Abstract
The formation of bonding between Ni and Al during the compound casting and a subsequent heat treatment is investigated. The preventive effect of the surface oxide layers was partially eliminated and the bonding between the metals started immediately after the compound casting. The bonding between the metals progressed rapidly during the heat treatment at 973 K and was almost complete after 10 minutes. The first intermetallics formed between the two metals were AlNi3, AlNi, and Al3Ni2. The first two transformed to Al3Ni2 by the reaction with the liquid Al on the interface during the heat treatment. A part of Al3Ni2 was also subsequently transformed to Al3Ni. Al3Ni also formed as eutectic and proeutectic phases during the solidification of the Al. Comparison of the results obtained in this study with those published previously in the literature for Ti/Al, Fe/Al, and Al/Al bimetals suggests that the difference between the Gibbs free energy of formation of oxides covering the two bars determine the rate of bonding between the two metals.
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Manuscript submitted August 5, 2021; accepted November 4, 2021.
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Safarzadeh, S., Raiszadeh, R. Interfacial Reactions Between Al and Ni During Compound Casting. Metall Mater Trans B 53, 431–441 (2022). https://doi.org/10.1007/s11663-021-02380-7
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DOI: https://doi.org/10.1007/s11663-021-02380-7