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Magnetic nanoparticles supported Cu2+ and Ce3+ complexes: toward the chemical and electrochemical oxidation of alcohol and sulfide derivatives

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Abstract

Heterogeneous catalysts are more prominent rather than homogenous catalysts since they are simply separated from products. To improve and develop heterogeneous catalysts, two core–shell magnetic nanocatalysts are prepared by anchoring of Cu and Ce complexes on the surface of Fe3O4, then the efficiency of the obtained catalysts are tested toward both chemical and electrochemical oxidation of sulfide and alcohol derivatives. Characterization of mentioned catalysts was performed by using FT-IR, XRD, EDX and SEM. The obtained results confirm that the reported method has outstanding advantages such as short reaction time, high yield, easy operation, easy separation, inexpensive and non-toxic material and chemical and thermal stability.

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Acknowledgements

The authors are deeply grateful to University of Kurdistan University for financial support of this research project.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

    Taiebeh Tamoradi, Aso Navaee, Abdollah Salimi & Mohammad Ghadermazi

  2. Department of Environmental Planning, Tehran University, Tehran, Iran

    Seyedeh Masoumeh Mousavi

  3. Department of Chemistry, Payame Noor University, Tehran, Iran

    Taiebeh Tamoradi & Hojat Veisi

Authors
  1. Taiebeh Tamoradi
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  2. Aso Navaee
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  3. Abdollah Salimi
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  4. Seyedeh Masoumeh Mousavi
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  5. Mohammad Ghadermazi
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  6. Hojat Veisi
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Correspondence to Taiebeh Tamoradi or Aso Navaee.

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Tamoradi, T., Navaee, A., Salimi, A. et al. Magnetic nanoparticles supported Cu2+ and Ce3+ complexes: toward the chemical and electrochemical oxidation of alcohol and sulfide derivatives. Res Chem Intermed 45, 4517–4530 (2019). https://doi.org/10.1007/s11164-019-03846-9

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  • DOI: https://doi.org/10.1007/s11164-019-03846-9

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