Skip to main content

Advertisement

SpringerLink
Log in

The preparation of hydrophobic hybrid film coatings from siloxane-modified polyacrylate associated with nano-fumed silica and organo-modified clay

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

Superhydrophobic hybrid film coatings were prepared from the dispersions of siloxane-modified polyacrylate associated with organo-modified clay (OMC-20A) and hydrophobic-fumed silica (FS-H15) coated on glass and cement boards by a dipping process. The hydrophobicity, surface morphology, surface energy, and surface roughness of the obtained hybrid film coatings (HBFCs) were investigated. The results showed that the hydrophobicity of the obtained HBFCs was related to surface roughness and the roughness profile of the surface. HBFCs obtained using 10 phr OMC-20A with 35 phr FS-H15 in hybrid coatings and fabricated by four dipping provided high roughness surfaces (Rq) at 546.67 nm with a micro-nano-binary structure and a low surface energy at 2.35 mN/m leading to superhydrophobic surfaces on the coated glass and cement boards demonstrating 151.34° and 150.88° water contact angles, respectively. As a result, these HBFCs coated on cement board performed great water repellent and self-cleaning.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17
Fig. 18
Fig. 19
Fig. 20
Fig. 21
Fig. 22
Fig. 23
Fig. 24
Fig. 25
Fig. 26
Fig. 27
Fig. 28
Fig. 29

Similar content being viewed by others

References

  1. Jeevahan, J, Chandrasekaran, M, Joseph, GB, Durairaj, RB, Mageshwaran, G, “Superhydrophobic Surfaces: A Review on Fundamentals, Applications, and Challenges.” J. Coat. Technol. Res., 15 (2) 231–250 (2018)

    Article  CAS  Google Scholar 

  2. Bhushan, B, Jung, YC, “Natural and Biomimetic Artificial Surfaces for Superhydrophobicity, Self-cleaning, Low Adhesion, and Drag Reduction.” Prog. Mater. Sci., 56 (1) 1–10 (2011)

    Article  CAS  Google Scholar 

  3. Latthe, SS, Sutar, RS, Kodag, VS, Bhosale, AK, Kumar, AM, Sadasivuni, KK, Xing, R, Liu, S, “Self–cleaning Superhydrophobic Coatings: Potential Industrial Applications.” Prog. Org. Coat., 128 52–58 (2019)

    Article  CAS  Google Scholar 

  4. Mahltig, B, “Smart Hydrophobic and Soil-repellent Protective Composite Coatings for Textiles and Leather.” In: Montemor, MF (ed.) Smart Composite Coatings and Membranes, pp. 261–292. Woodhead Publishing, Cambridge (2016)

    Chapter  Google Scholar 

  5. Pan, G, Xiao, X, Ye, Z, “Fabrication of Stable Superhydrophobic Coating on Fabric with Mechanical Durability, UV Resistance and High Oil-Water Separation Efficiency.” Surf. Coat. Technol., 360 318–328 (2019)

    Article  CAS  Google Scholar 

  6. Li, J, Yan, L, Ouyang, Q, Zha, F, Jing, Z, Li, X, Lei, Z, “Facile Fabrication of Translucent Superamphiphobic Coating on Paper to Prevent Liquid Pollution.” Chem. Eng. J., 246 238–243 (2014)

    Article  CAS  Google Scholar 

  7. Cappelletti, G, Fermo, P, Camiloni, M, “Smart Hybrid Coatings for Natural Stones Conservation.” Prog. Org. Coat., 78 511–516 (2015)

    Article  CAS  Google Scholar 

  8. Weng, CJ, Peng, CW, Chang, CH, Chang, YH, Yeh, JM, “Corrosion Resistance Conferred by Superhydrophobic Fluorinated Polyacrylate–silica Composite Coatings on Cold-Rolled Steel.” J. Appl. Polym. Sci., 126 (S2) E48–E55 (2012)

    Article  CAS  Google Scholar 

  9. Ulaeto, SB, Rajan, R, Pancrecious, JK, Rajan, TPD, Pai, BC, “Developments in Smart Anticorrosive Coatings with Multifunctional Characteristics.” Prog. Org. Coat., 111 294–314 (2017)

    Article  CAS  Google Scholar 

  10. Spasova, M, Manolova, N, Markova, N, Rashkov, I, “Superhydrophobic PVDF and PVDF-HFP Nanofibrous Mats with Antibacterial and Anti-biofouling Properties.” Appl. Surf. Sci., 363 363–371 (2016)

