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Synthesis of magnetic g-C3N4/NiFe2O4 nanocomposites for enhanced visible-light photocatalytic performance

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Abstract

A magnetically separable photocatalytic g-C3N4/NiFe2O4 nanocomposite was obtained via a two-step method. In the first step, the magnetic NiFe2O4 nanoparticles were acquired in a few minutes by ionic liquid self-combustion approach which significantly reduced the synthesis time of nanocomposites. Besides, the research of g-C3N4/NiFe2O4 nanocomposites for the visible-light-driven degradation of methylene blue in the absence of H2O2 was detailed. Compared with pure g-C3N4 and NiFe2O4, the as-prepared nanocomposites with NiFe2O4 doping of 12% manifested the enhanced photocatalytic activity and stability after three cycles for degrading methylene blue, and the photocatalytic process followed first-order reaction kinetics. Trapping experiments demonstrated that the H+ and OH• scavengers are the main active species and O2•− has a small effect for visible-light-driven degradation of methylene blue.

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References

  • Beydoun B, Amal R, Low GKC, McEvoy S (2000) Novel photocatalyst: titania-coated magnetite. Activity and photodissolution. J Phys Chem B 104:4387–4396

    CAS  Google Scholar 

  • Booshehri AY, Polo-Lopez MI, Castro-Alférez M, He PF, Xu R, Rong W, Malato S, Fernández-Ibánez P (2017) Assessment of solar photocatalysis using Ag/BiVO4 at pilot solar compound parabolic collector for inactivation of pathogens in well water and secondary effluents. Catal Today 281:124–134

    CAS  Google Scholar 

  • Chen Y, Lin B, Wang H, Zhu HB, Wl Yu, Basset J (2016) Surface modification of g-C3N4 by hydrazine: simple way for noble-metal free hydrogen evolution catalysts. Chem Eng J 286:339–346

    CAS  Google Scholar 

  • Chen XD, Chao M, Yong W, Zhao QQ, Li YJ, Chen XM, Yang DW, Li YX, Zhou Y (2020) Laser-synthesized rutile TiO2 with abundant oxygen vacancies for enhanced solar water evaporation. ACS Sustain Chem Eng 8:1095–1101

    CAS  Google Scholar 

  • Chidhambaram N, Ravichandran K (2017) Single step transformation of urea into metal-free g-C3N4 nanoflakes for visible light photocatalytic applications. Mater Lett 207:44–48

    CAS  Google Scholar 

  • Fang JJ, Chen YK, Wang W, Fang L, Lu CH, Zhu C, Kou JH, Ni YR, Xu ZZ (2019) Highly efficient photocatalytic hydrogen generation of g-C3N4–CdS sheets based on plasmon-enhanced triplet–triplet annihilation upconversion. Appl Catal B Environ 258:117762

    CAS  Google Scholar 

  • Fu JW, Yu JG, Jiang CJ, Cheng B (2018) g-C3N4-based heterostructured photocatalysts. Adv Energy Mater 8:1701503

    Google Scholar 

  • Gao SW, Low JX, Yu JG, Jaroniec M (2015) Polymeric photocatalysts based on graphitic carbon nitride. Adv Mater 27:2150–2176

    Google Scholar 

  • Gao ZW, Liu JY, Chen XM, Zheng XL, Jing M, Liu H, Ma T, Li L, Wang WC, Du XW (2019a) Engineering NiO/NiFe LDH intersection to bypass scaling relationship for oxygen evolution reaction via dynamic tridimensional adsorption of intermediates. Adv Mater 31:1804769

    Google Scholar 

  • Gao XC, Wang WL, Bi JQ, Chen YF, Hao XX, Sun XN, Zhang JD (2019b) Morphology-controllable preparation of NiFe2O4 as high performance electrode material for supercapacitor. Electrochim Acta 296:181–189

    CAS  Google Scholar 

  • Han F, Kambala VSR, Srinivasan M, Rajarathnam D, Naidu R (2009) Tailored titanium dioxide photocatalysts for the degradation of organic dyes in wastewater treatment: a review. Appl Catal A Gen 359:25–40

    CAS  Google Scholar 

  • Hassani A, Eghbali P, Ekicibil A, Metin Ö (2018) Monodisperse cobalt ferrite nanoparticles assembled on mesoporous graphitic carbon nitride (CoFe2O4/mpg-C3N4): a magnetically recoverable nanocomposite for the photocatalytic degradation of organic dyes. J Magn Mater 456:400–412

    CAS  Google Scholar 

  • Hu JS, Zhang PF, An WJ, Liu L, Liang YH, Cui WQ (2019) In-situ Fe-doped g-C3N4 heterogeneous catalyst via photocatalysis-Fenton reaction with enriched photocatalytic performance for removal of complex wastewater. Appl Catal B Environ 245:130–143

    CAS  Google Scholar 

  • Huang SQ, Xu YG, Xie M, Xu H, He MQ, Xia JX, Huang LY, Li HM (2015) Synthesis of magnetic CoFe2O4/g-C3N4 composite and its enhancement of photocatalytic ability under visible-light. Colloid Surf A Physicochem Eng Aspects 478:71–80

