Skip to main content
Log in

Effect of Trace Addition of Sn on the Precipitation Hardening in Al-Si-Cu Eutectic Alloy

  • Aluminum and Magnesium: High Strength Alloys for Automotive and Transportation Applications
  • Published:
JOM Aims and scope Submit manuscript

A Correction to this article was published on 21 March 2019

This article has been updated

Abstract

The work is devoted to studying the effect of a Sn trace addition on the precipitation hardening after aging of the eutectic Al-7 wt.% Si-7 wt.% Cu alloy. The addition of Sn and Si has a catalytic effect on the precipitation hardening and provides for a significantly higher hardness as compared with the binary Al-Cu alloy. The addition of 0.2 wt.% Sn leads to the formation of a substantially finer precipitation structure compared with the ternary alloy. As a result, the yield strength of the Sn containing alloy is up to 30% higher after uniaxial tensile tests. The finer precipitation structure of the quaternary alloy can be attributed to the higher stabilizing effect of Sn due to its partitioning in the θ″ and θ′ phases. The measured solubility of Sn (about 0.10 at.%) is close to the reported solubility of Si in θ′.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

Change history

  • 21 March 2019

    Torgom K. Akopyan’s name appeared incorrectly on the original published version of this article. It is corrected here.

References

  1. I.J. Polmear, Light Metals: From Traditional Alloys to Nanocrystals, 4th ed. (Oxford: Elsevier, 2006), p. 421.

    Google Scholar 

  2. A.M. Samuel, J. Gauthier, and F.H. Samuel, Metall. Mater. Trans. A 27A, 1785 (1996).

    Article  Google Scholar 

  3. M.V. Glazoff, A.V. Khvan, V.S. Zolotorevsky, N.A. Belov, and A.T. Dinsdale, Casting Aluminum Alloys. Their Physical and Mechanical Metallurgy (Oxford, U.K.: Elsevier, 2019), p. 564.

    Google Scholar 

  4. J.M. Silcock, T.J. Heal, and H.K. Hardy, J. Inst. Met. 82, 239 (1953–1954).

  5. M.J. Starink and P. Van Mourik, Mater. Sci. Eng. A 156, 183 (1992).

    Article  Google Scholar 

  6. A. Guinier, Nature 142, 569 (1938).

    Article  Google Scholar 

  7. T.J. Konno, K. Hiraga, and M. Kawasaki, Scr. Mater. 44, 2303 (2001).

    Article  Google Scholar 

  8. L. Bourgeois, C. Dwyer, M. Weyland, J.F. Nie, and B.C. Muddle, Acta Mater. 60, 633 (2012).

    Article  Google Scholar 

  9. A. Rodríguez-Veiga, B. Bellon, I. Papadimitriou, G. Esteban-Manzanares, I. Sabirov, and J. LLorca, J. Alloys Compd. 757, 504 (2018).

    Article  Google Scholar 

  10. S.K. Son, M. Takeda, M. Mitome, Y. Bando, and T. Endo, Mater. Lett. 59, 629 (2005).

    Article  Google Scholar 

  11. L. Bourgeois, C. Dwyer, M. Weyland, J.F. Nie, and B.C. Muddle, Acta Mater. 59, 7043 (2011).

    Article  Google Scholar 

  12. C. Wolerton and V. Ozolins, Phys. Rev. Lett. 86, 5518 (2001).

    Article  Google Scholar 

  13. S.C. Weakley-Bollin, W. Donlon, C. Wolverton, J.W. Jones, and J.E. Allison, Metall. Mater. Trans. A 35, 2407 (2004).

    Article  Google Scholar 

  14. D.O. Ovono, I. Guillot, and D. Massinon, Scr. Mater. 55, 259 (2006).

    Article  Google Scholar 

  15. A. Wiengmoon, J.T.H. Pearce, T. Chairuangsri, S. Isoda, H. Saito, and H. Kurata, Micron 45, 32 (2013).

    Article  Google Scholar 

  16. A. Biswas, D.J. Siegel, C. Wolverton, and D.N. Seidman, Acta Mater. 59, 6187 (2011).

    Article  Google Scholar 

  17. O. Beeri, D.C. Dunand, and D.N. Seidman, Mater. Sci. Eng. A 527, 3501 (2010).

    Article  Google Scholar 

  18. R. Sankaran and C. Laird, Mater. Sci. Eng. 14, 271 (1974).

    Article  Google Scholar 

  19. T. Honma, D.W. Saxey, and S.P. Ringer, Mater. Sci. Forum 519–521, 203 (2006).

    Article  Google Scholar 

  20. J.M. Silcock and H.M. Flower, Scr. Mater. 46, 389 (2002).

    Article  Google Scholar 

  21. L. Fan, Q.T. Hao, and W.K. Han, Rare Met. 34, 308 (2015).

    Article  Google Scholar 

  22. Y. Hu, G. Wang, M. Ye, S. Wang, L. Wang, and Y. Rong, Mater. Des. 151, 123 (2018).

    Article  Google Scholar 

  23. Y. Zhang, Z. Zhang, N.V. Medhekar, and L. Bourgeois, Acta Mater. 141, 341 (2017).

    Article  Google Scholar 

  24. L. Bourgeois, T. Wong, X.-Y. Xiong, J.F. Nie, and B.C. Muddle, Mater. Sci. Forum 519–521, 495 (2006).

    Article  Google Scholar 

  25. L. Bourgeois, J.F. Nie, and B.C. Muddle, Philos. Mag. 85, 3487 (2005).

    Article  Google Scholar 

  26. E. Holmes and B. Noble, J. Inst. Met. 95, 106 (1967).

    Google Scholar 

  27. H. Ohkubo, Y. Nagai, K. Inoue, Z. Tang, and M. Hasegawa, Mater. Sci. Forum 445, 165 (2004).

    Article  Google Scholar 

  28. C. Wolverton, Acta Mater. 55, 5867 (2007).

    Article  Google Scholar 

  29. M. Werinos, H. Antrekowitsch, T. Ebner, R. Prillhofer, W. Curtin, P. Uggowitzer, and S. Pogatscher, Acta Mater. 118, 296 (2016).

    Article  Google Scholar 

  30. S.P. Ringer, K. Hono, and T. Sakurai, Met. Mater. Trans. A 26, 2207 (1995).

    Article  Google Scholar 

  31. T. Honma, D.W. Saxey, and S.P. Ringer, Mater. Sci. Forum 519, 203 (2006).

    Article  Google Scholar 

  32. Information on www.thermocalc.com. Accessed 20 Nov 2018.

  33. Z. Shen, Q. Ding, C. Liu, J. Wang, H. Tian, J. Li, and Z. Zhang, J. Mater. Sci. Technol. 33, 1159 (2017).

    Article  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge the financial support of the Ministry of Science and Higher Education of the Russian Federation in the framework of Increase Competitiveness Program of MISiS (No. P02-2017-2-10) (experimental and computational analysis of phase equilibrium) and State Task Project No. 11.2072.2017/4.6 (preparation of alloys and analysis of precipitation structure).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Torgom K. Akopyan.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

This article was updated to correct the spelling of Torgom K. Akopyan.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (PDF 108 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Akopyan, T.K., Belov, N.A. & Letyagin, N.V. Effect of Trace Addition of Sn on the Precipitation Hardening in Al-Si-Cu Eutectic Alloy. JOM 71, 1768–1775 (2019). https://doi.org/10.1007/s11837-019-03422-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11837-019-03422-x

Navigation