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New 2D polyoxoanions built up of A-type sandwich anions and trivalent cerium, neodymium and samarium cations

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Abstract

New 2D undulating layer pure inorganic polymers H2[{M(H2O)8 M(H2O)7M(H2O)6}P2W18Ce3O70(OH)(H2O)2]∙xH2O; M = Ce3+ (1), Nd3+ (2) and Sm3+ (3) were synthesized by routine synthetic reactions in aqueous solution and characterized by elemental analysis, IR spectra, cyclic voltammetry, XRPD, magnetic susceptibility, TG analysis, and X-ray single-crystal diffraction. The 2D framework of 1–3 were built by tri-Ce4+ substituted sandwich-type polyoxoanions modified by six trivalent lanthanide cations M(H2O)x (x = 6–8) units. The M(H2O)x (x = 6–7) groups act as bridges to form 2D undulating layer, but the M(H2O)8 groups link the 2D layers together via hydrogen bonds to form a 3D supra-molecular framework.

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Acknowledgments

The authors would like to thank Professor Ulrich Kortz and Dr. Bassem S. Bassil of Jacobs University, Bremen, Germany, for partial single-crystal X-ray measurements undertaken.

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Authors and Affiliations

  1. Department of Chemistry, University of Kurdistan, P.O. Box 66135-416, Sanandaj, Iran

    Roushan Khoshnavazi, Liela Bahrami, Abuzar Noruzi & Kamal Abdi

  2. Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, Vill. S. Agata, Salita Sperone 31, 98166, Messina, Italy

    Francesco Nicolò

  3. Faculty of Chemistry, University of Isfahan, 81746-73441, Isfahan, Iran

    Hadi Amiri Rudbari

Authors
  1. Roushan Khoshnavazi
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  2. Francesco Nicolò
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  3. Hadi Amiri Rudbari
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  4. Liela Bahrami
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  5. Abuzar Noruzi
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  6. Kamal Abdi
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Corresponding author

Correspondence to Roushan Khoshnavazi.

Appendix: Supplementary material

Appendix: Supplementary material

Crystallographic data (CIF file) for the structural analysis have been deposited with the Fachinformationszentium Karlsruhe (FIZ), CSD-numbers 429254 (H107Ce6O123P2W18) 426105 (Ce6Nd6O227P4W36) and 426106 (Ce6O208P4Sm6W36). This data can be obtained free of charge via the following email: crysdata@fiz-karlsruhe.de. Tel. +49 7247 808-226; Fax +49 7247 808-666.

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Khoshnavazi, R., Nicolò, F., Rudbari, H.A. et al. New 2D polyoxoanions built up of A-type sandwich anions and trivalent cerium, neodymium and samarium cations. J IRAN CHEM SOC 13, 131–138 (2016). https://doi.org/10.1007/s13738-015-0720-y

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  • DOI: https://doi.org/10.1007/s13738-015-0720-y

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