Skip to main content
Log in

Experimental study of methyl tert-butyl ether as an oxygenated additive in diesel and Calophyllum inophyllum methyl ester blended fuel in CI engine

  • Research Article
  • Published:
Environmental Science and Pollution Research Aims and scope Submit manuscript

Abstract

This work presents the effect of the ternary oxygenated additive on diesel biodiesel blended fuel to evaluate the engine characteristics. The Calophyllum inophyllum trees being abundant in India can lessen the dependence on petroleum imports to a specific extent. Methyl tertiary butyl ether is used as an oxygenated additive for the ternary blends preparation as 5–20% by volume. Seven blends of neat baseline diesel, biodiesel (Calophyllum inophyllum Methyl Ester), a blend of diesel (50%)-biodiesel (50%), a blend of diesel (50%)-biodiesel-methyl tert-butyl ether (5, 10, 15, and 20%) are prepared which are tested on a single cylinder, constant speed diesel engine. The experimental results were revealed that the replacement of biodiesel by MTBE has shown a slight reduction in brake thermal efficiency with a slight increase in brake-specific fuel consumption. Further, the MTBE addition in ternary blends reduced the unburned hydrocarbon, CO, and NOx by 63.9, 6.4, and 3.37% respectively. In addition, the carbon dioxide emission is almost similar to diesel fuel at a higher addition of MTBE with diesel-biodiesel blend. In the combustion point of view, the addition of 5% MTBE resulted in 3.49 and 5.1% reduction of peak pressure and heat release rate are observed as compared to diesel fuel. Critical analysis in combustion aspects is also carried out and it is witnessed with prolonged ignition delay during MTBE addition with diesel-biodiesel blends.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15

Similar content being viewed by others

Abbreviations

CI:

Compression ignition

CIME:

Calophyllum inophyllum methyl ester

DEE:

Diethyl ether

MTBE:

Methyl tertiary-butyl ether

CO:

Carbon monoxide

CO2 :

Carbon dioxide

BTE:

Brake thermal efficiency

BSFC:

Brake-specific fuel consumption

BSEC:

Brake-specific energy consumption

B100:

100% Biodiesel (Calophyllum inophyllum)

D50B50:

50% diesel + 50% biodiesel

D50B45DEE5:

50% diesel + 45% biodiesel + 5% diethyl ether

D50B40DEE10:

50% diesel + 40% biodiesel + 10% diethyl ether

D50B45MTBE5:

50% diesel + 45% biodiesel + 5% methyl tertiary-butyl ether

D50B40MTBE10:

50% diesel + 40% biodiesel + 10% methyl tertiary-butyl ether

HC:

Hydrocarbons

NOx :

Oxides of nitrogen

ppm:

Parts per million

References

  • Alagu K, Nagappan B, Jayaraman J & GnanaDhas AA (2018). Impact of antioxidant additives on the performance and emission characteristics of CI engine fuelled with B20 blend of rice bran biodiesel. Environ Sci Pollut Res, pp.1–11

  • Ali OM, Mamat R, Masjuki HH, Abdullah AA (2016) Analysis of blended fuel properties and cycle-to-cycle variation in a diesel engine with a diethyl ether additive. Energy Convers Manag 108:511–519

    Article  CAS  Google Scholar 

  • Alptekin E (2017) Evaluation of ethanol and isopropanol as additives with diesel fuel in a CRDI diesel engine. Fuel 205:161–172

    Article  CAS  Google Scholar 

  • Arcoumanis C, Bae C, Crookes R, Kinoshita E (2008) The potential of di-methyl ether (DME) as an alternative fuel for compression-ignition engines: a review. Fuel 87(7):1014–1030

    Article  CAS  Google Scholar 

  • Arumugam A, Ponnusami V (2019) Biodiesel production from Calophyllum inophyllum oil a potential non-edible feedstock: an overview. Renew Energy 131:459–471

    Article  CAS  Google Scholar 

  • Ashok B, Nanthagopal K, Jeevanantham AK, Bhowmick P, Malhotra D, Agarwal P (2017) An assessment of Calophyllum inophyllum biodiesel fuelled diesel engine characteristics using novel antioxidant additives. Energy Convers Manag 148:935–943

