Abstract
Water quality index and chemometric methods were employed to assess the groundwater quality and contamination sources in the upper Ganges basin (UGB) and lower Ganges basin (LGB) as groundwater is a sole source for drinking, domestic and agricultural uses. Groundwater samples were collected from UGB (n = 44) and LGB (n = 26) and analysed for physicochemical parameters. Groundwater in this basin is desirable (51%) to permissible (TDS < 1000 mg/l, 96%) classes for drinking. Chemical constituents in the groundwater are lower than the maximum allowable limit recommended by the WHO for drinking except K. Drinking water quality index (DWQI) values reveal that groundwater belongs to excellent (89%) and good (10%) classes. However, the high concentrations of Fe and Mn in 61 and 77% of samples, respectively, restrict the usage for drinking according to USEPA recommendations. Both LGB and UGB groundwater in shallow wells have elevated concentration of TDS, EC and other ions (Ca2+, Cl- and SO42- in LGB; major ions, NO3-, PO43-, F-, Fe and Mn in UGB) and imply the influences of anthropogenic activities. Principal component analysis and hierarchical cluster analysis reiterated that groundwater quality is affected by the anthropogenic activities as well as mineral dissolutions (carbonate and silicate minerals). This study highlighted that the infiltration of wastewater from various contamination sources likely triggered the dissolution of the minerals in the vadose zone that resulted in the accumulation of ions in the shallow aquifer. An effective management plan is essential to protect this shallow aquifer.
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Adams S, Titus R, Pietersen K, Tredoux G, Harris C (2001) Hydrochemical characteristics of aquifers near Sutherland in the Western Karoo, South Africa. J Hydrol 241:91–103. https://doi.org/10.1016/S0022-1694(00)00370-X
Adimalla N (2020) Controlling factors and mechanism of groundwater quality variation in semiarid region of South India: an approach of water quality index (WQI) and health risk assessment (HRA). Environ Geochem Health 42:1725–1752. https://doi.org/10.1007/s10653-019-00374-8
Adimalla N, Li P, Venkatayogi S (2018) Hydrogeochemical evaluation of groundwater quality for drinking and irrigation purposes and integrated interpretation with water quality index studies. Environ Processes 5:363–383. https://doi.org/10.1007/s40710-018-0297-4
Adimalla N, Qian H (2019) Groundwater quality evaluation using water quality index (WQI) for drinking purposes and human health risk (HHR) assessment in an agricultural region of Nanganur, south India. Ecotoxicol Environ Saf 176:153–161. https://doi.org/10.1016/j.ecoenv.2019.03.066
Alcaine AA, Schulz C, Bundschuh J et al (2020) Hydrogeochemical controls on the mobility of arsenic, fluoride and other geogenic co-contaminants in the shallow aquifers of northeastern La Pampa Province in Argentina. Sci Total Environ 715:17. https://doi.org/10.1016/j.scitotenv.2020.136671
Amarasinghe UA, Muthuwatta L, Smakhtin V et al. (2016) Reviving the Ganges water machine: potential and challenges to meet increasing water demand in the Ganges River Basin. Colombo, Sri Lanka: International Water Management Institute (IWMI). 42p. (IWMI Research Report 167). https://doi.org/10.5337/2016.212
APHA (2017) Standard methods for the examination of water and wastewater. American Public Health Association, American Water Works Association, Water Environment Federation, Washington, DC, 23rd edition.