    CAS  Google Scholar 

  • Ji HY, Jing XC, Xu YG, Yan J, Li HP, Li YP, HuangZhangXu LYQH, Li HM (2015) Magnetic g-C3N4/NiFe2O4 hybrids with enhanced photocatalytic activity. RSC Adv 5:57960–57967

    CAS  Google Scholar 

  • Kumar ST, Kumar B, Baruah A, Shanker V (2013) Synthesis of magnetically separable and recyclable g-C3N4–Fe3O4 hybrid nanocomposites with enhanced photocatalytic performance under visible-light irradiation. J Phys Chem C 117:26135–26143

    CAS  Google Scholar 

  • Lam SM, Sin JC, Mohamed AR (2016) A review on photocatalytic application of g-C3N4/semiconductor (CNS) nanocomposites towards the erasure of dyeing wastewater. Mater Sci Semicond Process 47:62–84

    CAS  Google Scholar 

  • Lee KM, Lai CW, Ngai KS, Juan JC (2016) Recent developments of zinc oxide based photocatalyst in water treatment technology: a review. Water Res 88:428–448

    CAS  Google Scholar 

  • Lei H, Zhang HH, Zou Y, Ding XP, Jia YM, Wang FF (2019) Synergetic photocatalysis/piezocatalysis of bismuth oxybromide for degradation of organic pollutants. J Alloy Compd 809:151840

    CAS  Google Scholar 

  • Li F, Liu Y, Sun ZM, Liu Rh, Kou CG, Zhao Y, Zhao DS (2011) Facile preparation of porous LaFeO3 nanomaterial by self-combustion of ionic liquids. Mater Lett 65:406–408

    CAS  Google Scholar 

  • Li FT, Wang Q, Wang XJ, Li B, Hao YJ, Liu RH, Zhao DS (2014) In-situ one-step synthesis of novel BiOCl/Bi24O31Cl10 heterojunctions via self-combustion of ionic liquid with enhanced visible-light photocatalytic activities. Appl Catal B Environ 150:574–584

    Google Scholar 

  • Li FT, Ran JR, Jaroniec M, Qiao SZ (2015) Solution combustion synthesis of metal oxide nanomaterials for energy storage and conversion. Nanoscale 7:17590–17610

    CAS  Google Scholar 

  • Li X, Shen D, Liu C, Li JZ, Zhou YJ, Song XH, Huo PW, Wang HQ, Yan YS (2019) Fabricated rGO-modified Ag2S nanoparticles/g-C3N4 nanosheets photocatalyst for enhancing photocatalytic activity. J Colloid Interface Sci 554:468–478

    CAS  Google Scholar 

  • Liu L, Qi YH, Lu JR, Lin SL, An WJ, Liang YH, Cui WQ (2016) A stable Ag3PO4@g-C3N4 hybrid core@shell composite with enhanced visible light photocatalytic degradation. Appl Catal B Environ 183:133–141

    CAS  Google Scholar 

  • Liu X, Jin AL, Jia YS, Tl X, Deng CX, Zhu MH, Chen CF, Chen XS (2017) Synergy of adsorption and visible-light photocatalytic degradation of methylene blue by a bifunctional Z-scheme heterojunction of WO3/g-C3N4. Appl Surf Sci 405:359–371

    CAS  Google Scholar 

  • Liu Y, Song YC, You YH, Fu XJ, Wen J, Zheng XG (2018) NiFe2O4/g-C3N4 heterojunction composite with enhanced visible-light photocatalytic activity. J Saudi Chem Soc 22:439–448

    CAS  Google Scholar 

  • Mao J, Chen XM, Du XW (2016) Facile synthesis of three dimensional CdS nanoflowers with high photocatalytic performance. J Alloy Compd 656:972–977

    CAS  Google Scholar 

  • Miao XL, Yue XY, Ji ZY, Shen XP, Zhou H, Liu MM, Xu KQ, Zhu J, Zhu GX, Kong L, Shah SA (2018) Nitrogen-doped carbon dots decorated on g-C3N4/Ag3PO4 photocatalyst with improved visible light photocatalytic activity and mechanism insight. Appl Catal B Environ 227:459–469

    CAS  Google Scholar 

  • Moreira NFF, Sampaio MJ, Ribeiro R, Silva CG, Faria JL, Silva AMT (2019) Metal-free g-C3N4 photocatalysis of organic micropollutants in urban wastewater under visible light. Appl Catal B Environ 248:184–192

    CAS  Google Scholar 

  • Oseghe EO, Ofomaja AE (2018) Facile microwave synthesis of pine cone derived C-doped TiO2 for the photodegradation of tetracycline hydrochloride under visible-LED light. J Environ Manag 223:860–867

    CAS  Google Scholar 

  • Padervand M (2016) Visible-light photoactive Ag-AgBr/α-Ag3VO4 nanostructures prepared in a water-soluble ionic liquid for degradation of wastewater. Appl Nanosci 6:1119–1126

