Assal ME, Alkhathlan HZ, Al-Warthan A, Siddiqui MRH, Khan M, Adil SF (2017) Green synthesis and characterization of palladium nanoparticles using Origanum vulgare L. extract and their catalytic activity. Molecules 22:165–177

    Article  PubMed  PubMed Central  Google Scholar 

  • Shanmugam V, Mohan S, Manimaran P, Ravikumar K, Chandekar KV (2022) Hydrothermal development of a novel NiO/rGO nanocomposites for dual supercapacitor and photocatalytic applications. Mater Chem Phys 289:126425

    Article  CAS  Google Scholar 

  • Sherin L, Sohail A, Amjad U-S, Mustafa M, Jabeen R, Ul-Hamid A (2020) Facile green synthesis of silver nanoparticles using Terminalia bellerica kernel extract for catalytic reduction of anthropogenic water pollutants. Colloid Interface Sci Commun 37:100276

    Article  CAS  Google Scholar 

  • Sreekanth TVM, Jung MJ, Eom IY (2016) Green synthesis of silver nanoparticles, decorated on graphene oxide nanosheets and their catalytic activity. Appl Surf Sci 361:102–106

    Article  CAS  Google Scholar 

  • Surendra T, Roopan SM (2016) Photocatalytic and antibacterial properties of phyto-synthesized CeO2 NPs using Moringa oleifera peel extract. J Photochem Photobiol B Biol 161:122

    Article  CAS  Google Scholar 

  • Suvith V, Philip D (2014) Catalytic degradation of methylene blue using biosynthesized gold and silver nanoparticles. Spectrochim Acta Part A Mol Biomol Spectrosc 118:526–532

    Article  CAS  Google Scholar 

  • Umamaheswari C, Lakshmanan A, Nagarajan NS (2018) Green synthesis, characterization and catalytic degradation studies of gold nanoparticles against congo red and methyl orange. J Photochem Photobiol B 178:33–39

    Article  CAS  PubMed  Google Scholar 

  • Vasantham A, Thanigaimani K, Sudhakaran R, Mohan S, Arumugam N (2024) High Photo-Recombination of Z-Scheme h-BN @ ZnO/TiO2 Tube like Nanocrystal Towards Debasement of Toxic Organic Pollutants. Waste Biomass Valorization 1–12

  • Vidhu V, Philip D (2014) Spectroscopic, microscopic and catalytic properties of silver nanoparticles synthesized using Saraca indica flower. Spectrochim Acta Part A Mol Biomol Spectrosc 117:102–108

    Article  CAS  Google Scholar 

  • Yusoff N, Huang NM, Muhamad MR, Kumar SV, Lim HN, Harrison I et al (2013) Hydrothermal synthesis of CuO/functionalized graphene nanocomposites for dye degradation. Mater Lett 93:393

    Article  CAS  Google Scholar 

  • Yusuf M, Shahid M, Khan SA, Khan MI, Islam SU, Mohammad F, Khan MA (2013) Application of Terminalia chebula natural dye on wool fiber—evaluation of color and fastness properties. J Nat Fibers 10(1):14–28

    Article  CAS  Google Scholar 

  • Yusuf M, Shabbir M, Mohammad F (2017) Natural products and bioprospecting. Nat Color Histor Proces Sustain Prospects 7(1):123–145

    CAS  Google Scholar 

  • Zhang S, Liu X, Wang M, Wu B, Pan B, Yang H et al (2014a) Graphene oxide: a promising nanomaterial for energy and environmental applications. Environ Sci Technol Lett 1:196

    Article  Google Scholar 

  • Zhang P, Sui Y, Wang C, Wang Y, Cui G, Wang C et al (2014b) Porous hollow Co3O4 with rhombic dodecahedral structures for high-performance supercapacitor. Nanoscale 6:5343

    Article  CAS  PubMed  Google Scholar 

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Funding

The project was  funded by Researchers Supporting Project number (RSP2024R143), King Saud University, Riyadh, Saudi Arabia.

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Correspondence to G. Mahalakshmi.

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Mahalakshmi, G., Elangovan, K., Mohan, S. et al. Bio-reticulation of Pd nanorods enables catalytic treatment of various cloth dyes. Appl Nanosci 14, 807–818 (2024). https://doi.org/10.1007/s13204-024-03047-w

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