Abstract
Surface crystallization processes in the 80GeSe2–20Ga2Se3 glasses thermally annealed at 380 °C for 25 and 80 h were studied by both experimental methods and statistical analysis of images using Python scripts. It is shown that GeSe2 phase is formed as a result of annealing unevenly on glass surface in the form of thread-like crystallites with a length of 1–3 μm. The obtained dependences of number crystallites on their geometric parameters indicate a significant increase in their size (area, length and width) with an increase in the duration of annealing up to 80 h. At the same time, the crystallite growth orientation does not change and is 50°, 90° and 130°. Optimal conditions for crystallization processes can be selected based on the obtained results to prepare stable 80GeSe2–20Ga2Se3 glasses with predetermined optical properties.
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References
Abbady G, Abd-Elnaiem AM (2019) Thermal stability and crystallization kinetics of Ge13In8Se79 chalcogenide glass. Phase Transitions 92(7):667–682. https://doi.org/10.1080/01411594.2019.1619178
Adam JL, Calvez L, Trolès J, Nazabal V (2015) Chalcogenide glasses for infrared photonics. Int J Appl Glas Sci 6(3):287–294. https://doi.org/10.1111/ijag.12136
Atyia HE, Hegab NA (2021) Activation energy during the crystallization transition for Se-based chalcogenide glasses. Optik 243:167527. https://doi.org/10.1016/j.ijleo.2021.167527
Calvez L, Lin C, Rozé M, Ya L, Guillevic E, Bureau B, Allix M, Zhang X (2010) Similar behaviors of sulfide and selenide-based chalcogenide glasses to form glass-ceramics. Proc of SPIE 7598:759802-1–759816. https://doi.org/10.1117/12.840968
Cao Z, Dai S, Liu Z, Liu C, Ding S, Lin C (2021) Investigation of the acousto-optical properties of Ge–As–Te–(Se) chalcogenide glasses at 10.6 μm wavelength. J Am Ceram Soc 104(7):3224–3234. https://doi.org/10.1111/jace.17767
Choi JH, Lee JH, Choi YG, Kim JH, Kim HJ (2016) The relations between the mechanical properties and the nano crystalline in chalcogenide glass system. J Nanosci Nanotechnol 16(2):1603–1606. https://doi.org/10.1166/jnn.2016.11961
Dong G, Tao H, Xiao X, Lin C, Zhao X, Gu S (2007) Study of thermal and optical properties of GeS2–Ga2S3–Ag2S chalcogenide glasses. Mater Res Bull 42(10):1804–1810. https://doi.org/10.1016/j.materresbull.2006.12.003
Foster B (2007) AFM/Raman opens new horizons for research and industrial characterization. Am Lab 39(6):13
Gollapudi S, Gollapudi S (2019) OpenCV with Python. Learn Computer Vision Using OpenCV: With Deep Learning CNNs and RNNs, 31–50. https://doi.org/10.1007/978-1-4842-4261-2_2
Hassanien AS, Sharma I, Sharma P (2023 Inference of Sn addition on optical properties of the novel thermally evaporated thin a-Ge15Te50S35-xSnx films and some physical properties of their glasses. Materials Chemistry and Physics 293:126887. https://doi.org/10.1016/j.matchemphys.2022.126887
Hubert M, Calvez L, Zhang XH (2013) New chalcogenide glasses in the GeSe2–Ga2Se3–In2Se3 and GeSe2–Ga2Se3–PbSe domains. J Non-Cryst Solids 377:8–11. https://doi.org/10.1016/j.jnoncrysol.2013.02.005
Karbovnyk I, Bolesta I, Rovetskii I, Velgosh S, Klym H (2014) Studies of CdI2-Bi3 microstructures with optical methods, atomic force microscopy and positron annihilation spectroscopy. Mater Sci-Pol 32:391–395. https://doi.org/10.2478/s13536-014-0215-z
Karbovnyk I, Borshchyshyn I, Vakhula Y, Lutsyuk I, Klym H, Bolesta I (2016) Impedance characterization of Cr3+, Y3+ and Zr4+ activated forsterite nanoceramics synthesized by sol–gel method. Ceram Int 42(7):8501–8504. https://doi.org/10.1016/j.ceramint.2016.02.075
Kebaili I, Boukhris I, Alrowaili ZA, Abutalib MM, Al-Buriahi MS (2022) Characterization of physicochemical properties of As2Se3–GeTe–AgI chalcohalide glasses for solar cell and IR applications: influence of adding AgI. J Mater Sci: Mater Electron 33(2):800–809. https://doi.org/10.1007/s10854-021-07350-y
Keshari AK, Pandey AC (2008) Size and distribution: A Comparison of XRD, SAXS and SANS study of II–VI semiconductor nanocrystals. J Nanoscince and Nanotechnology 8:1221–1227. https://doi.org/10.1166/jnn.2008.370