    CAS  Google Scholar 

  • Palanivel B, Ayappan C, Jayaraman V, Chidambaram S, Maheswaran R, Mani A (2019) Inverse spinel NiFe2O4 deposited g-C3N4 nanosheet for enhanced visible light photocatalytic activity. Mater Sci Semicond Process 100:87–97

    CAS  Google Scholar 

  • Samadi M, Zirak M, Naseri A, Kheirabadi M, Ebrahimi M, Moshfegh AZ (2019) Design and tailoring of one-dimensional ZnO nanomaterials for photocatalytic degradation of organic dyes: a review. Res Chem Intermediat 45:2197–2254

    CAS  Google Scholar 

  • Shi L, Zhao KM, Liu SQ (2018) Photocatalytic degradation of MO and phenol over novel β-CoOOH/g-C3N4 composite under visible light irradiation. Mater Lett 228:121–124

    CAS  Google Scholar 

  • Turkyilmazoglu M (2019a) Free and circular jets cooled by single phase nanofluids. Eur J Mech B Fluid 76:1–6

    Google Scholar 

  • Turkyilmazoglu M (2019b) Fully developed slip flow in a concentric annuli via single and dual phase nanofluids models. Comput Methods Progr Biomed 179:104997

    Google Scholar 

  • Vadivel S, Maruthamani D, Habibi-Yangjeh A, Paul B, Dhar SS, Selvam K (2016) Facile synthesis of novel CaFe2O4/g-C3N4 nanocomposites for degradation of methylene blue under visible-light irradiation. J Colloid Interface Sci 480:126–136

    CAS  Google Scholar 

  • Wang XC, Maeda K, Thomas A, Takanabe K, Xin G, Carlsson JM, Domen K, Antonietti M (2009) A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat Mater 8:76–80

    CAS  Google Scholar 

  • Wang XC, Blechert S, Antonietti M (2012) Polymeric graphitic carbon nitride for heterogeneous photocatalysis. ACS Catal 2:1596–1606

    Google Scholar 

  • Wang HH, Peng DL, Hu XF, Ma XG, Ye WH, Zhang WH, Chang Y, Dong SJ (2018) Target preparation of multicomponent composites Au@CdS/g-C3N4 as efficient visible light photocatalysts with the assistance of biomolecules. Mater Res Bull 108:176–186

    CAS  Google Scholar 

  • Wu FJ, Li X, Liu W, Zhang ST (2017) Highly enhanced photocatalytic degradation of methylene blue over the indirect all-solid-state Z-scheme g-C3N4–RGO–TiO2 nanoheterojunctions. Appl Surf Sci 405:60–70

    CAS  Google Scholar 

  • Ye S, Qiu LG, Yuan YP, Zhu YJ, Xia J, Zhu JF (2013) Facile fabrication of magnetically separable graphitic carbon nitride photocatalysts with enhanced photocatalytic activity under visible light. J Mater Chem A 1:3008

    CAS  Google Scholar 

  • Ye LQ, Wu D, Chu KH, Wang B, Xie HQ, Yip HY, Wong PK (2016) Phosphorylation of g-C3N4 for enhanced photocatalytic CO2 reduction. Chem Eng J 304:376–383

    CAS  Google Scholar 

  • Yu JG, Yu XX (2008) Hydrothermal synthesis and photocatalytic activity of zinc oxide hollow spheres. Environ Sci Technol 42:4902–4907

    CAS  Google Scholar 

  • Zhang L, Wong KH, Zhang DQ, Hu C, Yu JC, Chan QY, Wong PK (2009) Zn:In(OH)ySz solid solution nanoplates: synthesis, characterization, and photocatalytic mechanism. Environ Sci Technol 43:7883–7888

    CAS  Google Scholar 

  • Zhao Y, Yuan M, Chen Y, YanXu JL, Huang YP, Lian JB, Bao J, Qiu JX, Xu L, Xu YG, Xu H, Li HM (2018) Construction of molybdenum dioxide nanosheets coated on the surface of nickel ferrite nanocrystals with ultrahigh specific capacity for hybrid supercapacitor. Electrochim Acta 206:439–448

    Google Scholar 

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Acknowledgements

The authors gratefully acknowledge the financial support of the Natural Science Foundation of Hebei Province, China (Grant no. B2018208090), Young Talents Program in University of Hebei Province, China (no. BJ2019002), the National Natural Science Foundation of China (Grant no. 51802075, 51901115), and the Shandong Provincial Natural Science Foundation, China (ZR2019PEM001 and ZR2019BB009).

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Authors and Affiliations

  1. College of Science, Hebei University of Science and Technology, Shijiazhuang, 050018, China

    Xuemin Chen, Mingli He, Guangyuan He & Jie Ren

  2. Key Laboratory for Robot and Intelligent Technology of Shandong Province, Shandong University of Science and Technology, No.579 Qianwangang Road, Huangdao District, Qingdao, 266590, China

    Yue Zhou & Chao Meng

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  1. Xuemin Chen
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Chen, X., He, M., He, G. et al. Synthesis of magnetic g-C3N4/NiFe2O4 nanocomposites for enhanced visible-light photocatalytic performance. Appl Nanosci 10, 4465–4473 (2020). https://doi.org/10.1007/s13204-020-01362-6

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