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On the Tendency of the Co-, Ni-, and Fe-Based Melts to the Bulk Amorphization

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Abstract

In this article, the influence of the liquid phase state on the glass-forming ability and solidification processes of the Co65.5Fe6.5Si18B10, Ni64.4Fe4Cr4.9Mn2B16.2C0.5Si8, and Fe50Cr15Mo14C15B6 alloys was studied. It was shown that in conditions of quenching from the melt at ~103 K/s, the largest fraction of the amorphous phase is achieved by cooling from a narrow temperature range near 1573 K (1300 °C) for Co65.5Fe6.5Si18B10, 1503 K (1230 °C) for Ni64.4Fe4Cr4.9Mn2B16.2C0.5Si8, and 1653 K (1380 °C) for Fe50Cr15Mo14C15B6. It was found that at these temperatures, there are anomalies in the viscosity and undercooling polytherms caused by changes in short-range ordering in these melts. Overheating the Co65.5Fe6.5Si18B10, Ni64.4Fe4Cr4.9Mn2B16.2C0.5Si8, and Fe50Cr15Mo14C15B6 melts above these temperatures is accompanied by changing the nature of their crystallization. It was shown that the analysis of the temperature dependences of undercooling and kinematic viscosity can be used to determine the optimum temperatures of the melts quenching to achieve their best bulk amorphization.

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References

  1. A.J. Drehman, A.L. Greer, and D. Tarnbull: Appl. Phys. Lett., 1982, vol. 41, pp. 716–17.

    Article  Google Scholar 

  2. V.V. Molokanov and V.N. Chebotnikov: Key Eng. Mater., 1990, vols. 40–41, pp. 319–32.

    Article  Google Scholar 

  3. A. Inoue, T. Zhang, and T. Masumoto: Mater. Trans. JIM, 1990, vol. 31, pp. 177–83.

    Article  Google Scholar 

  4. S.J. Poon and S.J. Ponnambalam: J. Mater. Res., 2004, vol. 19, pp. 1320–23.

    Article  Google Scholar 

  5. A. Inoue, Y. Shinohara, and J.S. Gook: Mater. Trans. JIM, 1995, vol. 36, pp. 1427–33.

    Article  Google Scholar 

  6. N.V. Kurakova, P.P. Umnov, V.V. Molokanov, T.A. Sviridova, and Y.K. Kovneristy: Perspectivnye Materially, 2007, vol. 4, pp. 66–72.

    Google Scholar 

  7. K. Amiya and A. Inoue: Rev. Adv. Mater. Sci., 2008, vol. 18, pp. 27–29.

    Google Scholar 

  8. S.J. Pang, T. Zhang, K. Asami, and A. Inoue: Corr. Sci., 2002, vol. 44, pp. 1847–56.

    Article  Google Scholar 

  9. W.H. Wang, C. Dong, and C.H. Shek: Mater. Sci. Eng. R, 2004, vol. 44, pp. 45–89.

    Article  Google Scholar 

  10. J. Latuszkiewicz, T. Kulik, and H. Matyja: J. Mater. Sci., 1980, vol. 15, pp. 2396–98.

    Article  Google Scholar 

  11. F.L.A. Machado, C.S. Martins, and S.M. Rezende: Phys. Rev. B, 1995, vol. 51, pp. 3926–29.

    Article  Google Scholar 

  12. Y.K. Kovneristy, E.K. Osipov, and E.A. Trofimov: Fisiko-Chimicheskie Osnovy Sozdaniya Amorfnych Splavov, Nauka, Moscow, 1983.

    Google Scholar 

  13. A. Inoue: Acta Mater., 2000, vol. 48, pp. 279–306.

    Article  Google Scholar 

  14. K.S. Filippov: Russ. Metall. (Metally), 2010, vol. 5, pp. 379–83.

    Article  Google Scholar 

  15. M.J. Durate, A. Kostka, J.A. Jimenez, P. Choi, J. Klemm, D. Crespo, D. Raabe, and F.U. Renner: Acta Mater., 2014, vol. 71, pp. 20–30.