Klapetek P, Yacoot A, Grolich P, Valtr M, Nečas D (2017) Gwyscan: a library to support non-equidistant scanning probe microscope measurements. Measurement Science and Technology 28(3):034015. https://doi.org/10.1016/j.fuel.2019.02.001
Klym H, Ingram A, Shpotyuk O, Calvez L, Petracovschi E, Kulyk B, Szatanik R (2015a) “Cold” crystallization in nanostructurized 80GeSe2-20Ga2Se3 glass. Nanoscale Res Lett 10:1–8. https://doi.org/10.1186/s11671-015-0775-9
Klym H, Ingram A, Shpotyuk O, Szatanik R (2015b) Free-volume study in GeS2-Ga2S3-CsCl chalcohalide glasses using positron annihilation technique. Phys Procedia 76:145–148. https://doi.org/10.1088/1757-899X/503/1/012020
Klym H, Ingram A, Shpotyuk O (2016a) Free-volume nanostructural transformation in crystallized GeS2–Ga2S3–CsCl glasses. Materialwiss Werkstofftech 47(2–3):198–202. https://doi.org/10.1002/mawe.201600476
Klym H, Ingram A, Shpotyuk O, Karbovnyk I (2016b) Influence of CsCl addition on the nanostructured voids and optical properties of 80GeS2-20Ga2S3 glasses. Opt Mater 59:39–42. https://doi.org/10.1016/j.optmat.2016.03.004
Klym H, Ingram A, Shpotyuk O, Hotra O, Popov AI (2016c) Positron trapping defects in free-volume investigation of Ge–Ga–S–CsCl glasses. Radiat Meas 90:117–121. https://doi.org/10.1016/j.radmeas.2016.01.023
Klym H, Karbovnyk I, Guidi MC, Hotra O, Popov AI (2016d) Optical and vibrational spectra of CsCl-enriched GeS2-Ga2S3 glasses. Nanoscale Res Lett 11:1–6. https://doi.org/10.1186/s11671-016-1350-8
Klym H, Karbovnyk I, Luchechko A, Kostiv Y, Pankratova V, Popov AI (2021a) Evolution of free volumes in polycrystalline BaGa2O4 ceramics doped with Eu3+ ions. Crystals 11(12):1515. https://doi.org/10.3390/cryst11121515
Klym H, Karbovnyk I, Piskunov S, Popov AI (2021b) Positron annihilation lifetime spectroscopy insight on free volume conversion of nanostructured MgAl2O4 ceramics. Nanomaterials 11(12):3373. https://doi.org/10.3390/nano11123373
Klym H, Karbovnyk I, Kostiv Y, Vasylchyshyn I (2018) Analysis of Crystallization Processes on the Surface of Ge-Ga-Se Glasses for Electronics and IR Photonics. In 2018 IEEE 38th International Conference on Electronics and Nanotechnology (ELNANO) pp. 152–155. https://doi.org/10.1109/ELNANO.2018.8477471
Klym H, Shpotyuk O, Karbovnyk I, Calvez L, Popov AI (2019) Structural investigation of crystallized Ge-Ga-Se chalcogenide glasses. In IOP Conference Series: Materials Science and Engineering 503(1):012020. https://doi.org/10.1088/1757-899X/503/1/012020
Klym H, Calvez L, Popov AI (2022) Free‐Volume Extended Defects in Structurally Modified Ge–Ga–S/Se Glasses. physica status solidi (b) 259(8):2100472. https://doi.org/10.1002/pssb.202100472
Kroon RE (2013) Nanoscience and the Scherrer equation versus the'Scherrer-Gottingen equation'. South African Journal of Science 109(5):1–2. https://hdl.handle.net/10520/EJC136410
Kumar A, Barman PB, Sharma R (2013) Crystallization kinetics of Ag-doped Se–Bi–Te chalcogenide glasses. J Therm Anal Calorim 114:1003–1013. https://doi.org/10.1007/s10973-013-3055-x
Lin C, Calvez L, Bureau B, Ledemi Y, Xu Y, Tao H, Zhao X (2010) Controllability study of crystallization on whole visible-transparent chalcogenide glasses of GeS2-Ga2S3-CsCl system. J Optoelectron Adv Mater 12(8):1684–1691
Lin C, Rüssel C, Dai S (2018) Chalcogenide glass-ceramics: functional design and crystallization mechanism. Prog Mater Sci 93:1–44. https://doi.org/10.1016/j.pmatsci.2017.11.001
Lucas P, Yang Z, Fah MK, Luo T, Jiang S, Boussard-Pledel C, Bureau B (2013) Telluride glasses for far infrared photonic applications. Optical Materials Express 3(8):1049–1058. https://doi.org/10.1364/OME.3.001049
Mao AW, Aitken BG, Youngman RE, Kaseman DC, Sen S (2013) Structure of glasses in the pseudobinary system Ga2Se3–GeSe2: violation of chemical order and 8-N coordination rule. J Phys Chem B 117(51):16594–16601. https://doi.org/10.1021/jp410017k
Mikla VI, Mikla VV (2009) Structural transformations in amorphous Asx Se1−x (0≤ x≤ 0.20) films. J Mater Sci: Mater Electron 20:1095–1105. https://doi.org/10.1007/s10854-008-9833-8
Nazabal V, Adam JL (2022). Infrared luminescence of chalcogenide glasses doped with rare earth ions and their potential applications. Optical Materials: X 15:100168. https://doi.org/10.1016/j.omx.2022.100168
