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An efficient and green method for the synthesis of Betti base employing nano-SiO2–H3BO3 as a novel recyclable heterogeneous catalyst

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Abstract

In this research, nano-SiO2–H3BO3 is introduced as a novel environmentally benign and recyclable heterogeneous catalyst for the synthesis of aminonaphthols under solvent-free conditions without an additional co-catalyst or additive in air. This synthesis method offers several advantages, such as a green and eco-friendly protocol, operational simplicity, mild reaction conditions, short reaction times, higher yields and easy work-up procedures. The work-up of these very clean reactions involves only recrystallization of the product from ethanol and recovery of the catalyst by filtration. The catalyst can be reused several times without losing activity.

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Acknowledgements

The authors would like to acknowledge the financial support from the Iran National Science Foundation (INSF) and the University of Tabriz.

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Authors and Affiliations

  1. Department of Organic and Biochemistry, Faculty of Chemistry, University of Tabriz, P.O. Box 51666-16471, Tabriz, Iran

    Reza Teimuri-Mofrad, Mahdi Gholamhosseini-Nazari, Somayeh Esmati & Aziz Shahrisa

Authors
  1. Reza Teimuri-Mofrad
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  2. Mahdi Gholamhosseini-Nazari
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  3. Somayeh Esmati
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  4. Aziz Shahrisa
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Corresponding author

Correspondence to Reza Teimuri-Mofrad.

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Teimuri-Mofrad, R., Gholamhosseini-Nazari, M., Esmati, S. et al. An efficient and green method for the synthesis of Betti base employing nano-SiO2–H3BO3 as a novel recyclable heterogeneous catalyst. Res Chem Intermed 43, 6845–6861 (2017). https://doi.org/10.1007/s11164-017-3024-2

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