    Article  Google Scholar 

  16. D.V. Louzguine-Luzgin, A.I. Bazlov, S.V. Ketov, and A. Inoue: Mater. Chem. Phys., 2015, vol. 162, pp. 197–206.

    Article  Google Scholar 

  17. M.K. Miller and P.K. Liaw: Bulk Metallic Glasses: An Overview, Springer, New York, NY, 2007.

    Google Scholar 

  18. K.J. Laws, B. Gun, and M. Ferry: Metall. Mater. Trans. A, 2009, vol. 40A, pp. 2377–87.

    Article  Google Scholar 

  19. Z.P. Lu and C.T. Liu: Acta Mater., 2002, vol. 50 (13), pp. 3501–12.

    Article  Google Scholar 

  20. K. Mondal and B.S. Murty: J. Non-Cryst. Solids, 2005, vol. 351, pp. 1366–71.

    Article  Google Scholar 

  21. S. Guo and C.T. Liu: Intermetallics, 2010, vol. 18, pp. 2065–68.

    Article  Google Scholar 

  22. Ana F. Kozmidis-Petrovic: Thermochemica Acta, 2011, vol. 523, pp. 116–23.

    Article  Google Scholar 

  23. H.J. Willy, L.Z. Zhao, and Z.W. Liu: Physica B, 2014, vol. 437, pp. 17–23.

    Article  Google Scholar 

  24. Z. Zhu, H. Zhang, H. Wang, B. Ding, Z.Q. Hu, and H. Huang: J. Mater. Res., 2009, vol. 24 (10), pp. 3108–15.

    Article  Google Scholar 

  25. B.J. Mao, H.F. Zhang, H.M. Fu, A.W. Wang, H. Li, and Z.Q. Hu: Adv. Eng. Mater., 2009, vol. 11 (12), pp. 986–91.

    Google Scholar 

  26. D.V. Lousguine-Luzgin, T. Saito, J. Saida, and A. Inoue: J. Mater. Res., 2008, vol. 23, pp. 515–22.

    Article  Google Scholar 

  27. V.V. Molokanov, M.I. Petrzhik, T.N. Mikhailova, V.P. Manov, and P.S. Popel: Rasplavy, 2000, No. 4, pp. 40–48.

    Google Scholar 

  28. V.V. Molokanov, M.I. Petrzhik, K.S. Filippov, T.A. Sviridova, A. Kastellero, M. Baricco, and L. Batezzati: Materialovedenie, 2002, No. 1, pp. 42–45.

    Google Scholar 

  29. V.V. Molokanov, M.I. Petrzhik, T.N. Mikhailova, T.A. Sviridova, and N.P. Djakonova: J. Non-Cryst. Solids, 1999, vols. 250–252, pp. 560–65.

    Article  Google Scholar 

  30. NV Kurakova, IV Sterkhova, PP Umnov, VI Lad’yanov, VV Molokanov, LV Kamaeva (2007) Russ. Metall. (Metally), vol 2007 No. 6, pp. 89–93.

    Article  Google Scholar 

  31. B.G. Livshiz: Metallografiya, Metallurgiya, Moscow, 1990.

    Google Scholar 

  32. MI Petrzhik, VV Molokanov (2000) Bull. Russ. Acad. Sci. Phys. 2000: 1384–89.

    Google Scholar 

  33. VI Ladyanov, SV Sterkhova, LV Kamaeva, TR Chueva, VV Molokanov (2010) J. Non-Cryst. Sol. 356, pp. 65–71.

    Article  Google Scholar 

  34. Y.G. Shvidkovsky: On Some Problems of Viscosity of Liquid Metals, Gostekhizdat, Moscow, 1955.

    Google Scholar 

  35. AL Beltyukov, SI Ladyanov (2008) Instrum. Exper. Techn., 2: 155–61.

    Google Scholar 

  36. AL Beltyukov, SI Ladyanov, NV Olyanina (2009) Rasplavy 2009: 19–27.

    Google Scholar 

  37. M. Calvo-Dahlborg, P.S. Popel, M.J. Kramer, M. Besser, J.R. Morris, and U. Dahlborg: J. Alloys Compd., 2013, vol. 550, pp. 9–22.

