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Dielectric properties and ion transport studies from Trukhan, EIS, and Bandara-Mellander approaches for plasticized sodium ion conducting polymer blend electrolytes

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Abstract

In the current article, transport parameters of ions (number density (n), mobility (μ), viscosity (η), and diffusion coefficient (D)) are determined using three methods (Bandara-Mellander (B.-M.), Trukhan, and EIS) for plasticized PVA:chitosan (Ch):sodium fluoride (NaF) electrolyte. The B.-M. results are in better agreement with the Trukhan results than the EIS approach. At the 55 wt.% of glycerol (glc), the film has the highest conductivity of 3.42 × 10−5 Scm−1 which shows the fast migration of ions. The universal Jonscher’s power law is well fitted to the AC conductivity spectra. The dielectric property is studied using the modulus curves and loss tangent tan (ϕ) spectra. The tan (ϕ) is fitted in the whole frequency (fr) window to measure the relaxation time (τ) and transport parameters of ions. The effect of glc on the transport of ions is well investigated. The n, µ, and D are enhanced with loading glc, while η is decreased.

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Acknowledgements

The authors gratefully acknowledge the financial support for this study from the Ministry of Higher Education and Scientific Research-Kurdish National Research Council (KNRC), Kurdistan Regional Government, Iraq. The financial support from the University of Sulaimani and the University of Human Development are greatly appreciated.

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Authors and Affiliations

  1. Department of Physics, College of Science, Charmo University, 46023, Chamchamal, Sulaymaniyah, Iraq

    Mohamad A. Brza

  2. Hameed Majid Advanced Polymeric Materials Research Lab, Physics Department, College of Science, University of Sulaimani, Kurdistan Regional Government, Qlyasan Street, Sulaymaniyah, 46001, Iraq

    Shujahadeen B. Aziz & Niyaz M. Sadiq

  3. The Development Center for Research and Training (DCRT), University of Human Development, Sulaymaniyah, Kurdistan Region, Iraq

    Shujahadeen B. Aziz

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Brza, M.A., Aziz, S.B. & Sadiq, N.M. Dielectric properties and ion transport studies from Trukhan, EIS, and Bandara-Mellander approaches for plasticized sodium ion conducting polymer blend electrolytes. Ionics 29, 1847–1861 (2023). https://doi.org/10.1007/s11581-023-04933-z

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