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Synthesis, characterization, and application of MgO/ZnO nanocomposite supported on activated carbon for photocatalytic degradation of methylene blue

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Abstract

In this study, nano-sized ZnO/MgO composites at different ratios were synthesized based on sol–gel method under ultrasonic radiation, and then combined with as-prepared activated carbon (AC). The prepared materials were characterized by transmission electron microscopy, scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectrometry, and Brunauer–Emmett–Teller surface area measurements. The photocatalytic activity of the prepared nanocomposites was tested on the decolorization of methylene blue (MB) aqueous solutions. The dye photo-decolorization process was studied considering the influence of experimental parameters such as catalyst concentration, ZnO/MgO/AC ratio, pH, and MB adsorption rate. The resulting material composition with the best catalytic activity towards the MB photo-decolorization was ZnO doped with 10 % MgO and 10 % AC. The complete photo-oxidation of a 1 × 10−5 mol l−1 MB solution, at natural pH and room temperature, was achieved in <20 min, nearly 60 min faster than the ZnO photo-assisted process. Experimental results show that ZnO/MgO/AC nanoparticles possess high photocatalytic activity in comparison with universal catalysts.

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References

  1. L. Michaelis, S. Granick, J. Am. Chem. Soc. 67, 1212 (1945)

    Article  CAS  Google Scholar 

  2. N.R. Tacconide, J. Carmona, K. Rajeshwar, J. Electrochem. Soc. 144, 2486 (1997)

    Article  Google Scholar 

  3. P. Kumar, M. Govindaraju, S. Senthamilselvi, K. Premkumar, Colloids Surf. B 103, 658 (2013)

    Article  CAS  Google Scholar 

  4. X. Liu, S. Gao, H. Xu, Z. Lou, W. Wang, B. Huang, Y. Dai, Nanoscale 5, 1870 (2013)

    Article  CAS  Google Scholar 

  5. A. Mills, J. Wang, J. Photochem. Photobiol. A 127, 123 (1999)

    Article  CAS  Google Scholar 

  6. Q. Wu, C. Feng, C. Wang, Colloids Surf. B 101, 210 (2013)

    Article  CAS  Google Scholar 

  7. Y. Galagan, W.F. Su, J. Photochem. Photobiol. A 195, 378 (2008)

    Article  CAS  Google Scholar 

  8. S.K. Lee, M. Sheridan, A. Mills, Chem. Mater. 17, 2744 (2005)

    Article  CAS  Google Scholar 

  9. A. Rezaee, H. Masoumbaigi, R. Darvishi, A.R. Khataee, S. Hashemiyan, Desalin. Water. Treat. 44, 174 (2012)

    Article  CAS  Google Scholar 

  10. S. Pande, S.K. Ghosh, S. Nath, S. Praharaj, S. Jana, S. Panigrahi, S. Basu, T. Pal, J. Colloid, Interface Sci. 299, 421 (2006)