    Article  CAS  Google Scholar 

  • Atabani AE, da Silva César A (2014) Calophyllum inophyllum L.—a prospective non-edible biodiesel feedstock. Study of biodiesel production, properties, fatty acid composition, blending and engine performance. Renew Sust Energ Rev 37:644–655

    Article  CAS  Google Scholar 

  • Atabani AE, Silitonga AS, Ong HC, Mahlia TMI, Masjuki HH, Badruddin IA, Fayaz H (2013) Non-edible vegetable oils: a critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production. Renew Sust Energ Rev 18:211–245

    Article  CAS  Google Scholar 

  • Awad OI, Mamat R, Noor MM, Ibrahim TK, Yusri IM, Yusop AF (2018) The impacts of compression ratio on the performance and emissions of ice powered by oxygenated fuels: a review. J Energy Inst 91(1):19–32

    Article  CAS  Google Scholar 

  • Cataluña R, Dalávia D, Da Silva R, Menezes E, Venturi V, Wagner R (2011) Acceleration tests using gasolines formulated with di-TAE, TAEE and MTBE ethers. Fuel 90(3):992–996

    Article  Google Scholar 

  • Cerri T, D’Errico G, Onorati A (2013) Experimental investigations on high octane number gasoline formulations for internal combustion engines. Fuel 111:305–315

    Article  CAS  Google Scholar 

  • Chauhan BS, Kumar N, Cho HM (2010) Performance and emission studies on an agriculture engine on neat Jatropha oil. J Mech Sci Technol 24(2):529–535

    Article  Google Scholar 

  • Das D, Kumar A, Yadav A (2018) Evaluation of performance, emission and combustion characteristics of a CI engine fueled with karanja biodiesel and diethyl ether blends. Biofuels 9(1):89–94

    Article  CAS  Google Scholar 

  • Donahue RJ, Foster DE (2000) Effects of oxygen enhancement on the emissions from a DI diesel via manipulation of fuels and combustion chamber gas composition (No. 2000–01-0512). SAE Technical Paper

  • Jaichandar S, Annamalai K (2013) Combined impact of injection pressure and combustion chamber geometry on the performance of a biodiesel fueled diesel engine. Energy 55:330–339

    Article  CAS  Google Scholar 

  • Jiaqiang E, Liu T, Yang WM, Li J, Gong J, Deng Y (2016) Effects of fatty acid methyl esters proportion on combustion and emission characteristics of a biodiesel fueled diesel engine. Energy Convers Manag 117:410–419

    Article  Google Scholar 

  • Kajitani S, Usisaki H, Clasen E, Campbell S, & Rhee KT (1994). MTBE for improved diesel combustion and emissions. SAE Technical Paper No. 941688

  • Kalsi SS, Subramanian KA (2017) Effect of simulated biogas on performance, combustion and emissions characteristics of a bio-diesel fueled diesel engine. Renew Energy 106:78–90

    Article  CAS  Google Scholar 

  • Lamani VT, Yadav AK, Narayanappa KG (2017) Influence of low-temperature combustion and dimethyl ether-diesel blends on performance, combustion, and emission characteristics of common rail diesel engine: a CFD study. Environ Sci Pollut Res 24(18):15500–15509

    Article  CAS  Google Scholar 

  • Lešnik L, Vajda B, Žunič Z, Škerget L, Kegl B (2013) The influence of biodiesel fuel on injection characteristics, diesel engine performance, and emission formation. Appl Energy 111:558–570

    Article  Google Scholar 

  • Liu H, Wang Z, Zhang J, Wang J, Shuai S (2017) Study on combustion and emission characteristics of polyoxymethylene dimethyl ethers/diesel blends in light-duty and heavy-duty diesel engines. Appl Energy 185:1393–1402

    Article  CAS  Google Scholar 

  • Miyamoto N, Ogawa H, Nurun NM, Obata K, & Arima T (1998). Smokeless, low NOx, high thermal efficiency, and low noise diesel combustion with oxygenated agents as main fuel(No. 980506). SAE technical paper

  • Monirul IM, Masjuki HH, Kalam MA, Mosarof MH, Zulkifli NWM, Teoh YH, How HG (2016) Assessment of performance, emission and combustion characteristics of palm, jatropha and Calophyllum inophyllum biodiesel blends. Fuel 181:985–995

