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A magnetically recoverable copper–salen complex as a nano-catalytic system for amine protection via acetylation using thioacetic acid

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Abstract

A novel copper(II)–salen complex was immobilized on the surface of magnetite nanoparticles using chitosan as a linker. This system exhibits superior catalytic activity in acetyl protection of various amines with thioacetic acid as the acetylating reagent. The method has advantages over others in high selectivity, simple work-up, green reaction medium and the application of an easily recoverable heterogeneous catalyst.

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Acknowledgement

We acknowledge Tarbiat Modares University for partial support of this work.

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Authors and Affiliations

  1. Chemistry Department, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran

    Elahe Yazdani, Maryam Kazemi Miraki, Arefe Salamatmanesh, Jamshid Azarnia, Kobra Azizi, Leila Ghandi & Akbar Heydari

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  1. Elahe Yazdani
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  2. Maryam Kazemi Miraki
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Correspondence to Akbar Heydari.

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This article is dedicated to memory of Hasan Rahimi.

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Yazdani, E., Kazemi Miraki, M., Salamatmanesh, A. et al. A magnetically recoverable copper–salen complex as a nano-catalytic system for amine protection via acetylation using thioacetic acid. Res Chem Intermed 45, 1775–1793 (2019). https://doi.org/10.1007/s11164-018-3702-8

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