Skip to main content
Log in

Biodiesel Production from Oily Residues Containing High Free Fatty Acids

  • Original Paper
  • Published:
Waste and Biomass Valorization Aims and scope Submit manuscript

Abstract

In this work, fat from industrial food grease trap was used as feedstock for enzymatic synthesis of biodiesel. This fat contains high free fatty acid which can be converted in biodiesel by esterification. The reactions were performed using immobilized lipases from Candida antarctica, Thermomyces lanuginosa and Mucor miehei with factorial design of type 32 to evaluate the best conditions of temperature (30, 40 and 50 °C) and enzyme concentration (5, 7.5 and 10% w w−1). When C. antarctica and T. lanuginosa enzymes were used, high yield was obtained in all studied conditions and none of the variables was statistically significant. For the enzyme from M. miehei significant effect of the temperature was reported, higher yield was obtained with lower temperatures. The lowest yields of biodiesel were obtained using enzyme from M. miehei.

Graphical Abstract

Fat from industrial food grease trap used as feedstock for enzymatic synthesis of biodiesel.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1

Similar content being viewed by others

References

  1. Berchmans, H.J., Hirata, S.: Biodiesel production from crude Jatropha curcas L. seed oil with a high content of free fatty acids. Bioresour. Technol. 99, 1716–1721 (2008)

    Article  Google Scholar 

  2. Corrêa, I.N.S., Souza, S.L., Catran, M., Bernardes, O.L., Portilho, M.F., Langone, M.A.P.: Enzymatic biodiesel synthesis using a byproduct obtained from palm oil refining. Enzyme Res. 1, 1–8 (2011)

    Article  Google Scholar 

  3. Lotero, E., Liu, Y., Lopez, D.E., Suwannakarn, K., Bruce, D.A., Goodwin Jr., J.G.: Synthesis of biodiesel via acid catalysis. Ind. Eng. Chem. Res. 4, 5353–5363 (2005)

    Article  Google Scholar 

  4. Math, M.C., Kumar, S.P., Chetty, S.V.: Optimization of biodiesel production from oils and fats with high free fatty acids. Indian J. Sci. Technol. 3, 318–321 (2010)

    Google Scholar 

  5. Encinar, J.M., Sánchez, N., Martínez, G., García, L.: Study of biodiesel production from animal fats with high free fatty acid contente. Bioresour. Technol. 102, 10907–10914 (2011)

    Article  Google Scholar 

  6. Li, Q., Zheng, L., Cai, H., Garza, E., Yu, Z., Zhou, S.: From organic waste to biodiesel: black soldier fly, Hermetia illucens, makes it feasible. Fuel 90, 1545–1548 (2011)

    Article  Google Scholar 

  7. Kansedo, J., Lee, K.T., Bhatia, S.: Cerbera odollam (sea mango) oil as a promising non-edible feedstock for biodiesel production. Fuel 88, 1148–1150 (2009)

    Article  Google Scholar 

  8. Janaun, J., Ellis, N.: Perspectives on biodiesel as a sustainable fuel. Sust. Energy Rev. 14, 1312–1320 (2010)

    Article  Google Scholar 

  9. Ramaraju, A., Ashok Kumar, T.V.: Biodiesel development from high free fatty acid punnakka oil. J. Eng. Appl. Sci. 6, 1–6 (2011)

    Google Scholar 

  10. Gombotz, K., Parette, R., Austic, G., Kannan, D., Matson, J.V.: MnO and TiO solid catalysts with low-grade feedstocks for biodiesel production. Fuel 92, 9–15 (2012)

    Article  Google Scholar 

  11. Ribeiro, A., Castro, F., Carvalho, J.: Influence of free fatty acid content in biodiesel production on non-edible oils. First International Conference WASTES: Solutions, Treatments and Opportunities, Guimarães, Portugal, 2011

  12. Canakci, M., Van Gerpen, J.: Biodiesel production form oils and fats with high free fatty acids. J. Am. Soc. Agric. Eng. 44, 1429–1436 (2001)

    Google Scholar 

  13. Bajaj, A., Lohan, P., Jha, P.N., Mehrotra, R.: Biodiesel production through lipase catalyzed transesterification: an overview. J. Mol. Catal. B Enzym. 62, 9–14 (2010)

    Article  Google Scholar 

  14. Wang, Y., Cao, X.: Enzymatic synthesis of fatty acid ethyl esters by utilizing camellia oil soapstocks and diethyl carbonate. Bioresour. Technol. 102, 10173–10179 (2011)

