Consistency of ZT-Scanner for Thermoelectric Measurements from 300 K to 700 K: A Comparative Analysis Using Si₈₀Ge₂₀ Polycrystalline Alloys

Abstract

A Harman-based instrument for the characterization of thermoelectric (TE) materials in a wide temperature range (the ZT-Scanner) was introduced in an earlier publication, with a focus on a two-sample system calibration (2SSC) procedure used for the precise evaluation of thermal losses during the measurements. This technique offers an option to accurately measure the main TE parameters from 300 K to 700 K. We now report the results of ZT-Scanner measurements of p-type Si₈₀Ge₂₀ polycrystalline samples, including the TE figure of merit ZT, Seebeck coefficient, and thermal and electrical conductivities. These samples proved to be extremely stable up to the maximum temperature of measurement, and could eventually serve as a standard for thermoelectric characterization. The measurements were performed using both PbSn solder and conductive silver paste contacts. In all cases, Ni plating was used as a protective barrier between the TE alloys and the contact material. The experimental data has been compared to the typical data measured by the Jet Propulsion Laboratory on similar samples, providing a quantitative estimation of the accuracy of the measurement system, which has been found to be better than 0.015, or 5%, up to 700 K for ZT. The consistency of the TE measurements is evaluated by means of a statistical analysis of repetitive tests on the same and on different samples of identical nature. We also analyze the influence of thermal and electrical contact resistance on the measured properties.