Abstract
The radicals and high temperatures generated by the Oxyhydrogen flame induce new reactions. This paper reports on the treatment of saturated chloride solutions with Oxyhydrogen flame. The results show that the oxyhydrogen flame can promote the hydrolysis definitely, including strong acid and strong alkali salts like NaCl and KCl. The extent and product of the hydrolysis depends on the Lewis acidity and hardness of the metal ions in the chlorides. The higher is the Lewis acidity of metal ions, and the higher is the extent of hydrolysis, thus the efficiency of oxyhydrogen flame (EH) of AlCl3 is the highest, up to 2.95%, as Al3+ is the strongest Lewis acid. Soft metals tend to produce basic chloride, and the harder ones prefer the oxides, carbonates or hydroxides. Through the exploration of this paper the authors believe that the hydroxide flame can be a universal method for treating any kind of chemical waste.
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The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.
References
State Council Accident Investigation Team of the People's Republic of China. Investigation report on“3•21” especially serious explosion accident of jiangsu xiangshui tianjiayi chemical co., LTD, https://www.mem.gov.cn/gk/sgcc/tbzdsgdcbg/2019tbzdsgcc/201911/P020191115565111829069.pdf; (2019). Accessed Nov 2019.
Central Committee General Office of the Communist Party of China, State Council General Office of the People’s Republic of China. The opinion of comprehensively strengthening hazardous chemicals safe production, http://www.gov.cn/zhengce/2020-02/26/content_5483625.htm; 2020. Accessed Feb 2020.
Bhowmick, G.D., Sarmah, A.K., Sen, R.: Zero-waste algal biorefinery for bioenergy and biochar: a green leap towards achieving energy and environmental sustainability. Sci Total Environ. 650, 2467–2482 (2019). https://doi.org/10.1016/j.scitotenv.2018.10.002
Cheng, H.H., Liu, C.B., Lei, Y.Y., Chiu, Y.C., Mangalindan, J., Wu, C.H., et al.: Biological treatment of DMSO-containing wastewater from semiconductor industry under aerobic and methanogenic conditions. Chemosphere. 236, 124291 (2019). https://doi.org/10.1016/j.chemosphere.2019.07.022
Kang, Y., Jang, J., Kim, S., Lim, J., Lee, Y., Kim, I.S.: PIP/TMC interfacial polymerization with electrospray: novel loose nanofiltration membrane for dye wastewater treatment. ACS Appl. Mater. Inter. 12, 36148–36158 (2020). https://doi.org/10.1021/acsami.0c09510
Xu, H., Yuan, H.F., Yu, J.G., Lin, S.: Study on the competitive adsorption and correlational mechanism for heavy metal ions using the carboxylated magnetic iron oxide nanoparticles (MNPs-COOH) as efficient adsorbents. Appl. Surf. Sci. 473, 960–966 (2019). https://doi.org/10.1016/j.apsusc.2018.12.006
Dai, C.M., Geissen, S.U., Zhang, Y.L., Zhang, Y.J., Zhou, X.F.: Selective removal of diclofenac from contaminated water using molecularly imprinted polymer microspheres. Environ. Pollut. 159(6), 1660–1666 (2011). https://doi.org/10.1016/j.envpol.2011.02.041
Ren, R.Y., Yang, L.H., Han, J.L., Cheng, H.Y., Ajibade, F.O., Guadie, A., et al.: Perylene pigment wastewater treatment by fenton-enhanced biological process. Environ. Res. 186, 109522 (2020). https://doi.org/10.1016/j.envres.2020.109522
Wang, L., Yang, J., Li, Y.M., Lv, J., Li, G.C.: Oxidation of N-nitrosodimethylamine in a heterogeneous nanoscale zero-valent iron/H2O2 Fenton-like system: influencing factors and degradation pathway. J. Chem. Technol. Biot. 92(3), 542–551 (2017). https://doi.org/10.1002/jctb.5033
Li, W., Xu, L.J.: Research methods for the degradation mechanism of organic pollutants in wastewater. Acta Chim. Sinica. 77, 705–716 (2019). https://doi.org/10.6023/A19030073
Costa, A.J.M.D., Kronka, M.S., Cordeiro-Junior, P.J.M., Fortunato, G.V., Santos, A.J.D., Lanza, M.R.V.: Treatment of tebuthiuron in synthetic and real wastewater using electrochemical flow-by reactor. J. Electroanal. Chem. 882, 114978 (2021). https://doi.org/10.1016/j.jelechem.2021.114978