    Article  Google Scholar 

  15. Souza, M.S., Aguieiras, E.C.G., Silva, M.A.P., Langone, M.A.P.: Biodiesel synthesis via esterification of feedstock with high content of free fatty acids. Appl. Biochem. Biotechnol. 154, 253–267 (2009)

    Article  Google Scholar 

  16. AOCS, American Oil Chemists Society; Official Method Ca-5a-40- Free Fatty Acids, p 2, 1997

  17. Costa Filho, E.H.: Estudo da Produção Enzimática de Biodiesel Utilizando Óleo Residual e Etanol. Dissertation, Federal University of Ceará, Brazil, 2008

  18. Silva, J.A.: Preparação de Biocatalisadores Utilizando Lipase de Candida antractica Tipo B imobilizada para Síntese de Ésteres de Vitamina A. Dissertation, Federal University of Ceará, Brazil, 2007

  19. Oliveira, J.F.G., Lucena, I.L., Saboya, R.M.A., Rodrigues, M.L., Torres, A.E.B., Fernandes, F.A.N., Cavalcante, C.L., Parente, E.J.: Biodiesel production from waste coconut oil by esterification with ethanol: the effect of water removal by adsorption. Renew. Energy 35, 2581–2584 (2010)

    Article  Google Scholar 

  20. Lucena, I.L., Saboya, R.M.A., Oliveira, J.F.G., Rodrigues, M.L., Torres Jr, A.E.B., Cavalcante, C.L., et al.: Oleic acid esterification with ethanol under continuous water removal conditions. Fuel 90, 902–904 (2011)

    Article  Google Scholar 

  21. Ma, L.L., Han, Y., Sun, K.A., Lu, J., Ding, J.C.: Kinetic and thermodynamic studies of the esterification of acidified oil catalyzed by sulfonated cation exchange resin. J. Energy Chem. 24, 456–462 (2015)

    Article  Google Scholar 

  22. Mello, V.M., Oliveira, F.C.C., Fraga, W.G., Nascimento, C.J., Suarez, P.A.Z.: Determination of the content of fatty acid methyl esters (FAME) in biodiesel samples obtained by esterification using 1H-NMR spectroscopy. Magn. Reson. Chem. 46, 1051–1054 (2008)

    Article  Google Scholar 

  23. Knothe, G.: Technical evaluation of biodiesel from vegetable oils versus algae. Will algae-derived biodiesel perform? Green Chem. 13, 3048–3065 (2011)

    Article  Google Scholar 

  24. Bringe, N.A.: Soybean oil composition for biodiesel. In: Knothe, G., Van Gerpen, J., Krahl, J. (eds.) The Biodiesel Handbook, pp. 161–164. AOCS Press, Champaign, IL (2005)

    Google Scholar 

  25. Rodrigues, R.C., Fernandez-Lafuente, R.: Lipase from Rhizomucor miehei as an industrial biocatalyst in chemical processs. J. Mol. Catal. B Enzym. 64, 1–22 (2010)

    Article  Google Scholar 

  26. Rodrigues, R.C., Fernandez-Lafuente, R.: Lipase from Rhizomucor miehei as a biocatalyst in fats and oils modification. J. Mol. Catal. B Enzym. 66, 15–32 (2010)

    Article  Google Scholar 

  27. Rodrigues, R.C., Volpato, G., Wada, K., Ayub, M.A.Z.: Enzymatic synthesis of biodiesel from transesterification reactions of vegetable oils and short chain alcohols. J. Am. Oil Chem. Soc. 85, 925–930 (2008)

    Article  Google Scholar 

  28. Shieh, C.J., Liao, H.F., Lee, C.C.: Optimization of lipase-catalyzed biodiesel by response surface methodology. Bioresour. Technol. 88, 103–106 (2003)

    Article  Google Scholar 

  29. ANP—National Agency of Petroleum, Natural Gas and Biofuels. ANP Resolution, 2008, N 7. Brasília, Brasil (2008)

  30. Awad, S., Paraschiv, M., Varuvel, E.G., Tazerout, M.: Optimization of biodiesel production from animal fat residue in wastewater using response surface methodoloy. Bioresour. Technol. 129, 315–320 (2013)

    Article  Google Scholar 

Download references

Acknowledgements

The authors thank CNPq, FAPES and UFES for the financial support to carry out this work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jairo P. de Oliveira.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pinotti, L.M., Benevides, L.C., Lira, T.S. et al. Biodiesel Production from Oily Residues Containing High Free Fatty Acids. Waste Biomass Valor 9, 293–299 (2018). https://doi.org/10.1007/s12649-016-9776-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12649-016-9776-x

Keywords

Navigation