Abstract
Pb(Mg1/3Nb2/3)O3-PbTiO3 nanoparticles were synthesized by solid-state route. The crystal structure and optical properties were characterized by X-ray diffraction and UV–visible spectroscopy. X-ray diffraction confirmed the perovskite structure and the mean size of the crystallites was determined by employing the Williamson–Hall (W–H) model. From the UV–Visible measurements, several fundamental optical properties such as transmittance, absorbance, refractive index, band gap (Eg), Urbach energy, optical conductivity, dielectric function, and absorption coefficient were determined. The band gap energy was found to be around 3.05 eV with a high transmittance value for high wavelength. Further, the optical data were utilized to investigate the linear susceptibility, third-order nonlinear optical susceptibility, and nonlinear refractive index of the sample. It is found that the values of χ(1), χ(3) and n2 were equal to 0.053 esu, 1.33 × 10−15 esu, and 3.88 × 10−14 esu, respectively.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Data availability
The data that support the findings of this study are available from the corresponding author upon reasonable request.
References
Abutalib MM, Shkir M, Yahia IS et al (2016) Thickness dependent optical dispersion and nonlinear optical properties of nanocrystalline fluorescein dye thin films for optoelectronic applications. Optik 127:6601. https://doi.org/10.1016/j.ijleo.2016.04.136
Ait Ali B, Bouhmouche A, Wendling L et al (2023) Impact of film thickness on the structural, linear and non-linear optical properties of ferroelectric Bi2FeCrO6 perovskite thin films. Vacuum 216:112411. https://doi.org/10.1016/j.vacuum.2023.112411
Arba Y, Yamkane Z, Louafi J et al (2023) Optical properties investigation of Sr2CaFe2WO9 triple perovskite for optoelectronic applications. Optik 288:171153. https://doi.org/10.1016/j.ijleo.2023.171153
Bouhmouche A, Jabar A, Natik A et al (2023) Strain Engineering on the optoelectronic properties of CsPbI3 halide perovskites: Ab-initio investigation. J Electron Mater 52:5430–5439. https://doi.org/10.1007/s11664-023-10476-w
Bouhmouche A, Rhrissi I, Jabar A et al (2024) Electronic, optical, and thermodynamic properties of a quantum spin liquid candidate NaRuO2: Ab-initio investigation. Mater Chem Phys 314:128860. https://doi.org/10.1016/j.matchemphys.2023.128860
Bourguiba F, Dhahri A, Tahri T et al (2016) Structural, optical spectroscopy, optical conductivity and dielectric properties of BaTi0.5(Fe0.33W0.17)O3 perovskite ceramic. Bull Mater Sci 5:1765–1774. https://doi.org/10.1007/s12034-016-1305-9
Chaput F, Boilo JP, Lejeune M et al (1989) Low-temperature route to lead magnesium niobate. J Am Ceram Soc 72:1355. https://doi.org/10.1111/j.1151-2916.1989.tb07651.x
Chung NTK, Tien NA, Vuong BX (2022) Optical and magnetic properties of YFeO3 nanoparticles synthesized by a co-precipitation method at high temperature. Chem Pap 76:923–930. https://doi.org/10.1007/s11696-021-01913-3
Clabel JLH, Pelosi AG, Valverde JVP et al (2024) Structural, linear and nonlinear optical properties of perovskite BaTiO3 tri-doped Er/Yb/Zn embedded in tellurium-zinc glass. Ceram Int 50:5948–5954. https://doi.org/10.1016/j.ceramint.2023.11.085
Gervais F (2002) Optical conductivity of oxides. Mater Sci Eng R 39:29–92. https://doi.org/10.1016/S0927-796X(02)00073-6
Ghasemifard M, Hosseini SM, Bagheri-Mohagheghi MM et al (2009) Structure comparison of PMN-PT and PMN-PZT nanocrystals prepared by gel-combustion method at optimized temperatures. Phys E Low-Dimens Syst Nanostruct 41:1701. https://doi.org/10.1016/j.physe.2009.06.007
Hassanien AS (2022) Intensive linear and nonlinear optical studies of thermally evaporated amorphous thin Cu-Ge-Se-Te films. J Non-Cryst Solids 586:121563. https://doi.org/10.1016/j.jnoncrysol.2022.121563
Jayasingh EM, Sooraj R, Prabnakaran K et al (2009) Characteristics of PMN-PT powder prepared by partial oxalate process route. Ferroelectr Lett Sect 36:45. https://doi.org/10.1080/07315170902938220
Khelifi J, Tozria A, Issaouia F et al (2014) The influence of disorder on the appearance of Griffiths phase and magnetoresistive properties in (La1-xNdx)2/3(Ca1-ySry)1/3MnO3 oxides. Ceram Int 40:1641–1649. https://doi.org/10.1016/j.ceramint.2013.07.055
Kiguchi T, Wakiya N, Shinozaki K et al (2009) Valence-EELS analysis of local electronic and optical properties of PMN-PT epitaxial film. Mater Sci Eng B 161:160–165. https://doi.org/10.1016/j.mseb.2009.01.015
Mchenry DA, Giniewicz JR, Shrout TR et al (1990) Electrical and optical properties of relaxor ferroelectrics. Ferroelectrics 120:161–171. https://doi.org/10.1080/00150199008221475
Meyzonnette J, Mangin J, Cathelinaud M (2019) Refractive index of optical materials. Springer Handb of Glass. https://doi.org/10.1007/978-3-319-93728-1_29
