Abstract
Good mechanical properties and corrosion resistance are the key factors for the application of biodegradable magnesium alloy wires as new medical implant materials. This study is aimed at investigating the influence of microstructural evolution on mechanical and corrosion properties of Mg–2Zn–0.5Nd alloy (ZN20) during room-temperature drawing. The decreases in the cross-sectional area of ZN20 alloy during drawing refined the grains from 10 to 5 μm under the influence of cold deformation, the basal texture was rotated around radius direction, the basal texture became dominant, and the texture transformed from drawing direction (DD)//\(<2{\bar{1}}{\bar{1}}1>\) to a point between \(<2{\bar{1}}{\bar{1}}1>\) and \(<2{\bar{1}}{\bar{1}}0>\) parallel to DD. The ultimate tensile strength of the wire was increased by 44.7% compared with that of the extruded alloy due to grain boundary strengthening, hard orientation and work hardening during drawing process, while the elongation was decreased by 85% under the influence of work hardening. The corrosion resistance of the alloy was improved after drawing due to grain refinement, while it was sensitive to prismatic texture.
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Asgari M, Hang R, Wang C, Yu Z, Li Z, Xiao Y. Biodegradable metallic wires in dental and orthopedic applications: a review. Metals. 2018;8(4):212.
Wu H, Zhao C, Ni J, Zhang S, Liu J, Yan J, Chen Y, Zhang X. Research of a novel biodegradable surgical staple made of high purity magnesium. Bioact Mater. 2016;1:122.
Witte F. The history of biodegradable magnesium implants: a review. Acta Biomater. 2010;6(5):1680.
Staiger MP, Pietak AM, Huadmai J, Dias G. Magnesium and its alloys as orthopedic biomaterials: a review. Biomater. 2006;27(9):1728.
Chen YJ, Xu ZG, Smith C, Sankar J. Recent advances on the development of magnesium alloys for biodegradable implants. Acta Biomater. 2014;10(11):4561.
Wang WD, Wan P, Liu C, Tan LL, Li WR, Li LG, Yang K. Degradation and biological properties of Ca–P contained micro-arc oxidation self-sealing coating on pure magnesium for bone fixation. Regener Biomater. 2015;2(2):107.
Chen J, Tan L, Yu X, Etim I, Ibrahim M, Yang K. Mechanical properties of magnesium alloys for medical application: a review. J Mech Behav Biomed Mater. 2018;87:68.
Birbilis N, Zhang MX, Estrin Y. Surface grain size effects on the corrosion of magnesium. Key Eng Mater. 2008;384:229.
Birbilis N, Estrin Y. Corrosion of pure Mg as a function of grain size and processing route. Adv Eng Mater. 2008;10(6):579.
Orlov D, Ralston KD, Birbilis N, Estrin Y. Enhanced corrosion resistance of Mg alloy ZK60 after processing by integrated extrusion and equal channel angular pressing. Acta Mater. 2011;59(15):6176.
Mccall CR, Hill MA, Lillard RS. Crystallographic pitting in magnesium single crystals. Corros Eng Sci Technol. 2005;40(4):337.
Uan JY, Li CF, Yu BL. Characterization and improvement in the corrosion performance of a hot-chamber diecast Mg alloy thin plate by the removal of interdendritic phases at the die chill layer. Metall Mater Trans A. 2008;39(3):703.
Li Z, Gu X, Lou S, Zheng Y. The development of binary Mg–Ca alloys for use as biodegradable materials within bone. Biomater. 2008;29(10):1329.
Wang W, Han J, Yang X, Li M, Yang K. Novel biocompatible magnesium alloys design with nutrient alloying elements Si, Ca and Sr: structure and properties characterization. Mater Sci Eng B. 2016;214:26.
Chen J, Tan L, Yu X, Yang K. Effect of minor content of Gd on the mechanical and degradable properties of as-cast Mg–2Zn–xGd–0.5Zr alloys. J Mater Sci Technol. 2019;35(4):503.