    Article  CAS  Google Scholar 

  11. Cappelletti, G, Fermo, P, “Hydrophobic and Superhydrophobic Coatings for Limestone and Marble Conservation.” In: Montemor, MF (ed.) Smart Composite Coatings and Membranes, pp. 421–452. Woodhead Publishing, Cambridge (2016)

    Chapter  Google Scholar 

  12. Wang, Y, Liu, J, Li, M, Wang, Q, Chen, Q, “The icephobicity Comparison of Polysiloxane Modified Hydrophobic and Superhydrophobic Surfaces Under Condensing Environments.” Appl. Surf. Sci., 385 472–480 (2016)

    Article  CAS  Google Scholar 

  13. Celia, E, Darmanin, T, de Givenchy, ET, Amigoni, S, Guittard, F, “Recent Advances in Designing Superhydrophobic Surfaces.” J. Colloid Interface Sci., 402 1–18 (2013)

    Article  CAS  Google Scholar 

  14. Liu, Y, Chen, X, Xin, JH, “Super-Hydrophobic Surfaces from a Simple Coating Method: A Bionic Nanoengineering Approach.” Nanotechnology, 17 (13) 3259 (2016)

    Article  Google Scholar 

  15. Liu, H, Feng, L, Zhai, J, Jiang, L, Zhu, D, “Reversible Wettability of a Chemical Vapor Deposition Prepared ZnO film between Superhydrophobicity and Superhydrophilicity.” Langmuir, 20 (14) 5659–5661 (2004)

    Article  CAS  Google Scholar 

  16. Huang, Y, Hu, M, Yi, S, Liu, X, Li, H, Huang, C, Luo, Y, Li, Y, “Preparation and Characterization of Silica/Fluorinated Acrylate Copolymers Hybrid Films and the Investigation of Their Icephobicity.” Thin Solid Films, 520 (17) 5644–5651 (2012)

    Article  CAS  Google Scholar 

  17. Huang, Y, Chen, B, Lv, Z, Guo, F, “Facile Fabrication of Durable Superhydrophobic SiO2/polyacrylate Composite Coatings with Low Nanoparticle Filling.” J. Coat. Technol. Res., 17 (5) 1289–1295 (2020)

    Article  CAS  Google Scholar 

  18. Li, K, Zeng, X, Li, H, Lai, X, “Fabrication and Characterization of Stable Superhydrophobic Fluorinated-Polyacrylate/Silica Hybrid Coating.” Appl. Surf. Sci., 298 214–220 (2014)

    Article  CAS  Google Scholar 

  19. Li, K, Zeng, X, Li, H, Lai, X, Xie, H, “Effects of Calcination Temperature on the Microstructure and Wetting Behavior of Superhydrophobic Polydimethylsiloxane/Silica Coating.” Colloids Surf. A Physicochem. Eng. Asp., 445 111–118 (2014)

    Article  CAS  Google Scholar 

  20. Li, K, Zeng, X, Li, H, Lai, X, Ye, C, Xie, H, “Study on the Wetting Behavior and Theoretical Models of Polydimethylsiloxane/Silica Coating.” Appl. Surf. Sci., 279 458–463 (2013)

    Article  CAS  Google Scholar 

  21. Söz, CK, Yilgör, E, Yilgör, I, “Influence of the Coating Method on the Formation of Superhydrophobic Silicone–Urea Surfaces Modified with Fumed Silica Nanoparticles.” Prog. Org. Coat., 84 143–152 (2015)

    Article  Google Scholar 

  22. Manoudis, PN, Karapanagiotis, I, “Modification of the Wettability of Polymer Surfaces Using Nanoparticles.” Prog. Org. Coat., 77 (2) 331–338 (2014)

    Article  CAS  Google Scholar 

  23. Kumar, D, Wu, X, Fu, Q, Ho, JWC, Kanhere, PD, Li, L, Chen, Z, “Development of Durable Self-cleaning Coatings Using Organic–Inorganic Hybrid Sol–Gel Method.” Appl. Surf. Sci., 344 205–212 (2015)

    Article  CAS  Google Scholar 

  24. Subasri, R, Hima, H, “Investigations on the Use of Nanoclay for Generation of Superhydrophobic Coatings.” Surf. Coat. Technol., 264 121–126 (2015)

