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Synthesis and crystal structure of [chlorobis(triphenylphospino)(p-chlorobenzaldehyde thiosemicarbazone)] copper(I) complex

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Abstract

Reactions of copper(I) halides with p-chlorobenzaldehyde thiosemicarbazone (H1L) and triphenylphosphine in 1 : 1 : 2 molar ratio yielded complexes of stoichiometry, [CuX(η 1-S- H 1L)(Ph3P)2] (X = I, 1: Br, 2; Cl, 3). All the three complexes were characterized using analytical (CHNS) and spectroscopic (IR, 1H NMR) techniques. The structure of complex 3 was confirmed by X-ray crystallography. It has been found to crystallize in the triclinic system with space group P-1 and unit cell parameters: a = 10.207(5) Å, b = 13.027(5) Å, c = 16.269(5) Å, α= 100.054(5) ∘, β= 99.228(5)∘ and γ= 97.234(5)∘. This complex has distorted tetrahedral geometry with two phosphorus atoms from two triphenylphosphine ligands, thione sulfur of thiosemicarbazone ligand and chloride ion occupying the four corners of the tetrahedron. The structure of complex 3 was in contrast to sulfur-bridged dinuclear complex of copper(I) chloride with benzaldehydethiosemicarbazone, [Cu2Cl2(μ 2-S-Hbtsc)2(Ph3P)2] ⋅2H2O. The intermolecular H-bonding, Cl ⋯HC ph, 2.733 Å and π interactions, {CHph⋯π, 2.796; 2.776 Å} in this complex led to the formation of 1D chain. Two such 1D chains were cross-linked via, Cl ⋯HC ph, 2.896 Å H-bonding to form a 2D network.

p-Chlorobenzaldehyde thiosemicarbazone formed tetrahedral monomeric complex 3 with copper(I) chloride in the presence of triphenylphospine. The intermolecular H-bonding, Cl⋯HCph, 2.733 Å and π interactions, {CHph⋯π, 2.796; 2.776 Å} in this complex led to the formation of 1D chain.

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Authors and Affiliations

  1. Department of Chemistry, Lovely Professional University, Phagwara, Punjab, India

    ASHIQ KHAN, POONAM SHARMA & REKHA SHARMA

  2. Post Graduate Department of Physics & Electronics, University of Jammu, Jammu Tawi, 180006, India

    RAJNIKANT, VIVEK K GUPTA & NARESH PADHA

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  1. ASHIQ KHAN
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  2. POONAM SHARMA
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  3. RAJNIKANT
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  4. VIVEK K GUPTA
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Correspondence to REKHA SHARMA.

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Supplementary Information (SI)

All details have been deposited with the Cambridge Crystallographic Data Centre, CCDC for 3 is 1042089. Copies of this information can be obtained free of charge from The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: 44-1223-336-033; email: deposit@ccdc.cam.ac.uk; or http://www.ccdc.cam.ac.uk). Cif file of complex 3 and PXRD patterns of complexes 1-3 are given in Supplementary Information, available at www.ias.ac.in/chemsci.

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KHAN, A., SHARMA, P., RAJNIKANT et al. Synthesis and crystal structure of [chlorobis(triphenylphospino)(p-chlorobenzaldehyde thiosemicarbazone)] copper(I) complex. J Chem Sci 128, 185–191 (2016). https://doi.org/10.1007/s12039-015-1030-8

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  • DOI: https://doi.org/10.1007/s12039-015-1030-8

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