Brindha K, Elango L (2013) Geochemistry of fluoride rich groundwater in a weathered granitic rock region, Southern India. Water Qual Expo Health 5:127–138. https://doi.org/10.1007/s12403-013-0096-0
Bu J, Sun Z, Ma R, Liu Y, Gong X, Pan Z, Wei W (2020) Shallow groundwater quality and its controlling factors in the Su-Xi-Chang region, Eastern China. Int J Environ Res Public Health 17:1267
CGWB (2007) Groundwater information booklet. Central Ground Water Board, Ministry of Water Resources, Govt. of India, Vaishali District, Bihar. http://cgwb.gov.in/District_Profile/Bihar/Vaishali.pdf. Accessed 10 Aug 2020
CGWB (2009) District groundwater profiles. Central Ground Water Board, Ministry of water resources, Government of India. http://cgwb.gov.in/District-GW-Brochures.html. Accessed 10 Aug 2020
CGWB (2014) State profile. Central Ground Water Board, Ministry of Water Resources, Government of India. http://cgwb.gov.in/gw_profiles/st_up.html. Accessed 10 Aug 2020
Chakraborti D, Das B, Murrill MT (2011) Examining India’s groundwater quality management. Environ Sci Technol 45:27–33. https://doi.org/10.1021/es101695d
Chakraborty M, Mukherjee A, Ahmed KM (2015) A review of groundwater arsenic in the Bengal Basin, Bangladesh and India: from Source to Sink. Curr Pollut Rep 1:220–247. https://doi.org/10.1007/s40726-015-0022-0
Chandra R, Gupta M, Pandey A (2011) Monitoring of River Ram Ganga: physico-chemical characteristic at Bareilly. Recent Res Sci Technol 3:16–18
CPCB (2013) Pollution assessment: River Ganga. Central Pollution Control Board, Ministry of Environment and Forests, Govt. of India.
CWC/NRSC (2014) Ganga Basin, Ministry of Water Resources, Government of India.
Datta PS, Deb DL, Tyagi SK (1996) Stable isotope (18O) investigations on the processes controlling fluoride contamination of groundwater. J Contam Hydrol 24:85–96. https://doi.org/10.1016/0169-7722(96)00004-6
Davis SN, De Weist RJM (1966) Hydrogeology. John Wiley and Sons, New York
Davraz A, Karaguzel R, Soyaslan I, Sener E, Seyman F, Sener S (2009) Hydrogeology of karst aquifer systems in SW Turkey and an assessment of water quality and contamination problems. Environ Geol 58:973–988. https://doi.org/10.1007/s00254-008-1577-5
Elumalai V, Nwabisa DP, Rajmohan N (2019) Evaluation of high fluoride contaminated fractured rock aquifer in South Africa – geochemical and chemometric approaches. Chemosphere 235:1–11. https://doi.org/10.1016/j.chemosphere.2019.06.065
Enalou HB, Moore F, Keshavarzi B, Zarei M (2018) Source apportionment and health risk assessment of fluoride in water resources, south of Fars province, Iran: stable isotopes (δ18O and δD) and geochemical modeling approaches. Appl Geochem 98:197–205. https://doi.org/10.1016/j.apgeochem.2018.09.019
Farooqi A, Masuda H, Kusakabe M, Naseem M, Firdous N (2007) Distribution of highly arsenic and fluoride contaminated groundwater from east Punjab, Pakistan, and the controlling role of anthropogenic pollutants in the natural hydrological cycle. Geochem J 41:213–234. https://doi.org/10.2343/geochemj.41.213
Furi W, Razack M, Abiye TA, Ayenew T, Legesse D (2011) Fluoride enrichment mechanism and geospatial distribution in the volcanic aquifers of the Middle Awash basin, Northern Main Ethiopian Rift. J Afr Earth Sci 60:315–327. https://doi.org/10.1016/j.jafrearsci.2011.03.004
Hajji S, Nasri G, Boughariou E, Bahloul M, Allouche N, Bouri S (2020) Towards understanding groundwater quality using hydrochemical and statistical approaches: case of shallow aquifer of Mahdia–Ksour Essaf (Sahel of Tunisia). Environ Sci Pollut Res 27:5251–5265. https://doi.org/10.1007/s11356-019-06982-2