    Article  CAS  Google Scholar 

  • Mosarof, M. H., Kalam, M. A., Masjuki, H. H., Alabdulkarem, A., Ashraful, A. M., Arslan, A., ... & Monirul, I. M. (2016). Optimization of performance, emission, friction and wear characteristics of palm and Calophyllum inophyllum biodiesel blends. Energy Convers Manag, 118, 119–134

    Article  CAS  Google Scholar 

  • Nanthagopal K, Ashok B, Raj RTK (2016) Influence of fuel injection pressures on Calophyllum inophyllum methyl ester fuelled direct injection diesel engine. Energy Convers Manag 116:165–173

    Article  CAS  Google Scholar 

  • Nanthagopal K, Ashok B, Tamilarasu A, Johny A, Mohan A (2017) Influence on the effect of zinc oxide and titanium dioxide nanoparticles as an additive with Calophyllum inophyllum methyl ester in a CI engine. Energy Convers Manag 146:8–19

    Article  CAS  Google Scholar 

  • Nanthagopal K, Ashok B, Saravanan B, Patel D, Sudarshan B, Ramasamy RA (2018) An assessment on the effects of 1-pentanol and 1-butanol as additives with Calophyllum Inophyllum biodiesel. Energy Convers Manag 158:70–80

    Article  CAS  Google Scholar 

  • Natarajan M, Frame EA, Naegeli DW, Asmus T, Clark W, Garbak J, ... & Wallace JP (2001). Oxygenates for advanced petroleum-based diesel fuels: Part 1. Screening and selection methodology for the oxygenates. SAE Technical Paper No. 2001–01-3631

  • Ong HC, Masjuki HH, Mahlia TMI, Silitonga AS, Chong WT, Leong KY (2014) Optimization of biodiesel production and engine performance from high free fatty acid Calophyllum inophyllum oil in CI diesel engine. Energy Convers Manag 81:30–40

    Article  CAS  Google Scholar 

  • Ong ZC, Mishani MBM, Chong WT, Soon RS, Ong HC, Ismail Z (2017) Identification of optimum Calophyllum inophyllum bio-fuel blend in diesel engine using advanced vibration analysis technique. Renew Energy 109:295–304

    Article  CAS  Google Scholar 

  • Praveen A, Rao GLN, & Balakrishna B (2017). Performance and emission characteristics of a diesel engine using Calophyllum inophyllum biodiesel blends with TiO2 nanoadditives and EGR. Egyp J Petroleum

  • Rahman SA, Masjuki HH, Kalam MA, Abedin MJ, Sanjid A, Sajjad H (2013) Production of palm and Calophyllum inophyllum based biodiesel and investigation of blend performance and exhaust emission in an unmodified diesel engine at high idling conditions. Energy Convers Manag 76:362–367

    Article  CAS  Google Scholar 

  • Rajamohan S, Kasimani R. (2018a). Analytical characterization of products obtained from slow pyrolysis of Calophyllum inophyllum seed cake: study on performance and emission characteristics of direct injection diesel engine fuelled with bio-oil blends. Environ Sci Poll Res, 1–6

  • Rajamohan S, Kasimani R. (2018b). Studies on the effects of storage stability of bio-oil obtained from pyrolysis of Calophyllum inophyllum deoiled seed cake on the performance and emission characteristics of a direct-injection diesel engine

  • Rakopoulos DC, Rakopoulos CD, Giakoumis EG, Dimaratos AM (2012) Characteristics of performance and emissions in high-speed direct injection diesel engine fueled with diethyl ether/diesel fuel blends. Energy 43(1):214–224

    Article  CAS  Google Scholar 

  • Ramakrishnan P, Kasimani R, Peer MS, Rajamohan S (2018) Assessment of n-pentanol/Calophyllum inophyllum/diesel blends on the performance, emission, and combustion characteristics of a constant-speed variable compression ratio direct injection diesel engine. Environ Sci Pollut Res 25(14):13731–13744

    Article  CAS  Google Scholar 

  • Ren Y, Huang Z, Miao H, Di Y, Jiang D, Zeng K et al (2008) Combustion and emissions of a DI diesel engine fuelled with diesel-oxygenate blends. Fuel 87(12):2691–2697

