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Alkylation of 5-(3,3-R,R′-2-oxido-1-triazeneoxymethyl)tetrazoles

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Abstract

Alkylation of 5-(3,3-R,R′-2-oxido-1-triazeneoxymethyl)tetrazole salts with iodomethane, dimethyl sulfate, chloroacetonitrile, and 1-chloromethoxy-3,3-dimethyl-1-triazene 2-oxide affords two isomers at positions 1 and 2 of the tetrazole ring as the major products. Tetrazoles containing oxymethyltriazene oxide groups at positions 5 and 1 (or 5 and 2) were synthesized for the first time.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    G. A. Smirnov & P. B. Gordeev

Authors
  1. G. A. Smirnov
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  2. P. B. Gordeev
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Correspondence to G. A. Smirnov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2153—2158, November, 2020.

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Smirnov, G.A., Gordeev, P.B. Alkylation of 5-(3,3-R,R′-2-oxido-1-triazeneoxymethyl)tetrazoles. Russ Chem Bull 69, 2153–2158 (2020). https://doi.org/10.1007/s11172-020-3014-1

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  • DOI: https://doi.org/10.1007/s11172-020-3014-1

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