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Robust double-layered ANF/MXene-PEDOT:PSS Janus films with excellent multi-source driven heating and electromagnetic interference shielding properties

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Abstract

The strategy of incorporating polymers into MXene-based functional materials has been widely used to improve their mechanical properties, however with inevitable sacrifice of their electrical conductivity and electromagnetic interference (EMI) shielding performance. This study demonstrates a facile yet efficient layering structure design to prepare the highly robust and conductive double-layer Janus films comprised of independent aramid nanofiber (ANF) and Ti3C2Tx MXene/poly(3,4-ethylenedioxy-thiophene):poly(styrenesulfonate) (PEDOT:PSS) layers. The ANF layer serves to provide good mechanical stability, whilst the MXene/PEDOT:PSS layer ensures excellent electrical conductivity. Doping PEDOT:PSS into the MXene layer enhances the interfacial bonding strength between the MXene and ANF layers and improves the hydrophobicity and water/oxidation resistance of MXene layer. The resultant ANF/MXene-PEDOT:PSS Janus film with a conductive layer thickness of 4.4 µm was shown to display low sheet resistance (2.18 Ω/sq), good EMI shielding effectiveness (EMI SE of 48.1 dB), high mechanical strength (155.9 MPa), and overall toughness (19.4 MJ/m3). Moreover, the excellent electrical conductivity and light absorption capacity of the MXene-PEDOT:PSS conductive layer mean that these Janus films display multi-source driven heating functions, producing excellent Joule heating (382 °C at 4 V) and photothermal conversion (59.6 °C at 100 mW/m2) properties.

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Acknowledgements

The authors gratefully acknowledge the financial support for this work by the National Key Research and Development Program of China (No. 2019YFA0706802), the National Natural Science Foundation of China (Nos. 51903223 and 12072325), and the National Natural Science Foundation of China of Henan Province (No. 222300420541). The authors would like to express their gratitude to EditSprings (https://www.editsprings.cn) for the expert linguistic services provided.

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  1. Key Laboratory of Materials Processing and Mold Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, 450002, China

    Bing Zhou, Jianzhou Song, Bo Wang, Yuezhan Feng, Chuntai Liu & Changyu Shen

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  1. Bing Zhou
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Correspondence to Yuezhan Feng or Chuntai Liu.

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Robust double-layered ANF/MXene-PEDOT:PSS Janus films with excellent multi-source driven heating and electromagnetic interference shielding properties

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Zhou, B., Song, J., Wang, B. et al. Robust double-layered ANF/MXene-PEDOT:PSS Janus films with excellent multi-source driven heating and electromagnetic interference shielding properties. Nano Res. 15, 9520–9530 (2022). https://doi.org/10.1007/s12274-022-4756-x

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