Moubah R, Bouaine A, Ulhaq-Bouillet C et al (2007) Epitaxial growth of one-dimensional thin films prepared by pulsed laser deposition. Appl Phys Lett 91:172517. https://doi.org/10.1063/1.2802731
Moubah R, Colis S, Ulhaq-Bouillet C et al (2008) Structural and magnetic properties of layered Ca3Co4O9 thin films. Eur Phys J B 66:315–319. https://doi.org/10.1140/epjb/e2008-00439-7
Moubah R, Colis S, Leuvrey C et al (2010) Synthesis and characterization of Ca3Co4O9 thin films prepared by sol–gel spin-coating technique on Al2O3 (001). Thin Solid Films 518:4546. https://doi.org/10.1016/j.tsf.2009.12.027
Moubah R, Colis S, Gallart M et al (2012a) Thickness-dependent optical band gap in one-dimensional Ca3Co2O6 nanometric films. J Luminescence 132:457–460. https://doi.org/10.1016/j.jlumin.2011.09.032
Moubah R, Elzo M, El Moussaoui S et al (2012b) Direct imaging of both ferroelectric and antiferromagnetic domains in multiferroic BiFeO3 single crystal using x-ray photoemission electron microscopy appl. Phys Lett 100:042406. https://doi.org/10.1063/1.3679101
Nasri M, Rejaiba O, Charguia R et al (2022) Temperature and frequency dependence of negative capacitance, dielectric and electric properties in La0.57Nd0.1Sr0.13Ag0.2MnO3 ceramic. J Low Temp Phys 206:250–268. https://doi.org/10.1007/s10909-021-02656-x
Omari LH, Lemziouka H, Moubah R et al (2020) Structural and optical properties of Fe-doped Ruddlesden–Popper Ca3Ti2-xFexO7-δ nanoparticles. Mater Chem Phys 246:122810. https://doi.org/10.1016/j.matchemphys.2020.122810
Qiu C, Wang B, Zhang N et al (2020) Transparent ferroelectric crystals with ultrahigh piezoelectricity. Nature 577:350. https://doi.org/10.1038/s41586-019-1891-y
Raddaoui G, Rejaiba O, Nasri M et al (2022) Investigation studies of structural, electrical, dielectric, and optical of DyTi0.5Mn0.5O3 multiferroic for optoelectronics applications. J Mater Sci: Mater Electron 33:21890–21912. https://doi.org/10.1007/s10854-022-08976-2
Rejaiba O, Hcini F, Nasri M et al (2021) Structural, dielectric and electrical properties of sol–gel auto-combustion technic of CuFeCr0.5Ni0.5O4 ferrite. J Mater Sci 56:16044–16058. https://doi.org/10.1007/s10853-021-06315-0
Rejaiba O, Khirouni K, Dhaou MH et al (2022) Investigation study of optical and dielectric parameters using absorption and diffuse reflectance spectroscopy method on La0.57Nd0.1Sr0.13Ag0.2MnO3 perovskite for optoelectronic application. Opt Quant Electron 54:315. https://doi.org/10.1007/s11082-022-03633-8
Rhrissi I, El Harafi O, Arba Y et al (2023) Impact of film thickness on the structural and linear/nonlinear optical properties in highly oriented Cs3Bi2I9 perovskite film. Mater Sci Eng: B 297:116784. https://doi.org/10.1016/j.mseb.2023.116784
Sakr GB, Yahia IS, Fadel M, Fouad SS (2010) Optical spectroscopy, optical conductivity, dielectric properties and new methods for determining the gap states of CuSe thin films. J Alloys Comp 07:557–562. https://doi.org/10.1016/j.jallcom.2010.08.022
Salhi A, Sayouri S, Haddad M (2022) Optical properties of calcium-doped barium titanate prepared by sol-gel route and microwave pre-treatment. Opt Mater 133:113008. https://doi.org/10.1016/j.optmat.2022.113008
Sharma N, Sharma S, Sarin A et al (2016) Effect of Sb addition on linear and non-linear optical properties of amorphous Ge–Se–Sn thin films. Opt Mater 51:56–61. https://doi.org/10.1016/j.optmat.2015.11.021
Shen W, Chen J, Wu J et al (2021) nonlinear optics in lead halide perovskites: mechanisms and applications. ACS Photonics 8:113–124. https://doi.org/10.1021/acsphotonics.0c01501
Shrivastava R, Kundu RS (2023) Studies on photoluminescence and thermoluminescence properties of yttrium aluminium perovskite (YAP-YAlO3) doped with cerium(III). Chem Pap 77:7155. https://doi.org/10.1007/s11696-023-03005-w
Souifi K, Rejaiba O, Nasri M et al (2022) Hopping conduction mechanism and impedance spectroscopy analyses of the half-doped perovsikte Nd0.5Ba0.5FeO3 prepared by sol–gel method. App Phys A 128:981. https://doi.org/10.1007/s00339-022-06131-6
Wan X, Chan HLW, Choy CL et al (2004) Optical properties of (1–x)Pb(Mg1∕3Nb2∕3)O3-xPbTiO3 single crystals studied by spectroscopic ellipsometry. J Appl Phys 96:1387–1391. https://doi.org/10.1063/1.1767287
Wei Z, Huang Y, Tsuboi T et al (2012) Optical characteristics of Er3+-doped PMN–PT transparent ceramics. Ceram Int 38:3397. https://doi.org/10.1016/j.ceramint.2011.12.051
Wemple SH, DiDomenico M (1971) Behavior of the electronic dielectric constant in covalent and ionic materials. Phys Rev B 3:1338. https://doi.org/10.1103/PhysRevB.3.1338
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Laghfiri, C., Rhrissi, I., Arba, Y. et al. Structural, linear and nonlinear optical properties of Pb(Mg1/3Nb2/3)O3-PbTiO3 nanoparticles. Chem. Pap. (2024). https://doi.org/10.1007/s11696-024-03426-1
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11696-024-03426-1