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Synthesis of 1-nitrazaalkyl-5-(1,1,1-trinitro-3-nitrazapropyl)tetrazoles

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Abstract

Alkylation of 5-aminotetrazole with chloromethylnitrazaalkanes led to 1-nitrazaalkyl derivatives, which reacted with formalin solution and sodium carbonate followed by treatment with nitroform to form 1-nitrazaalkyl-5-(1,1,1-trinitro-3-azapropyl)tetrazoles. The latter were nitrated for the first time to obtain tetrazoles containing both trinitromethyl and nitrazaalkyl groups.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    M. M. Krayushkin, E. I. Chernoburova & I. V. Zavarzin

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  1. M. M. Krayushkin
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  2. E. I. Chernoburova
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  3. I. V. Zavarzin
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Correspondence to I. V. Zavarzin.

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Dedicated to the Academician of the Russian Academy of Sciences V. A. Tartakovsky on the occasion of his 90th birthday.

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1981–1986, September, 2022.

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Krayushkin, M.M., Chernoburova, E.I. & Zavarzin, I.V. Synthesis of 1-nitrazaalkyl-5-(1,1,1-trinitro-3-nitrazapropyl)tetrazoles. Russ Chem Bull 71, 1981–1986 (2022). https://doi.org/10.1007/s11172-022-3617-9

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