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(C2N2H10)[Co(HPHO3)2Cl2]: the first phosphite analog of layered hydrogen selenites

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Abstract

Purple crystals of ethylenediammonium cobalt bis(hydrogen phosphite) dichloride were produced from an aqueous solution containing ethylenediamine, cobalt chloride, and phosphorous acid. The new compound is monoclinic, P21/c, a = 8.6665(3) Å, b = 7.2866(2) Å, c = 9.7300(3) Å, β = 112.726(3); V = 566.74(3) Å3, Z = 2. The 2D structure comprised ethylenediammonium cations sandwiched between the [Co(HPHO3)2Cl2]2− layers. The latter are built of trans-CoO4Cl2 octahedra linked by hydrogen-bonded dimers of hydrophosphite ions, (HPHO3)22−. The new compound is a complete structural analog of the recently reported (C2N2H10)[Co(HSeO3)2Cl2] and isostructural analogs with other transition metal dications; it is, in fact, the first representative of a new “layered hydrophosphite” family. Its structure provides yet another illustration of essential similarities in the crystal chemistry of selenites and phosphites, including protonated species, wherein the lone pair of SeIV and the nearly nonpolar P–H enhance formation of loose and/or open-framework structural architectures.

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Funding

The X-ray study was carried out in accordance with the state task of the Russian Federation, state registration number 122011300125–2. The topological analysis was supported by the Russian Science Foundation, grant no. 20–77-10065-П.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 1-3 Leninskie Gory, Moscow, 199991, Russia

    Dmitri O. Charkin, Alexander M. Banaru, Dmitri N. Dmitriev & Dina V. Deyneko

  2. Laboratory of Arctic Mineralogy and Material Sciences, FRC Kola Science Centre RAS, 14 Fersman Str., Apatity, Murmansk Region, 184209, Russia

    Dmitri O. Charkin, Alexander M. Banaru, Vadim E. Kireev, Dina V. Deyneko & Sergey M. Aksenov

  3. I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, FRC Kola Science Centre RAS, 26a, Akademgorodok, Apatity, Murmansk Region, 184209, Russia

    Alevtina N. Gosteva

  4. Department of Material Sciences, Moscow State University, 1-73 Leninskie Gory, Moscow, 199991, Russia

    Vadim E. Kireev

  5. Geological Institute, FRC Kola Science Centre RAS, 14 Fersman Str., Apatity, Murmansk Region, 184209, Russia

    Sergey M. Aksenov

Authors
  1. Dmitri O. Charkin
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Contributions

Dmitri O. Charkin – conceptualization; synthesis; writing—original draft preparation. Alexander M. Banaru – formal analysis; writing—original draft preparation. Dmitry N. Dmitriev – formal analysis; synthesis. Alevtina N. Gosteva – formal analysis. Vadim E. Kireev – formal analysis. Dina V. Deyneko – formal analysis. Sergey M. Aksenov – conceptualization; formal analysis; writing—original draft preparation; supervision.

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Correspondence to Sergey M. Aksenov.

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Charkin, D.O., Banaru, A.M., Dmitriev, D.N. et al. (C2N2H10)[Co(HPHO3)2Cl2]: the first phosphite analog of layered hydrogen selenites. Struct Chem 35, 39–46 (2024). https://doi.org/10.1007/s11224-023-02254-5

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