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Synthesis and Characterization of Aqueous Chitosan-polyurethanes Dispersion for Textile Applications with Multipurpose Performance Profile

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Abstract

As the use of high performance textiles has grown, the need for chemical finishes to provide the fabric properties required in the special applications has grown accordingly. In this project, a series of water dispersible polyurethanes dispersion (CS-PUs) with multipurpose performance profile was developed using isophorone diisocyanate (IPDI), polyethylene glycol (PEG), 2,2-dimethylol propionic acid (DMPA) and chitosan (CS) for textile applications. In two step synthesis process, NCO functional PU prepolymers prepared by reacting IPDI, PEG, and DMPA were extended with varying molar quantities of chitosan followed by structural characterization through FTIR. The prepared CS-PU dispersions were applied onto the dyed and printed poly-cotton blend fabrics. The performance behavior of the treated fabric in terms of crease recovery, tear strength, tensile strength, and antibacterial properties was evaluated by applying standard test methods. These investigations show that the CS-PU dispersions can be applied as antibacterial textile finishes with significant improvement in the physical and mechanical properties of poly-cotton fabrics.

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References

  1. R. Paul, “Functional Finishes for Textiles”, Woodhead Publishing Ltd., Cambridge, UK, 2015.

    Google Scholar 

  2. G. Liu, X. Ding, Y. Cao, Z. Zheng, and Y. Peng, Macromol. Rapid. Commun., 26, 649 (2005).

    Article  CAS  Google Scholar 

  3. B. K. K. Swamy and Siddaramaiah, J. Appl. Polym. Sci., 90, 2945 (2003).

    Article  CAS  Google Scholar 

  4. M. Barikani and M. Mohammadi, Cabohydr. Polym., 68, 773 (2007).

    Article  CAS  Google Scholar 

  5. K. M. Zia, I. A. Bhatti, M. Barikani, M. Zuber, and M. A. Sheikh, Carbohydr. Polym., 76, 183 (2008).

    Article  Google Scholar 

  6. K. M. Zia, I. A. Bhatti, M. Barikani, M., Zuber, and M. Islam-ud-Din, Appl. Surf. Sci., 254, 6754 (2008).

    Article  CAS  Google Scholar 

  7. S. S. Silva, S. M. C. Menezes, and R. B. Garcia, Polym. J., 39, 1515 (2003).

    CAS  Google Scholar 

  8. L. M. Yu, K. Kazazian, and M. S. Shoichet, J. Biomed. Mater. Res. Part A, 82, 243 (2007).

    Article  Google Scholar 

  9. Y. H. Lin, N. K. Chou, W. J. Wu, S. Hsu, S. W. Whu, G. H. Ho, C. L. Tsai, S. S. Wang, S. H. Chu, and K. H. Hsieh, J. Appl. Polym. Sci., 104, 2683 (2007).

    Article  CAS  Google Scholar 

  10. H. T. Chiu, X. Y. Hsu, H. M. Yang, and Y. S. Ciou, Text. Sci. Eng., 5, 3 (2015).

    Google Scholar 

  11. W. Ye, M. F. Leung, J. H. Xin, and L. Z. Pei, Polymer, 46, 10538 (2005).

    Article  CAS  Google Scholar 

  12. K. F. El-Tahlawy, M. A. El-Bendary, A. G. Elhendawy, and S. M. Hudson, Carbohydr. Polym., 60, 421 (2005).

    Article  CAS  Google Scholar 

  13. Z. T. Zhang, L. Chen, J. Ji, Y. L. Huang, and D. H. Chen, Text. Res. J., 73, 1103 (2003).

    Article  CAS  Google Scholar 

  14. W. Ye, J. H. Xin, P. Li, K. L. D. Lee, and T. L. Kwong, J. Appl. Polym. Sci., 102, 1787 (2006).

    Article  CAS  Google Scholar 

  15. R. D. Mehta and R. Combs, Am. Dyest. Rep., 86, 43 (1997).

    CAS  Google Scholar 

  16. S. A. Bahmani, G. C. East, and I. Holme, Color. Technol. 116, 94 (2000).

    Article  CAS  Google Scholar 

  17. S. Vilchez, A. M. Manich, P. Jovancic, and P. Erra, Carbohydr. Polym., 71, 515 (2008).

    Article  CAS  Google Scholar 

  18. M. D. Teli, J. Sheikh, and P. Shastrakar, J. Text., 2013, 1 (2013).

    Article  Google Scholar 

  19. M. D. Teli, J. Sheikh, and P. Shastrakar, J. Text. Sci. Eng., 4, 1 (2014).

    Google Scholar 

  20. W. H. Huh, I. K. Kang, D. H. Lee, W. S. Kim, D. H. Lee, L. S. Park, K. E. Min, and K. H. Seo, Appl. Polym., 81, 2769 (2001).