    Article  CAS  Google Scholar 

  • Roy MM (2008) Investigation of methyl tertiary butyl ether—diesel combustion and odorous emissions in a direct-injection diesel engine. Proceed Instit Mech Eng Part D: J Automobile Eng 222(2):251–263

    Article  Google Scholar 

  • Roy MM, Tsunemoto H, Ishitani H (2000) Effect of MTBE and DME on odorous emissions in a DI diesel engine. JSME Int J Series B Fluids and Thermal Eng 43(3):511–517

    Article  CAS  Google Scholar 

  • Sezer I (2011) Thermodynamic, performance and emission investigation of a diesel engine running on dimethyl ether and diethyl ether. Int J Therm Sci 50(8):1594–1603

    Article  CAS  Google Scholar 

  • Shameer PM, Ramesh K (2017) FTIR assessment and investigation of synthetic antioxidant on the fuel stability of Calophyllum inophyllum biodiesel. Fuel 209:411–416

    Article  Google Scholar 

  • Shih LKL (1998). Comparison of the effects of various fuel additives on the diesel engine emissions SAE Technical Paper No. 982573

  • Silitonga AS, Hassan MH, Ong HC, Kusumo F (2017) Analysis of the performance, emission and combustion characteristics of a turbocharged diesel engine fuelled with Jatropha curcas biodiesel-diesel blends using kernel-based extreme learning machine. Environ Sci Pollut Res 24(32):25383–25405

    Article  CAS  Google Scholar 

  • Sivakumar V, Sarangan J, & Anand RB (2010). Performance, combustion and emission characteristics of a CI engine using MTBE blended diesel fuel. In Frontiers in Automobile and Mechanical Engineering (FAME), 170–174

  • Srihari S, Thirumalini S, Prashanth K (2017) An experimental study on the performance and emission characteristics of PCCI-DI engine fuelled with diethyl ether-biodiesel-diesel blends. Renew Energy 107:440–447

    Article  CAS  Google Scholar 

  • Stone CR, Green-Armytage DI (1987) Comparison of methods for the calculation of mass fraction burnt from engine pressure—time diagrams. Proceed Instit Mech Eng Part D: Trans Eng 201(1):61–67

    Article  Google Scholar 

  • Topgül T (2015) The effects of MTBE blends on engine performance and exhaust emissions in a spark ignition engine. Fuel Process Technol 138:483–489

    Article  Google Scholar 

  • Venu H, Madhavan V (2017) Influence of diethyl ether (DEE) addition in ethanol-biodiesel-diesel (EBD) and methanol-biodiesel-diesel (MBD) blends in a diesel engine. Fuel 189:377–390

    Article  CAS  Google Scholar 

  • Vijayakumar C, Ramesh M, Murugesan A, Panneerselvam N, Subramaniam D, Bharathiraja M (2016) Biodiesel from plant seed oils as an alternate fuel for compression ignition engines—a review. Environ Sci Pollut Res 23(24):24711–24730

    Article  CAS  Google Scholar 

  • Viswanathan K (2018) Experimental investigation on emission reduction in neem oil biodiesel using selective catalytic reduction and catalytic converter techniques. Environ Sci Poll Res. 1–2

  • Yang SY, Naser N, Chung SH, & Al-Qurashi K (2014). Ignition delay and soot oxidative reactivity of MTBE blended diesel fuel. SAE Technical Paper No. 2014-01-1266

  • Yokota H, Nakajima H, & Kakegawa T (1998). A new concept for low emission diesel combustion (2nd rep.: reduction of HC and CO emission, and improvement of fuel consumption by EGR and MTBE blended fuel). SAE Technical Paper No. 981933

  • Zhu L, Cheung CS, Zhang WG, Huang Z (2011) Combustion, performance and emission characteristics of a DI diesel engine fueled with ethanol–biodiesel blends. Fuel 90(5):1743–1750

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Nanthagopal Kasianantham.

Additional information

Responsible editor: Philippe Garrigues

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bragadeshwaran, A., Kasianantham, N., Ballusamy, S. et al. Experimental study of methyl tert-butyl ether as an oxygenated additive in diesel and Calophyllum inophyllum methyl ester blended fuel in CI engine. Environ Sci Pollut Res 25, 33573–33590 (2018). https://doi.org/10.1007/s11356-018-3318-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11356-018-3318-y

Keywords

Navigation