    Article  CAS  Google Scholar 

  25. Yilgor, I, Bilgin, S, Isik, M, Yilgor, E, “Facile Preparation of Superhydrophobic Polymer Surfaces.” Polymer, 53 (6) 1180–1188 (2012)

    Article  CAS  Google Scholar 

  26. Yilgor, I, Bilgin, S, Isik, M, Yilgor, E, “Tunable Wetting of Polymer Surfaces.” Langmuir, 28 (41) 14808–14814 (2021)

    Article  Google Scholar 

  27. Shang, Q, Fu, B, Liu, H, Wang, M, Xiao, G, “Facile Creation of Superhydrophobic Surface with Fluorine–Silicon Polymer Under Ambient Atmosphere.” J. Coat. Technol. Res., 9 (5) 589–595 (2012)

    Article  CAS  Google Scholar 

  28. Shang, Q, Zhou, Y, Xiao, G, “A Simple Method for the Fabrication of Silica-based Superhydrophobic Surfaces.” J. Coat. Technol. Res., 11 (4) 509–515 (2014)

    Article  CAS  Google Scholar 

  29. Lakshmi, RV, Bharathidasan, T, Basu, BJ, “Superhydrophobic Sol–gel Nanocomposite Coatings with Enhanced Hardness.” Appl. Surf. Sci., 257 (24) 10421–10426 (2011)

    Article  CAS  Google Scholar 

  30. Qu, M, Xue, M, Yuan, M, He, J, Abbas, A, Zhao, Y, Wang, J, Liu, X, He, J, “Fabrication of Fluorine-Free Superhydrophobic Coatings from Montmorillonite with Mechanical Durability and Chemical Stability.” J. Coat. Technol. Res., 16 (4) 1043–1053 (2019)

    Article  CAS  Google Scholar 

  31. Kumar, D, Wu, X, Fu, Q, Ho, JWC, Kanhere, PD, Li, L, Chen, Z, “Hydrophobic Sol–gel Coatings Based on Polydimethylsiloxane for Self-cleaning Applications.” Mater. Des., 86 855–862 (2015)

    Article  CAS  Google Scholar 

  32. Christopher, KR, Pal, A, Mirchandani, G, Dhar, T, “Synthesis and Characterization of Polystyrene-acrylate/polysiloxane (PSA/PSi) Core Shell Polymers and Evaluation of Their Properties for High Durable Exterior Coatings.” Prog. Org. Coat., 77 (6) 1063–1068 (2014)

    Article  CAS  Google Scholar 

  33. Yuan, X, Yue, ZF, Liu, ZQ, Wen, SF, Li, L, Feng, T, “Effect of Siloxane-Modified Polyacrylate on Water Uptake and Anticorrosion Mechanism of Silicone–Epoxy Coatings.” J. Coat. Technol. Res., 13 (1) 123–132 (2016)

    Article  CAS  Google Scholar 

  34. Mohammad Rabea, A, Mohseni, M, Mirabedini, SM, “Investigating the Antigraffiti Properties of a Polyurethane Clearcoat Containing a Silicone Polyacrylate Additive.” J. Coat. Technol. Res., 8 (4) 497–503 (2011)

    Article  Google Scholar 

  35. Zhang, XM, Li, L, Zhang, Y, “Study on the Surface Structure and Properties of PDMS/PMMA Antifouling Coatings.” Phys. Procedia, 50 328–336 (2013)

    Article  CAS  Google Scholar 

  36. Huang, K, Liu, Y, Wu, D, “Synthesis and Characterization of Polyacrylate Modified by Polysiloxane Latexes and Films.” Prog. Org. Coat., 77 (11) 1774–1779 (2014)

    Article  CAS  Google Scholar 

  37. Kozakiewicz, J, Trzaskowska, J, Domanowski, W, Kieplin, A, Ofat-Kawalec, I, Przybylski, J, Woźniak, M, Witwicki, D, Sylwestrzak, K, “Studies on Synthesis and characterization of Aqueous Hybrid Silicone-Acrylic and Acrylic-Silicone Dispersions and Coatings. Part I.” Coatings, 9 (1) 25 (2019)

    Article  Google Scholar 

  38. Kozakiewicz, J, Trzaskowska, J, Domanowski, W, Kieplin, A, Ofat-Kawalec, I, Przybylski, J, Woźniak, M, Witwicki, D, Sylwestrzak, K, “Studies on Synthesis and Characterization of Aqueous Hybrid Silicone-Acrylic and Acrylic-Silicone Dispersions and Coatings. Part II.” Prog. Org. Coat., 138 105297 (2020)