Mabuchi M, Kubota K, Higashi K. New recycling process by extrusion for machined chips of AZ91 magnesium and mechanical-properties of extruded bars. Mater Trans JIM. 1995;36(10):1249.
Kim WJ, Chung SW, Chung CS, Kum D. Superplasticity in thin magnesium alloy sheets and deformation mechanism maps for magnesium alloys at elevated temperatures. Acta Mater. 2001;49(16):3337.
Yamashita A, Horita Z, Langdon TG. Improving the mechanical properties of magnesium and a magnesium alloy through severe plastic deformation. Mater Sci Eng A Struct. 2001;300(1–2):142.
Zhu S, Wang L, Liu Q, Guan S. The microstructure and properties of cyclic extrusion compression treated Mg–Zn–Y–Nd alloy for vascular stent application. J Mech Behav Biomed. 2012;8(2):1.
Homma T, Kunito N, Kamado S. Fabrication of extraordinary high-strength magnesium alloy by hot extrusion. Scr Mater. 2009;61(6):644.
Bohlen J, Yi S, Letzig D, Kainer KU. Effect of rare earth elements on the microstructure and texture development in magnesium–manganese alloys during extrusion. Mater Sci Eng A Struct. 2010;527:7092.
Xie ZR, Zhang C, Pan HC. Microstructures and bio-corrosion resistances of as-extruded Mg–Ca alloys with ultra-fine grain size. Rare Met. 2017. https://doi.org/10.1007/s12598-017-0945-2.
Che QY, Wang KS, Wang W, Huang LY, Li TQ, Xi XP, Peng P, Qiao K. Microstructure and mechanical properties of magnesium–lithium alloy prepared by friction stir processing. Rare Met. 2019. https://doi.org/10.1007/s12598-019-01217-2.
Li X, Fan YF, Huo C. Corrosion resistance of nanostructured magnesium hydroxide coating on magnesium alloy AZ31: influence of EDTA. Rare Met. 2019;38(6):520.
Stanford N, Barnett M. Effect of composition on the texture and deformation behaviour of wrought Mg alloys. Scr Mater. 2008;58:179.
Kim WJ, Jeong HG. Mechanical properties and texture evolution in ECAP processed AZ61 Mg alloys. Mater Sci Forum. 2003;419(4):201.
Jiang MG, Yan H, Chen RS. Enhanced mechanical properties due to grain refinement and texture modification in an AZ61 Mg alloy processed by small strain impact forging. Mater Sci Eng A Struct. 2015;621:204.
Liu M, Zanna S, Ardelean H, Frateur I, Schmutz P, Song GL. A preliminary quantitative XPS study of the surface films formed on pure Magnesium and on Magnesium–Aluminium intermetallics by exposure to high-purity water. Mater Sci Forum. 2009;618–619:255.
Ahmadkhaniha D, Fedel M, Heydarzadeh Sohi M, Deflorian F. Corrosion behavior of severely plastic deformed magnesium based alloys: a review. Sur Eng Appl Electr. 2017;53(5):439.
Song GL, Mishra R, Xu Z. Crystallographic orientation and electrochemical activity of AZ31 Mg alloy. Electrochem Commun. 2010;12(8):1009.
Acknowledgements
This work was financially supported by the National Key Research and Development Program of China (Nos. 2016YFC1101804 and 2016YFC1100604), the National Natural Science Foundation of China (Nos. 51971222 and 51801220), the Natural Science Foundation of Liaoning Province of China (No. 2019-MS-326).
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Gao, M., Ma, Z., Etim, I.P. et al. Microstructure, mechanical and corrosion properties of Mg–Zn–Nd alloy with different accumulative area reduction after room-temperature drawing. Rare Met. 40, 897–907 (2021). https://doi.org/10.1007/s12598-020-01460-y
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DOI: https://doi.org/10.1007/s12598-020-01460-y