    Article  CAS  Google Scholar 

  21. E. R. Kenawy, F. I. Abdel-Hay, A. A. El-Magd, and Y. Mahmoud, J. Bioact. Compat. Polym., 20, 95 (2005).

    Article  CAS  Google Scholar 

  22. K. S. Huange, W. J. Wu, J. B. Chen, and H. S. Lian, Carbohydr. Polym., 73, 254 (2008).

    Article  Google Scholar 

  23. Y. Ma, T. Zhou, and C. Zhao, Carbohydr. Res., 343, 230 (2008).

    Article  CAS  Google Scholar 

  24. S. Strand, Text. Res. J., 78, 390 (2008).

    Article  Google Scholar 

  25. Y. Shin, D. I. Yoo, and J. Jang, Appl. Polym., 80, 2495 (2001).

    Article  CAS  Google Scholar 

  26. Y. Gao and R. Cranston, Text. Res. J., 78, 60 (2008).

    Article  CAS  Google Scholar 

  27. H. Tamura, Y. Tsuruta, and S. Tokura, Mater. Sci. Eng. C., 20, 143 (2002).

    Article  Google Scholar 

  28. M. Barikani, H. Honarkar, and M. Barikani, Monatsh. Chem., 141, 653 (2010).

    Article  CAS  Google Scholar 

  29. F. Kara, E. A. Aksoy, Z. Yuksekdag, N. Hasirci, and S. Aksoy, Carbohydr. Polym., 112, 39 (2014).

    Article  CAS  Google Scholar 

  30. A. A. El-Sayed, L. K. E. Gabry, and O. G. Allam, J. Mater. Sci. Mater. Med., 21, 507 (2010).

    Article  Google Scholar 

  31. F. Mumtaz, M. Zuber, K. M. Zia, T. Jamil, and R. Hussain, Korean J. Chem. Eng., 30, 2259 (2013).

    Article  CAS  Google Scholar 

  32. R. C. Goy, D. Britto, and O. B. G. Assis, J. Polímeros., 19, 1 (2009).

    Article  Google Scholar 

  33. ISO BS EN 22313, “Textiles Fabrics-Determination of the Recovery from Creasing of a Horizontally Folded Specimen by Measuring the Angle of Recovery”, 1992.

  34. ISO BS EN 13937-1, “Textile Fabrics -Determination of Tear Strength of Fabrics”, 1999.

  35. ISO BS EN 13934-1, “Textile Fabrics-Determination of Tensile Strength of Fabrics”, 1999.

  36. S. Tabasum, M. Zuber, T. Jamil, M. Shahid, and R. Hussain, Int. J. Biol. Macromol., 56, 99 (2013).

    Article  CAS  Google Scholar 

  37. Z. Xinhua, T. U. Weiping, and H. U. Jianqing, Chin. J. Chem. Eng., 14, 99 (2006).

    Article  Google Scholar 

  38. H. Sardon, L. Irusta, and M. J. Fernández-Berridi, Prog. Org. Coat., 66, 291 (2009).

    Article  CAS  Google Scholar 

  39. K. M. Zia, S. Anjum, M. Zuber, M. Mujahid, and T. Jamil, Int. J. Biol. Macromol., 66, 26 (2014).

    Article  CAS  Google Scholar 

  40. J. Wang, Y. Zuo, M. H. Zhao, J. X. Jiang, Y. Man, J. Wu, Y. J. Hu, C. L. Liu, Y. B. Li, and J. D. Li, Int. J. Nanomed., 10, 697 (2015).

    Article  Google Scholar 

  41. V. M. Bispo, A. A. P. Mansur, E. F. B. Stancioli, and H. S. Mansur, J. Biomed. Nanotechnol., 6, 166 (2010).

    Article  CAS  Google Scholar 

  42. E. S. Costa-Junior, E. F. B. Stancioli, A. A. P. Mansur, W. L. Vasconcelos, and H. S. Mansur, Carbohydr. Polym., 76, 472 (2009).

