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Two fluorescent cyclopalladated arylpyrazine complexes: synthesis, crystal structures and application in the double Suzuki coupling of N-heteroaryl halides with 1,4-benzenediboronic acid

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Abstract

Two 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (Sphos) adducts of cyclopalladated arylpyrazine complexes have been synthesized and characterized. Additionally, the structures of both complexes were determined by single-crystal X-ray analysis. These palladacycles are fluorescent in CH2Cl2 at room temperature. They have been applied to the double Suzuki coupling of N-heteroaryl halides with 1,4-benzenediboronic acid, giving the desired products in good yields.

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Acknowledgments

We are grateful to the Innovation Scientists and Technicians Troop Construction Projects of Henan Province, the Aid Project for the Leading Young Teachers in Henan Provincial Institutions of Higher Education of China (2013GGJS–151), and the Science Foundation of Henan Education Department (14A150049 and 15B150008).

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Authors and Affiliations

  1. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450052, Henan, China

    Zhi-Qiang Xiao, Xin Han, Xin-Qi Hao & Mao-Ping Song

  2. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471022, Henan, China

    Chen Xu, Hong-Mei Li, Zhi-Qiang Wang & Wei-Jun Fu

Authors
  1. Zhi-Qiang Xiao
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  2. Chen Xu
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  3. Hong-Mei Li
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  4. Xin Han
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  5. Zhi-Qiang Wang
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  6. Wei-Jun Fu
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  7. Xin-Qi Hao
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  8. Mao-Ping Song
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Correspondence to Chen Xu or Xin-Qi Hao.

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Xiao, ZQ., Xu, C., Li, HM. et al. Two fluorescent cyclopalladated arylpyrazine complexes: synthesis, crystal structures and application in the double Suzuki coupling of N-heteroaryl halides with 1,4-benzenediboronic acid. Transition Met Chem 40, 501–508 (2015). https://doi.org/10.1007/s11243-015-9942-1

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  • DOI: https://doi.org/10.1007/s11243-015-9942-1

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