Houemenou H, Tweed S, Dobigny G et al (2020) Degradation of groundwater quality in expanding cities in West Africa. A case study of the unregulated shallow aquifer in Cotonou. J Hydrol 582:16. https://doi.org/10.1016/j.jhydrol.2019.124438
Hui, Du JZ, Ma SM, Kang Z, Gong Y (2020) Application of water quality index and multivariate statistical analysis in the hydrogeochemical assessment of shallow groundwater in Hailun, northeast China. Human Ecol Risk Assess17. https://doi.org/10.1080/10807039.2020.1749827
HWRIS (2020) Hydrology and Water Resources Information System for India, Water Resources Systems Division, National Institute of Hydrology Jalvigyan Bhawan, Roorkee - 247 667, India. http://117.252.14.242/rbis/basin%20maps/ganga_about.htm. Accessed 3 Aug 2020
Jasmin I, Mallikarjuna P (2014) Physicochemical quality evaluation of groundwater and development of drinking water quality index for Araniar River Basin, Tamil Nadu, India. Environ Monit Assess 186:935–948. https://doi.org/10.1007/s10661-013-3425-7
Jehan S, Ullah I, Khan S, Muhammad S, Khattak SA, Khan T (2020) Evaluation of the Swat River, Northern Pakistan, water quality using multivariate statistical techniques and water quality index (WQI) model. Environ Sci Pollut Res 27:38545–38558. https://doi.org/10.1007/s11356-020-09688-y
Jiang Y, Wu Y, Groves C, Yuan D, Kambesis P (2009) Natural and anthropogenic factors affecting the groundwater quality in the Nandong karst underground river system in Yunan, China. J Contam Hydrol 109:49–61. https://doi.org/10.1016/j.jconhyd.2009.08.001
Kaushik SJ (2002) European sea bass, Dicentrachuslabrax. In: Webster CD, Lim C (eds) Nutrient requirement sand feeding of finfish for aquaculture. CAB International, Wallingford, pp 28–39
Keefe J, Granz D, Maxfield R (2003) Standard operating procedure for groundwater sampling. The Office of Environmental Measurement and Evaluation, EPA, New England e Region 1, 11 Technology Dr North Chelmsford, MA 01863.
Khan MYA, Gani KM, Chakrapani GJ (2015) Assessment of surface water quality and its spatial variation. A case study of Ramganga River, Ganga Basin, India. Arab J Geosci 9:28. https://doi.org/10.1007/s12517-015-2134-7
Khan R, Jhariya DC (2017) Groundwater quality assessment for drinking purpose in Raipur city, Chhattisgarh using water quality index and geographic information system. J Geol Soc India 90:69–76. https://doi.org/10.1007/s12594-017-0665-0
Kumar PS, Elango L, James E (2014) Assessment of hydrochemistry and groundwater quality in the coastal area of South Chennai, India. Arab J Geosci 7:2641–2653. https://doi.org/10.1007/s12517-013-0940-3
Kumar S, Venkatesh AS, Singh R, Udayabhanu G, Saha D (2018) Geochemical signatures and isotopic systematics constraining dynamics of fluoride contamination in groundwater across Jamui district, Indo-Gangetic alluvial plains, India. Chemosphere 205:493–505. https://doi.org/10.1016/j.chemosphere.2018.04.116
Kundu MC, Mandal B (2008) Assessment of potential hazards of fluoride contamination in drinking groundwater of an intensively cultivated district in West Bengal, India. Environ Monit Assess 152:97–103. https://doi.org/10.1007/s10661-008-0299-1
Manikandan E, Rajmohan N, Anbazhagan S (2020) Monsoon impact on groundwater chemistry and geochemical processes in the shallow hard rock aquifer. Catena 195:104766. https://doi.org/10.1016/j.catena.2020.104766
MDWS (2011) Report of the Central Team on Arsenic mitigation in rural drinking water sources in Ballia district, Uttar Pradesh State. Ministry of Drinking Water and Sanitation, Government of India, New Delhi.
