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Synthesis of Betti base derivatives catalyzed by nano-CuO-ionic liquid and experimental and quantum chemical studies on corrosion inhibition performance of them

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Abstract

In this research, for the first time, aminonaphthol derivatives were introduced as efficient corrosion inhibitors. A linear polarization method was employed to investigate the corrosion inhibitory effect of the synthesized aminonaphthols at a concentration of 200 ppm for mild steel acid pickling in 1 M HCl and 0.5 M H2SO4 solutions. The results showed that, even in such strongly corrosive media, all of the synthesized aminonaphthol derivatives exhibit good inhibitory effects toward mild steel corrosion with inhibition efficiencies in the range of 84–95%. A facile, efficient and environmentally friendly method has been introduced for the synthesis of aminonaphthol derivatives by nano-CuO in ionic liquid as a novel catalytic system. Mild, one-pot, operational simplicity and reusability of the catalyst make this protocol highly significant. Experiments showed that these compounds can be used as effective corrosion inhibitors for mild steel acid pickling. The semi-emperical B3LYP method was used for the theoretical calculations. The results of quantum chemical studies confirmed the experimental findings.

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Scheme 1
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Acknowledgements

The authors would like to acknowledge the financial support from the Iran National Science Foundation (INSF) and the University of Tabriz.

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Authors and Affiliations

  1. Laboratory of Organic Synthesis Research, Department of Organic and Biochemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 5166614766, Iran

    Reza Teimuri-Mofrad, Mahdi Gholamhosseini-Nazari, Somayeh Esmati & Aziz Shahrisa

  2. Research Laboratory for Electrochemical Instrumentation and Energy Systems, Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 5166614766, Iran

    Iraj Ahadzadeh

Authors
  1. Reza Teimuri-Mofrad
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  2. Iraj Ahadzadeh
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Correspondence to Reza Teimuri-Mofrad.

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11164_2018_3287_MOESM1_ESM.docx

Detailed procedure for preparation and characterization of catalyst with spectral data and scan spectra of all compounds are available. Also, the optimized structure, HOMO and LUMO distribution for compound 4a–q are presented. Supplementary data associated with this article can be found via the ‘‘Supplementary Content’’ section of this article’s webpage. (DOCX 15265 kb)

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Teimuri-Mofrad, R., Ahadzadeh, I., Gholamhosseini-Nazari, M. et al. Synthesis of Betti base derivatives catalyzed by nano-CuO-ionic liquid and experimental and quantum chemical studies on corrosion inhibition performance of them. Res Chem Intermed 44, 2913–2927 (2018). https://doi.org/10.1007/s11164-018-3287-2

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