    Article  Google Scholar 

  38. N.A. Mauro, J.C. Bendert, A.J. Vogt, J.M. Gewin, and K.F. Kelton: J. Chem. Phys., 2011, vol. 135, p. 0044502.

    Article  Google Scholar 

  39. P.S. Popel, M. Calvo-Dahlborg, and U. Dahlborg: J. Non-Cryst. Sol., 2007, vol. 353, pp. 32–40.

    Article  Google Scholar 

  40. V.V. Brazhkin, Y. Katayama, M.V. Kondrin, T. Hattori, A.G. Laypin, and H. Saitoh: Phys. Rev. Lett., 2008, vol. 100, p. 1457014.

    Article  Google Scholar 

  41. IV Sterkhova, LV Kamaeva, VI Ladyanov (2013) Rasplavy 2013: 3–12.

    Google Scholar 

  42. AL Beltyukov, SG Menshikova, VI Ladyanov (2015) J. Non-Cryst. Solids 410: 1–6.

    Article  Google Scholar 

  43. D. Herlach, P. Galenko, and D. Holland-Moritz: Metastable Solids from Undercooled Melts. Pergamon Materials Series, Elsevier, Amsterdam, 2007.

    Google Scholar 

  44. I.V. Sterkhova and L.V. Kamaeva: J. Non-Cryst. Sol., 2014, vol. 401, pp. 241–44.

    Article  Google Scholar 

  45. Y.K. Kovneristy: The Bulk-Amortized Metal Alloys, Nauka, Moscow, 1999.

    Google Scholar 

  46. V.A. Volkov, A.A. Chulkina, I.A. Elkin, and E.P. Elsukov: Phys. Met. Metallogr., 2016, vol. 17, pp. 178–87.

    Article  Google Scholar 

Download references

Acknowledgments

This work has been carried out thanks to the financial support of the project of the programs of the Ural Branch of Russian Academy of Sciences (Grant No. 15-6-2-40).

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Authors and Affiliations

  1. Physical-Technical Institute of Ural Branch of Russian Academy of Sciences, 132 Kirov Str., Izhevsk, Russia, 426000

    Irina V. Sterkhova (Scientist), Vladimir I. Lad’yanov (Head, Department of Structural-Phase Transformations) & Larisa V. Kamaeva (Senior Staff Scientist)

  2. Ural Federal University named after the first President of Russia B.N. Yeltsin, 19 Mira Str., Yekaterinburg, Russia, 620002

    Vladimir I. Lad’yanov (Head, Department of Structural-Phase Transformations)

  3. A.A. Baikov Institute of Metallurgy and Materials Science of Russian Academy of Sciences, 49 Leninsky Prospect, Moscow, Russia, 119991

    Nadezhda V. Umnova (Senior Staff Scientist) & Pavel P. Umnov (Senior Staff Scientist)

Authors
  1. Irina V. Sterkhova
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  2. Vladimir I. Lad’yanov
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  3. Larisa V. Kamaeva
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  4. Nadezhda V. Umnova
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  5. Pavel P. Umnov
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Correspondence to Irina V. Sterkhova.

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Manuscript submitted February 8, 2016.

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Sterkhova, I.V., Lad’yanov, V.I., Kamaeva, L.V. et al. On the Tendency of the Co-, Ni-, and Fe-Based Melts to the Bulk Amorphization. Metall Mater Trans A 47, 5487–5495 (2016). https://doi.org/10.1007/s11661-016-3693-2

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