Morales-Arredondo I, Rodríguez R, Armienta MA, Villanueva-Estrada RE (2016) The origin of groundwater arsenic and fluorine in a volcanic sedimentary basin in central Mexico: a hydrochemistry hypothesis. Hydrogeol J 24:1029–1044. https://doi.org/10.1007/s10040-015-1357-8
Mukherjee A, Fryar AE, Eastridge EM, Nally RS, Chakraborty M, Scanlon BR (2018) Controls on high and low groundwater arsenic on the opposite banks of the lower reaches of River Ganges, Bengal basin, India. Sci Total Environ 645:1371–1387. https://doi.org/10.1016/j.scitotenv.2018.06.376
Muzenda F, Masocha M, Misi SN (2019) Groundwater quality assessment using a water quality index and GIS: a case of Ushewokunze Settlement, Harare, Zimbabwe. Phys Chem Earth 112:134–140. https://doi.org/10.1016/j.pce.2019.02.011
Nagarajan R, Rajmohan N, Mahendran U, Senthamilkumar S (2010) Evaluation of groundwater quality and its suitability for drinking and agricultural use in Thanjavur city, Tamil Nadu, India. Environ Monit Assess 171:289–308. https://doi.org/10.1007/s10661-009-1279-9
Nolan BT, Hitt KJ, Ruddy BC (2002) Probability of nitrate contamination of recently recharged groundwaters in the Conterminous United States. Environ Sci Technol 36:2138–2145. https://doi.org/10.1021/es0113854
Olaka LA, Wilke FDH, Olago DO, Odada EO, Mulch A, Musolff A (2016) Groundwater fluoride enrichment in an active rift setting: Central Kenya Rift case study. Sci Total Environ 545-546:641–653. https://doi.org/10.1016/j.scitotenv.2015.11.161
Palmucci W, Rusi S, Di Curzio D (2016) Mobilisation processes responsible for iron and manganese contamination of groundwater in Central Adriatic Italy. Environ Sci Pollut Res 23:11790–11805. https://doi.org/10.1007/s11356-016-6371-4
Pandey DS, Singh KK, Tripathi PK, Rai P, Singh PK (2009) Arsenic contamination in groundwater: an alarming problem and its remedial measures in Ballia district (U.P.). Bhu-Jal News 24:114–118
Paul R, Brindha K, Gowrisankar G, Tan ML, Singh MK (2019) Identification of hydrogeochemical processes controlling groundwater quality in Tripura, Northeast India using evaluation indices, GIS, and multivariate statistical methods. Environ Earth Sci 78:16. https://doi.org/10.1007/s12665-019-8479-6
PHED (2015) Public Health Engineering Department, Bihar. http://phed.bih.nic.in/WaterQuality.htm. Accessed 3 July 2020
Piper AM (1944) A graphic procedure in the geochemical interpretation of water-analyses. EOS Trans Am Geophys Union 25:914–928. https://doi.org/10.1029/TR025i006p00914
Qian H, Chen J, Howard KWF (2020) Assessing groundwater pollution and potential remediation processes in a multi-layer aquifer system. Environ Pollut 263:10. https://doi.org/10.1016/j.envpol.2020.114669
Quino Lima I, Ramos Ramos O, Ormachea Muñoz M, Quintanilla Aguirre J, Duwig C, Maity JP, Sracek O, Bhattacharya P (2020) Spatial dependency of arsenic, antimony, boron and other trace elements in the shallow groundwater systems of the Lower Katari Basin, Bolivian Altiplano. Sci Total Environ 719:137505. https://doi.org/10.1016/j.scitotenv.2020.137505
Rajmohan N (2020) Groundwater contamination issues in the shallow aquifer, Ramganga Sub-basin, India. In: Kumar M SD, Honda R (ed) Emerging Issues in the Water Environment during Anthropocene: A South East Asian Perspective. Springer Nature, pp 337-354. https://doi.org/10.1007/978-981-32-9771-5_18
Rajmohan N, Amarasinghe UA (2016) Groundwater quality issues and management in Ramganga Sub-Basin. Environ Earth Sci 75:1030. https://doi.org/10.1007/s12665-016-5833-9
Rajmohan N, Nagarajan R, Jayaprakash M, Prathapar SA (2020) The impact of seasonal waterlogging on the depth-wise distribution of major and trace metals in the soils of the eastern Ganges basin. Catena 189:104510. https://doi.org/10.1016/j.catena.2020.104510
Rajmohan N, Patel N, Singh G, Amarasinghe UA (2017) Hydrochemical evaluation and identification of geochemical processes in the shallow and deep wells in the Ramganga Sub-Basin, India. Environ Sci Pollut Res 24:21459–21475. https://doi.org/10.1007/s11356-017-9704-z
Rajmohan N, Prathapar SA (2014) Extend of arsenic contamination and its impact on food chain and human health in Eastern Ganges Basin: a review. Colombo, Sri Lanka: International Water Management Institute (IWMI). (IWMI Working Paper 161) 47p. (IWMI Working Paper 161). https://doi.org/10.5337/2014.224.
