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Chemoselective reduction of nitroarenes, N-acetylation of arylamines, and one-pot reductive acetylation of nitroarenes using carbon-supported palladium catalytic system in water

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Abstract

Developing and/or modifying fundamental chemical reactions using chemical industry-favorite heterogeneous recoverable catalytic systems in the water solvent is very important. In this paper, we developed convenient, green, and efficient approaches for the chemoselective reduction of nitroarenes, N-acetylation of arylamines, and one-pot reductive acetylation of nitroarenes in the presence of the recoverable heterogeneous carbon-supported palladium (Pd/C) catalytic system in water. The utilize of the simple, effective, and recoverable catalyst and also using of water as an entirely green solvent along with relatively short reaction times and good-to-excellent yields of the desired products are some of the noticeable features of the presented synthetic protocols.

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Acknowledgements

We are thankful to the Research Council of Urmia University for the partial support of this work.

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  1. Department of Organic Chemistry, Faculty of Chemistry, Urmia University, Urmia, Iran

    Behzad Zeynizadeh, Farkhondeh Mohammad Aminzadeh & Hossein Mousavi

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  1. Behzad Zeynizadeh
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  2. Farkhondeh Mohammad Aminzadeh
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Zeynizadeh, B., Mohammad Aminzadeh, F. & Mousavi, H. Chemoselective reduction of nitroarenes, N-acetylation of arylamines, and one-pot reductive acetylation of nitroarenes using carbon-supported palladium catalytic system in water. Res Chem Intermed 47, 3289–3312 (2021). https://doi.org/10.1007/s11164-021-04469-9

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