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Boosting the electrochemical performances of LiNi1/3Co1/3Mn1/3O2 cathodes via optimizing calcination temperature for lithium-ion batteries

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Abstract

The research of high-performance cathode materials for rechargeable lithium-ion batteries (LIBs) is highly desirable. The ternary layered oxide LiNi1/3Co1/3Mn1/3O2 (LNCM) is a promising cathode material for LIBs due to its high discharge voltage, large specific capacity, good thermostability, and low cost. However, the LNCM cathode still has certain limitations, including cationic mixing and low electronic conductivity. These drawbacks ultimately result in poor cycling stability, rapid voltage degradation, and capacity loss during high-rate cycling. To address these issues, we have established a feasible sol-gel method combined with calcination to prepare LNCM, which can significantly improve the electrochemical activity of the LNCM cathode. The developed LNCM−850/10 cathode displays an initial specific discharge capacity of 215.3 mAh g−1 at a current rate of 0.2 C and retains a high reversible capacity of 93.9 mAh g−1 after 200 cycles. In addition, the LNCM−850/10 cathode also exhibits excellent high-rate charge-discharge capability and high-rate cycling performance. These remarkable results are probably due to the low Li+/Ni2+ cation mixing degree, good particle morphology, and uniform particle size distribution of LNCM−850/10, which effectively improves the electronic conductivity and lowers the charge transfer resistance, while reducing the Li+ diffusion distance and accelerating the insertion/extraction of Li+. Our study demonstrates that careful control of the calcination temperature of sol-gel-synthesized LNCM precursors can promote the development of LNCM cathodes suitable for advanced LIBs.

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Data availability

The data that support the findings of this study are available from the corresponding authors upon reasonable request.

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Funding

This work was supported by the Natural Science Foundation of Henan, China (No. 222300420138), for the project entitled “Design, synthesis, and oxygen production performance of cobalt-titanium encapsulated polyoxotungstates with photocatalytic function orientation” and by the Ph.D. Programs Foundation of Henan University of Technology (No. 2021BS0027) for the project entitled “Polyoxometalate-based functional materials and their applications in the field of energy storage.”

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  1. Qing Han and Chenguang Bao contributed equally to this work.

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou, 450001, People’s Republic of China

    Qing Han, Chenguang Bao, Yongmei Xiao & Xinli Yang

  2. Key Laboratory of High Specific Energy Materials for Electrochemical Power Sources of Zhengzhou City, Zhengzhou, 450001, People’s Republic of China

    Qing Han, Yongmei Xiao & Xuejing Qiu

  3. Chilwee Group Co., Ltd., Huzhou, 313100, People’s Republic of China

    Chenguang Bao & Xinli Yang

  4. School of Environmental Engineering, Henan University of Technology, Zhengzhou, 450001, People’s Republic of China

    Xuejing Qiu

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Qing Han: conceptualization, software, writing—original draft, funding acquisition. Chenguang Bao: methodology, investigation. Yongmei Xiao: data curation, validation. Xuejing Qiu: data curation, validation. Xinli Yang: resources, methodology, writing—review and editing, supervision.

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Han, Q., Bao, C., Xiao, Y. et al. Boosting the electrochemical performances of LiNi1/3Co1/3Mn1/3O2 cathodes via optimizing calcination temperature for lithium-ion batteries. Ionics 29, 4483–4493 (2023). https://doi.org/10.1007/s11581-023-05173-x

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