Narayanan, C.M., Narayan, V.: Biological wastewater treatment and bioreactor design: a review. Sustain. Environ. Res. 29, 33 (2019). https://doi.org/10.1186/s42834-019-0036-1
Khalidi-idrissi, A., Madinzi, A., Anouzla, A., Pala, A., Mouhir, L., Kadmi, Y., Souabi, S.: Recent advances in the biological treatment of wastewater rich in emerging pollutants produced by pharmaceutical industrial discharges. Int. J. Environ. Sci. Tech. (2023). https://doi.org/10.1007/s13762-023-04867-z
Jin, Q.Q., Kang, J., Chen, Q., Shen, J.M., Guo, F., Chen, Z.L.: Efficiently enhanced Fenton-like reaction via Fe complex immobilized on silica particles for catalytic hydrogen peroxide degradation of 2,4-dichlorophenol. Appl. Catal B-Environ. 268, 118453 (2020). https://doi.org/10.1016/j.apcatb.2019.118453
Oturan, N., Aravindakumar, C.T., Olvera-Vargas, H., Paul, M.M.S., Oturan, M.A.: Electro-Fenton oxidation of para-aminosalicylic acid: degradation kinetics and mineralization pathway using Pt/carbon-felt and BDD/carbon-felt cells. Environ. Sci. Pollut. Res. 25, 20363–20373 (2018). https://doi.org/10.1007/s11356-017-9309-6
Peng, N., Liu, Z., Liu, T., Gai, C.: Emissions of polycyclic aromatic hydrocarbons (PAHs) during hydrothermally treated municipal solid waste combustion for energy generation. Appl. Energy. 184, 396–403 (2016). https://doi.org/10.1016/j.apenergy.2016.10.028
Al-Rawajfeh, A.E., Ihm, S., Varshney, H., Mabrouk, A.N.: Scale formation model for high top brine temperature multi-stage flash (MSF) desalination plants. Desalination 350, 53–60 (2014). https://doi.org/10.1016/j.desal.2014.07.016
Hung, C.H., Katz, J.L.: Formation of mixed oxide powders in flames: part I. TiO2-SiO2. J. Mater. Res. 7(7), 1861–1869 (1992). https://doi.org/10.1557/JMR.1992.1861
Curran, H.J.: Developing detailed chemical kinetic mechanisms for fuel combustion. Proc. Combust. Inst. 37, 57–81 (2019). https://doi.org/10.1016/j.proci.2018.06.054
Nomoto, S., Shimoyama, A., Shiraishi, S., Sahara, D.: Under-flame oxidation of amines and amino acids in an aqueous solution. Biosci. Biotech. Biochem. 60(11), 1851–1855 (1996). https://doi.org/10.1271/bbb.60.1851
Nomoto, S., Shimoyama, A., Shiraishi, S., Seno, T., Sahara, D.: Under-flame reaction of sulfur-containing amino acids by a hydrogen-oxygen flame. Biosci. Biotech. Biochem. 62(4), 643–649 (1998). https://doi.org/10.1271/bbb.62.643
Mehra, R.K., Duan, H., Juknelevicius, R., Ma, F.H., Li, J.Y.: Progress in hydrogen enriched compressed natural gas (HCNG) internal combustion engines-A comprehensive review. Renew. Sustain. Energy Rev. 80, 1458–1498 (2017). https://doi.org/10.1016/j.rser.2017.05.061
Marcelo, M., Juan, C.V., Filipe, Q.M., Mariane, D., Milena, Z.L., Manuel, F.G.H., Fauze, J.A.: Synthesis and characterization of iron oxide pigments through the method of the forced hydrolysis of inorganic salts. Dyes Pigments 120, 271–278 (2015). https://doi.org/10.1016/j.dyepig.2015.04.026
Yang, G.Y., Ren, Q.Q., Zhou, L., Xu, J., Lyu, Q.G.: Effect of Atmosphere on HCl Releasement during MSWI Fly Ash Thermal Treatment. J. Therm. Sci. (2023). https://doi.org/10.1007/s11630-023-1789-8
Speight, J.G.: Lange’s Handbook of Chemistry, 16th edn. McGraw-Hill, New York (2005)
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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by SJ, CL and DZ. The first draft of the manuscript was written by SJ and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Ji, S., Lai, C., Guo, Z. et al. Chemical Waste Treatment Based on Hydrogen Energy: (I) Aqueous Metal Chloride Solution Under the Oxyhydrogen Flame. Waste Biomass Valor 15, 1281–1289 (2024). https://doi.org/10.1007/s12649-023-02241-1
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DOI: https://doi.org/10.1007/s12649-023-02241-1