    Article  CAS  Google Scholar 

  43. H. S. Mansur, E. S. Costa-Junior, A. A. P. Mansur, and E. F. B. Stanciolli, Mat. Sci. Eng.: C., 29, 1574 (2009).

    Article  CAS  Google Scholar 

  44. I. M. Deygen, and E. V. Kudryashova, Colloid Surf. BBiointerfaces, 141, 36 (2016).

    Article  CAS  Google Scholar 

  45. H. S. Mansur, A. A. P. Mansur, E. Curti, and M. V. D. Almeida, J. Mater. Chem. B, 1, 1696 (2013).

    Article  CAS  Google Scholar 

  46. M. Barikani, H. Honarkar, and M. Barikani, Monatsh. Chem., 141, 653 (2010).

    Article  CAS  Google Scholar 

  47. B. Sun, Y. Zuo, J. Li, L. Wang, K. Tang, D. Huang, J. Du, P. Luo, and Y. Li, Mater. Sci. Eng. C, 33, 3138 (2013).

    Article  CAS  Google Scholar 

  48. Y. K. Jhon, I. Cheong, and J. Kim, Colloid Surf. APhysicochem. Eng. Asp., 179, 71 (2001).

    Article  CAS  Google Scholar 

  49. K. Slater, J. Text. Inst., 77, 157 (1986).

    Article  Google Scholar 

  50. R. Mehta and K. V. Narrasimham, Man-made Text. Ind., 30, 327 (1987).

    CAS  Google Scholar 

  51. D. J. Nagle, M. Celina, L. Rintoul, and P. M. Fredericks, Polym. Degrad. Stabil., 92, 1446 (2007).

    Article  CAS  Google Scholar 

  52. K. S. Huang, W. J. Wu, J. B. Chen, and H. S. Lian, Carbohydr. Polym., 73, 254 (2008).

    Article  CAS  Google Scholar 

  53. K. M. Hsiao and Y. Y. Chen, Dyeing Magazine, 22, 9 (1996).

    Google Scholar 

  54. S. H. Eryuruk and F. Kalaoglu, AUTEX Res. J., 15, 207 (2015).

    Article  CAS  Google Scholar 

  55. S. Dhamija and M. Chopra, Ind. J. Fibre Text. Res., 32, 439 (2007).

    CAS  Google Scholar 

  56. C. Tomasino, T. W. Wilson, and W. R. Goynes, Ind. Eng. Chem. Prod. Res. Dev., 21, 4 (1982).

    Article  CAS  Google Scholar 

  57. C. Tomasino in “Effect of Mechanical and Physical Properties on Fabric Hand” (H. M. Behery Ed.), Woodhead Publishing Limited, Cambridge England, 2005.

  58. K. H. Lee and B. K. Kim, Polymer, 37, 2251 (1996).

    Article  CAS  Google Scholar 

  59. F. Siedenbiedel and J. C. Tiller, Polymer, 4, 46 (2012).

    Article  CAS  Google Scholar 

  60. M. Ashraf, F. Dumont, C. Campagne, P. Champagne, A. Perwuelz, A. Leriche, and N. E. Chihib, J. Eng. Fibers Fabr., 9, 15 (2014).

    CAS  Google Scholar 

  61. C. Maneerat and Y. Hayata, Int. J. Food Microbiol., 107, 99 (2006).

    Article  CAS  Google Scholar 

  62. A. McBain, A. Rickard, and P. Gilbert, J. Ind. Microbiol. Biotechnol., 29, 326 (2002).

    Article  CAS  Google Scholar 

  63. P. Gilbert and L. Moore, J. Appl. Microbiol., 99, 703 (2005).

    Article  CAS  Google Scholar 

  64. R. Zhao, H. Wang, T. Ji, G. Anderson, G. Nie, and Y. Zhao, Sci. Bull., 60, 216 (2015).

    Article  CAS  Google Scholar 

  65. M. B. Yagci, S. Bolca, J. P. A. Heuts, W. Ming, and G. de-With, Prog. Org. Coat., 72, 305 (2011).

    Article  CAS  Google Scholar 

  66. S. Hu, C. Jou, and M. Yang, Carbohydr. Polym., 58, 173 (2004).

    Article  CAS  Google Scholar 

  67. M. Kong, X. G. Chen, C. S. Liu, C. G. Liu, X. H. Meng, and L. J. Yu, Colloid Surf. B-Biointerfaces, 65, 197 (2008).

    Article  CAS  Google Scholar 

  68. I. M. Helander, E.L. Nurmiaho-Lassila, R. Ahvenainen, J. Rhoades, and S. Roller, Int. J. Food Microbiol., 71, 235 (2001).

    Article  CAS  Google Scholar 

  69. H. Liu, Y. Du, X. Wang, and L. Sun, Int. J. Food Microbiol., 95, 147 (2004).

    Article  CAS  Google Scholar 

  70. P. K. Dutta, S. Tripathi, G. K. Mehrotra, and J. Dutta, Food Chem., 114, 1173 (2009).

    Article  CAS  Google Scholar 

  71. A. P. M. Camacho, M. O. C. Rocha, M. M. C. Ortega, A. B. Hernandez, J. M. E. Brauer, and M. P. Jatomea, Polym. Int., 60, 1663 (2011).

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University of Agriculture, Faisalabad, 38030, Pakistan

    Shazia Muzaffar, Ijaz Ahmad Bhatti, Haq Nawaz Bhatti & Muhammad Shahid

  2. Institute of Chemistry, Government College University, Faisalabad, 38030, Pakistan

    Mohammad Zuber

Authors
  1. Shazia Muzaffar
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  2. Ijaz Ahmad Bhatti
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  3. Mohammad Zuber
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  4. Haq Nawaz Bhatti
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  5. Muhammad Shahid
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Correspondence to Mohammad Zuber.

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Muzaffar, S., Bhatti, I.A., Zuber, M. et al. Synthesis and Characterization of Aqueous Chitosan-polyurethanes Dispersion for Textile Applications with Multipurpose Performance Profile. Fibers Polym 19, 587–598 (2018). https://doi.org/10.1007/s12221-018-7896-6

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  • DOI: https://doi.org/10.1007/s12221-018-7896-6

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