Nečas D, Klapetek P (2012) Gwyddion: an open-source software for SPM data analysis. Open Physics 10(1):181–188. https://doi.org/10.2478/s11534-011-0096-2
Patra, P, Annapurna K (2022). Transparent tellurite glass-ceramics for photonics applications: A comprehensive review on crystalline phases and crystallization mechanisms. Progress in Materials Science, 125, 100890. https://doi.org/10.1016/j.pmatsci.2021.100890
Petracovschi E, Calvez L, Cormier L, Le Coq D, Du J (2018) Short and medium range structures of 80GeSe2–20Ga2Se3 chalcogenide glasses. Journal of Physics: Condensed Matter 30(18):185403. https://doi.org/10.1088/1361-648X/aaaf36
Savchyn VP, Popov AI, Aksimentyeva OI, Klym H, Horbenko YY, Serga V, Karbovnyk I (2016) Cathodoluminescence characterization of polystyrene-BaZrO3 hybrid composites. Low Temperature Physics 42(7):597–600. https://doi.org/10.1063/1.4959020
Shen X, Nie Q, Xu T, Dai S, Wang X, Chen F (2009) Crystallization behavior of GeSe2–Ga2Se3–CsI glasses studied by differential thermal analysis. Physica B 404(2):223–226. https://doi.org/10.1016/j.physb.2008.10.024
Shen X, Chen F, Lv X, Dai S, Wang X, Zhang W, Heo J (2011) Preparation and third-order optical nonlinearity of glass ceramics based on GeS2–Ga2S3–CsCl pseudo-ternary system. J Non-Cryst Solids 357(11–13):2316–2319. https://doi.org/10.1016/j.jnoncrysol.2011.01.019
Shpotyuk O, Calvez L, Petracovschi E, Klym H, Ingram A, Demchenko P (2014) Thermally-induced crystallization behaviour of 80GeSe2–20Ga2Se3 glass as probed by combined X-ray diffraction and PAL spectroscopy. J Alloy Compd 582:323–327. https://doi.org/10.1016/j.jallcom.2013.07.127
Svoboda R (2019) Oxidation-influenced crystallization in (GeSe2)x(Sb2Se3)1–x chalcogenide glasses. J Non-Cryst Solids 510:6–14. https://doi.org/10.1016/j.jnoncrysol.2019.01.020
Tang G, Yang Z, Luo L, Chen W (2008) Formation and properties of GeSe2–Ga2Se3–PbI2 novel chalcohalide glasses. J Am Ceram Soc 91(5):1686–1689. https://doi.org/10.1111/j.1551-2916.2008.02321.x
Tostanoski NJ, Heilweil EJ, Wachtel PF, Musgraves JD, Sundaram SK (2023) Structure-terahertz property relationship and femtosecond laser irradiation effects in chalcogenide glasses. Journal of Non-Crystalline Solids 600:122020. https://doi.org/10.1016/j.jnoncrysol.2022.122020
Villán AF (2019) Mastering OpenCV 4 with Python: a practical guide covering topics from image processing, augmented reality to deep learning with OpenCV 4 and Python 3.7. Packt Publishing Ltd.
Wang H, Zhang X, Yang G, Xu Y, Ma H, Adam JL, Chen G (2009) Micro-crystallization of the infrared transmitting chalcogenide glass in GeSe2–As2Se3–PbSe system. Ceram Int 35(1):83–86. https://doi.org/10.1016/j.ceramint.2007.09.115
Wang S, Zhang F, Yang Q, Li M, Hou X, Chen F (2023) Chalcogenide glass IR artificial compound eyes based on femtosecond laser microfabrication. Adv Mater Technol 8(2):2200741. https://doi.org/10.1002/admt.202200741
Zakery A, Elliott SR (2003) Optical properties and applications of chalcogenide glasses: a review. J Non-Cryst Solids 330(1–3):1–12. https://doi.org/10.1016/j.jnoncrysol.2003.08.064
Zha Y, Waldmann M, Arnold CB (2013) A review on solution processing of chalcogenide glasses for optical components. Opt Mater Express 3(9):1259–1272. https://doi.org/10.1364/OME.3.001259
Acknowledgements
This research was supported by the Ministry of Education and Science of Ukraine under Project No 0122U000807 and the National Research Foundation of Ukraine under Project 2020.02/017 “Light-generation low-dimensional structures with polarized luminescence based on organic and inorganic materials.” H.K. thanks to Dr. L. Calvez for sample preparation, Dr. B. Kulyk for assistance in AFM experiment and Prof. O. Shpotyuk for discussion.
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Klym, H., Kushnir, O. & Karbovnyk, I. Surface crystallization of GeSe2 in the 80GeSe2–20Ga2Se3 glasses caused by thermal annealing: experimental study and statistical analysis. Appl Nanosci 13, 7445–7454 (2023). https://doi.org/10.1007/s13204-023-02910-6
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DOI: https://doi.org/10.1007/s13204-023-02910-6