Ranjbar A, Cherubini C, Saber A (2020) Investigation of transient sea level rise impacts on water quality of unconfined shallow coastal aquifers. Int J Environ Sci Technol 17:2607–2622. https://doi.org/10.1007/s13762-020-02684-2
Saha D, Dwivedi SN, Sahu S (2009) Arsenic in groundwater in parts of middle Ganga plain in Bihar—an appraisal. BhuJal News 24:82–94
Sankar MS, Vega MA, Defoe PP, Kibria MG, Ford S, Telfeyan K, Neal A, Mohajerin TJ, Hettiarachchi GM, Barua S, Hobson C, Johannesson K, Datta S (2014) Elevated arsenic and manganese in groundwaters of Murshidabad, West Bengal, India. Sci Total Environ 488-489:570–579. https://doi.org/10.1016/j.scitotenv.2014.02.077
Sawyer GN, McCarty DL (1967) Chemistry of sanitary engineers. Mcgraw Hill, New York
Sharma B, Amarasinghe U, Xueliang C, de Condappa D, Shah T, Mukherji A, Bharati L, Ambili G, Qureshi A, Pant D, Xenarios S, Singh R, Smakhtin V (2010) The Indus and the Ganges: river basins under extreme pressure. Water Int 35:493–521. https://doi.org/10.1080/02508060.2010.512996
Sinha DK, Saxena R (2006) Statistical assessment of underground drinking water contamination and effect of monsoon at Hasanpur, J. P. Nagar (Uttar Pradesh, India). J Environ Sci Eng 48:157–164
Sinha DK, Saxena S, Saxena R (2006) Seasonal variation in the aquatic environment of Ramganga River at Moradabad - a quantitative study. Indian J Environ Protect 26:488–496
Somasundaram MV, Ravindran G, Tellam JH (1993) Ground-water pollution of the Madras Urban Aquifer, India. Groundwater 31:4–11. https://doi.org/10.1111/j.1745-6584.1993.tb00821.x
USEPA (2012) Edition of the drinking water standards and health advisories. EPA, Washington
WHO (2011) Guidelines for drinking-water quality, 4th edn. World Health Organization, Geneva
Zaidi FK, Nazzal Y, Jafri MK, Naeem M, Ahmed I (2015) Reverse ion exchange as a major process controlling the groundwater chemistry in an arid environment: a case study from northwestern Saudi Arabia. Environ Monit Assess 187:607. https://doi.org/10.1007/s10661-015-4828-4
Zhai Y, Wang J, Huan H, Zhou J, Wei W (2013) Characterizing the groundwater renewability and evolution of the strongly exploited aquifers of the North China Plain by major ions and environmental tracers. J Radioanal Nucl Chem 296:1263–1274. https://doi.org/10.1007/s10967-012-2409-3
Acknowledgement
The author would like to thank Dr. S.A. Prathapar and Dr. Upali A. Amarasinghe, International Water Management Institute (IWMI), Sri Lanka, for their constant support and encouragement. The author wishes to express his gratitude to the three anonymous reviewers and the editor for their constructive comments, which helped to improve the manuscript significantly.
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Rajmohan, N. Application of water quality index and chemometric methods on contamination assessment in the shallow aquifer, Ganges River basin, India. Environ Sci Pollut Res 28, 23243–23257 (2021). https://doi.org/10.1007/s11356-020-12270-1
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DOI: https://doi.org/10.1007/s11356-020-12270-1