Abstract
Effects of geographical origin of Coffee Arabica beans (Brazil, Colombia and Peru), roasting degree, particle size and different brewing methods (French press, chemex and cold brew) on physicochemical and spectral properties of coffee samples were investigated in this study. Analyses of pH, total phenolic content (TPC) and total antioxidant activity (TA), UV and fluorescence spectroscopy measurements were performed. Principal component analysis (PCA) was used to obtain the most effective parameters on chemical changes. Results indicated that the increase of roasting degree caused decrements in the intensities of UV-spectra because of the degradation of trigonelline and chlorogenic acid molecules while counterpart trend was observed in the fluorescence spectra due to formation of fluorescence Maillard reaction products (MRP) during roasting. French press and cold brew methods caused similar TPC (1873.33–3818.33 and 2648.88–3824.44 μg/mL gallic acid equivalent, respectively) and TA (0.18–0.32 and 0.16–0.27 μmol/mL Trolox equivalent, respectively) values whereas chemex method showed different physicochemical properties (TPC: 1008.88–3543.88 μg/mL gallic acid equivalent and TA: 0.08–0.26 μmol/mL Trolox equivalent). Roasting degree and brewing method—compared to other parameters—were the most discriminating factors on the basis of UV spectra and fluorescence spectra of coffee brew samples, respectively. All roasting degrees could be distinguished with the rate of 71.42% on PC1 and 23.45% on PC2 of total variance according to UV-spectra while chemex and French press-cold brew methods could be differentiated with the rate of 97.24% on PC1 and 1.79% on PC2 of total variance based on fluorescence spectra on PCA score graphs.
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References
Adrian J, Frangne R (1991) Synthesis and availability of niacin in roasted coffee. In: Friedman M (ed) Nutritional and toxicological consequences of food processing. Springer, Berlin, pp 49–59
Ahmed M, Jiang GH, Park JS, Lee KC, Seok YY, Eun JB (2019) Effects of ultrasonication, agitation and stirring extraction techniques on the physicochemical properties, health-promoting phytochemicals and structure of cold-brewed coffee. J Sci Food Agric 99(1):290–301
Akgün B, Arıcı MJ (2019) Evaluation of acrylamide and selected parameters in some Turkish coffee brands from the Turkish market. Food Addit Contam Part A 36(4):548–560
Andrzejewski D, Roach JA, Gay ML, Musser SM (2004) Analysis of coffee for the presence of acrylamide by LC-MS/MS. J Agric Food Chem 52(7):1996–2002
Angeloni G, Guerrini L, Masella P, Innocenti M, Bellumori M, Parenti A (2019) Characterization and comparison of cold brew and cold drip coffee extraction methods. J Sci Food Agric 99(1):391–399
Babova O, Occhipinti A, Maffei ME (2016) Chemical partitioning and antioxidant capacity of green coffee (Coffea arabica and Coffea canephora) of different geographical origin. Phytochemistry 123:33–39. https://doi.org/10.1016/j.phytochem.2016.01.016
Barbin DF, Felicio ALDSM, Sun D-W, Nixdorf SL, Hirooka EY (2014) Application of infrared spectral techniques on quality and compositional attributes of coffee: an overview. Food Res Int 61:23–32
Belay A, Gholap A (2009) Characterization and determination of chlorogenic acids (CGA) in coffee beans by UV–Vis spectroscopy. Afr J Pure Appl Chem 3(11):34–240
Bertone E, Venturello A, Giraudo A, Pellegrino G, Geobaldo FJFC (2016) Simultaneous determination by NIR spectroscopy of the roasting degree and Arabica/Robusta ratio in roasted and ground coffee. Food Control 59:683–689
Bhumiratana N, Adhikari K, Chambers E (2011) Evolution of sensory aroma attributes from coffee beans to brewed coffee. LWT Food Sci Technol 44(10):2185–2192. https://doi.org/10.1016/j.lwt.2011.07.001
Blumberg S, Frank O, Hofmann T (2010) Quantitative studies on the influence of the bean roasting parameters and hot water percolation on the concentrations of bitter compounds in coffee brew. J Agric Food Chem 58(6):3720–3728
Bona E, Marquetti I, Link JV, Makimori GY, da Costa AV, Lemes AL, Ferreira JM, dos Santos Scholz MB, Valderrama P, Poppi RJ (2017) Support vector machines in tandem with infrared spectroscopy for geographical classification of green arabica coffee. LWT Food Sci Technol 76:330–336