    Article  CAS  Google Scholar 

  39. Liu, BL, Zhang, BT, Cao, SS, Deng, XB, Hou, X, Chen, H, “Preparation of the Stable Core–Shell Latex Particles Containing Organic-Siloxane in the Shell.” Prog. Org. Coat., 61 (1) 21–27 (2008)

    Article  CAS  Google Scholar 

  40. Rodríguez, R, de Las Heras Alarcón, C, Ekanayake, P, McDonald, PJ, Keddie, JL, Barandiaran, MJ, Asua, JM, “Correlation of Silicone Incorporation into Hybrid Acrylic Coatings with the Resulting Hydrophobic and Thermal Properties.” Macromolecules, 41 (22) 8537–8546 (2008)

    Article  Google Scholar 

  41. Kozakiewicz, J, Ofat, I, Trzaskowska, J, “Silicone-Containing Aqueous Polymer Dispersions with Hybrid Particle Structure.” Adv Colloid Interface Sci., 223 1–39 (2015)

    Article  CAS  Google Scholar 

  42. Pilch-Pitera, B, Kozakiewicz, J, Ofat, I, Trzaskowska, J, Špírková, M, “Silicone-Acrylic Hybrid Aqueous Dispersions of Core–Shell Particle Structure and Corresponding Silicone-Acrylic Nanopowders Designed for Modification of Powder Coatings and Plastics. Part III: Effect of Modification with Selected Silicone-Acrylic Nanopowders on Properties of Polyurethane Powder Coatings.” Prog. Org. Coat., 78 429–436 (2015)

    Article  CAS  Google Scholar 

  43. Zhang, Q, Wu, M, “Structure of Vinyl Polysiloxane on Properties of Polyacrylates Film and its Pigment Printing Application.” J. Coat. Technol. Res., 17 (4) 937–948 (2020)

    Article  CAS  Google Scholar 

  44. Protsak, IS, Morozov, YM, Dong, W, Le, Z, Zhang, D, Henderson, IM, “A 29Si, 1H, and 13C Solid-State NMR Study on the Surface Species of Various Depolymerized Organosiloxanes at Silica Surface.” Nanoscale Res. Lett., 14 (1) 1–15 (2019)

    Article  CAS  Google Scholar 

  45. Zoldesi, CI, van Walree, CA, Imhof, A, “Deformable Hollow Hybrid Silica/Siloxane Colloids by Emulsion Templating.” Langmuir, 22 (9) 4343–4352 (2006)

    Article  CAS  Google Scholar 

  46. Zheng, D, Jiang, Y, Yu, W, Jiang, X, Zhao, X, Choi, CH, Sun, G, “Salvinia-Effect-Inspired ‘Sticky’ Superhydrophobic Surfaces by Meniscus-Confined Electrodeposition.” Langmuir, 33 (47) 13640–13648 (2017)

    Article  CAS  Google Scholar 

  47. Quillin, DT, Caulfield, DF, Koutsky, JA, “Surface Energy Compatibilites of Cellulose and Polypropylene.” MRS Online Proceedings Library (OPL), 266 (1992)

Download references

Acknowledgments

The authors are thankful for the doctoral scholarship from the 100th Anniversary Chulalongkorn University and the 90th Anniversary of Chulalongkorn University for financial support. The authors also thank the Department of Materials Science, Faculty of Science, Chulalongkorn University.

Author information

Authors and Affiliations

  1. Department of Materials Science, Faculty of Science, Chulalongkorn University, Bangkok, 10330, Thailand

    Weepol Pramualkijja & Nantana Jiratumnukul

Authors
  1. Weepol Pramualkijja
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Nantana Jiratumnukul
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Nantana Jiratumnukul.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (AVI 19808 kb)

Supplementary file2 (AVI 3879 kb)

Supplementary file3 (AVI 17225 kb)

Supplementary file4 (AVI 22822 kb)

Supplementary file5 (DOCX 51 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pramualkijja, W., Jiratumnukul, N. The preparation of hydrophobic hybrid film coatings from siloxane-modified polyacrylate associated with nano-fumed silica and organo-modified clay. J Coat Technol Res 19, 1467–1492 (2022). https://doi.org/10.1007/s11998-022-00621-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-022-00621-1

Keywords

Search

Navigation