Brand-Williams W, Cuvelier ME, Berset CL (1995) Use of a free radical method to evaluate antioxidant activity. LWT Food Sci Technol 28(1):25–30
Chu B, Yu K, Zhao Y, He YJS (2018) Development of noninvasive classification methods for different roasting degrees of coffee beans using hyperspectral imaging. Sensors 18(4):1259
Cordoba N, Pataquiva L, Osorio C, Moreno FLM, Ruiz RY (2019) Effect of grinding, extraction time and type of coffee on the physicochemical and flavour characteristics of cold brew coffee. Sci Rep 9(1):8440
Craig AP, Fields C, Liang N, Kitts D, Erickson AJT (2016) Performance review of a fast HPLC-UV method for the quantification of chlorogenic acids in green coffee bean extracts. Talanta 154:481–485
Dankowska A, Domagała A, Kowalewski W (2017) Quantification of Coffea arabica and Coffea canephora var. robusta concentration in blends by means of synchronous fluorescence and UV–Vis spectroscopies. Talanta 172:215–220. https://doi.org/10.1016/j.talanta.2017.05.036
de Moura Ribeiro MV, Boralle N, Pezza HR, Pezza L, Toci AT (2017) Authenticity of roasted coffee using 1H NMR spectroscopy. J Food Compos Anal 57:24–30
Farah A, Donangelo CM (2006) Phenolic compounds in coffee. Braz J Plant Physiol 18(1):23–36
Fibrianto K, Wulandari ES, Jovino A, Rahmawati MA, Wandani NC, Fibrianti S, Waziiroh E, Yuwono SS (2019). Brewing time and temperature optimization of Robusta Dampit Coffee on several drip techniques. Paper presented at the IOP Conference Series: Earth and Environmental Science
Fuller M, Rao NZ (2017) The effect of time, roasting temperature, and grind size on caffeine and chlorogenic acid concentrations in cold brew coffee. Sci Rep 7(1):17979
Giraudo A, Grassi S, Savorani F, Gavoci G, Casiraghi E, Geobaldo F (2019) Determination of the geographical origin of green coffee beans using NIR spectroscopy and multivariate data analysis. Food Control 99:137–145. https://doi.org/10.1016/j.foodcont.2018.12.033
Illy A, Viani R (2005) Espresso coffee: the science of quality. Academic Press, Cambridge
Magalhães LM, Machado S, Segundo MA, Lopes JA, Páscoa RNJT (2016) Rapid assessment of bioactive phenolics and methylxanthines in spent coffee grounds by FT-NIR spectroscopy. Talanta 147:460–467
Matiacevich SB, Santagapita PR, Buera MP (2005) Fluorescence from the Maillard reaction and its potential applications in food science. Crit Rev Food Sci Nutr 45(6):483–495
Moon J-K, Yoo HS, Shibamoto T (2009) Role of roasting conditions in the level of chlorogenic acid content in coffee beans: correlation with coffee acidity. J Agric Food Chem 57(12):5365–5369
Navarra G, Moschetti M, Guarrasi V, Mangione M, Militello V, Leone M (2017) Simultaneous determination of caffeine and chlorogenic acids in green coffee by UV/Vis spectroscopy. J Chem 2017:1–8
Rao NZ, Fuller M (2018) Acidity and antioxidant activity of cold brew coffee. Sci Rep 8(1):16030
Wolska J, Janda K, Jakubczyk K, Szymkowiak M, Chlubek D, Gutowska I (2017) Levels of antioxidant activity and fluoride content in coffee infusions of arabica, robusta and green coffee beans in according to their brewing methods. Biol Trace Elem Res 179(2):327–333
Yisak H, Redi-Abshiro M, Chandravanshi BS (2018) New fluorescence spectroscopic method for the simultaneous determination of alkaloids in aqueous extract of green coffee beans. Chem Cent J 12(1):1–7
Zhang C, Linforth R, Fisk ID (2012) Cafestol extraction yield from different coffee brew mechanisms. Food Res Int 49(1):27–31
Zhang C, Shen T, Liu F, He YJS (2018) Identification of coffee varieties using laser-induced breakdown spectroscopy and chemometrics. Sensors 18(1):95
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Author would like to thank Mr. Cafer Soydan for roasting of coffee beans, Prof. Dr. Sencer Buzrul for critical reading of the manuscript and Dr. Ezgi Aytac for experimental support.
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Bilge, G. Investigating the effects of geographical origin, roasting degree, particle size and brewing method on the physicochemical and spectral properties of Arabica coffee by PCA analysis. J Food Sci Technol 57, 3345–3354 (2020). https://doi.org/10.1007/s13197-020-04367-9
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DOI: https://doi.org/10.1007/s13197-020-04367-9