    Article  CAS  Google Scholar 

  11. M. Ushamani, K. Sreekumar, C.S. Kartha, R. Joseph, Appl. Opt. 43, 3697 (2004)

    Article  CAS  Google Scholar 

  12. D.W. Grattan, M. Gilberg, Stud. Conserv. 39, 210 (1994)

    Article  CAS  Google Scholar 

  13. T. Pal, N.R. Jana, Langmuir 12, 3114 (1996)

    Article  CAS  Google Scholar 

  14. T. Pal, T.K. Sau, N.R. Jana, Langmuir 13, 1481 (1997)

    Article  CAS  Google Scholar 

  15. Y.T. Liao, L. Zang, D.L. Akins, Catal. Commun. 6, 141 (2005)

    Article  CAS  Google Scholar 

  16. H. Kusic, N. Koprivanac, L. Srsan, J. Photochem. Photobiol. A 181, 195 (2006)

    Article  CAS  Google Scholar 

  17. O. Akhavan, ACS Nano 4, 4174 (2010)

    Article  CAS  Google Scholar 

  18. O. Akhavan, M. Abdolahad, A. Esfandia, M. Mohtashamifar, J. Phys. Chem. C 114, 12955 (2010)

    Article  CAS  Google Scholar 

  19. C. Karunakaran, V. Rajeswari, P. Gomathisankar, Mater. Sci. Semicond. Process. 14, 133 (2011)

    Article  CAS  Google Scholar 

  20. O. Akhavan, R. Azimirad, S. Safa, Mater. Chem. Phys. 130, 598 (2011)

    Article  CAS  Google Scholar 

  21. R. Wahab, Y.S. Kim, A. Mishra, S.I. Yun, H.S. Shin, Nanoscale Res. Lett. 5, 1675 (2010)

    Article  CAS  Google Scholar 

  22. O. Akhavan, M. Mehrabian, K. Mirabbaszadeh, R. Azimirad, J. Phys. D Appl. Phys. 42, 225305 (2009)

    Article  Google Scholar 

  23. O. Seven, B. Dindar, S. Aydemir, D. Metin, M.A. Ozinel, S. Iclia, J. Photochem. Photobiol. A Chem. 165, 103 (2004)

    Article  CAS  Google Scholar 

  24. X. Xiang, L. Xie, Z. Li, F. Li, Chem. Eng. J. 221, 222 (2013)

    Article  CAS  Google Scholar 

  25. K. Tennakone, J. Bandara, K.M.P. Bandaranayake, G.R.R.A. Kumara, A. Konno, Jpn. J. Appl. Phys. 40, L732 (2001)

    Article  CAS  Google Scholar 

  26. N.K. Nga, P.T. Hong, T.D. Lam, T.Q. Huy, J. Colloid Interface Sci. 398, 210 (2013)

    Article  CAS  Google Scholar 

  27. R.D. Rashmi, M.U. Iohborlang, K.R. Prasanta, D. Bodhaditya, B. Saumen, S. Lokendra, J. Exp. Nanosci. 9, 512 (2014)

    Article  Google Scholar 

  28. G.D. Mihai, V. Meynen, M. Mertens, N. Bilba, P. Cool, E.F. Vansant, J. Mater. Sci. 45, 5786 (2010)

    Article  CAS  Google Scholar 

  29. J. Silvestre-Albero, J.C. Serrano-Ruiz, A. Sepulveda-Escribano, F. Rodrıguez-Reinoso, Appl. Catal. A 351, 16 (2008)

    Article  CAS  Google Scholar 

  30. R.M. Mohamed, Desalin. Water. Treat. 50, 147 (2012)

    Article  CAS  Google Scholar 

  31. J. Zhai, X. Tao, Y. Pu, X.F. Zeng, J.F. Chen, Appl. Surf. Sci. 257, 393 (2010)

    Article  CAS  Google Scholar 

  32. Y. Zhi, Y. Li, Q. Zhang, H. Wang, Langmuir 26, 15546 (2010)

    Article  CAS  Google Scholar 

  33. A. Meidanchi, O. Akhavan, Carbon 69, 230 (2014)

    Article  CAS  Google Scholar 

  34. J.N. Tiwari, K. Mahesh, N.H. Le, K.C. Kemp, R. Timilsina, R.N. Tiwari, K.S. Kim, Carbon 56, 173 (2013)

    Article  CAS  Google Scholar 

  35. Y. Fu, X. Wang, Ind. Eng. Chem. Res. 50, 7210 (2011)

    Article  CAS  Google Scholar 

  36. J. Xu, Powder Technol. 210, 1 (2011)

    Article  CAS  Google Scholar 

  37. B. Gao, P.S. Yap, T.M. Lim, T.T. Lim, Chem. Eng. J. 171, 1098 (2011)

    Article  CAS  Google Scholar 

  38. S. Sohrabnezhad, Spectrochim. Acta A81, 228 (2011)

    Article  Google Scholar 

  39. P. Liu, L. Zhang, Sep. Purif. Technol. 58, 32 (2007)

    Article  CAS  Google Scholar 

  40. G.L. Puma, A. Bono, D. Krishnaiah, J.G. Collin, J. Hazard. Mater. 157, 209 (2008)

    Article  Google Scholar 

  41. J. Shia, J. Zheng, P. Wua, X. Jib, Catal. Commun. 9, 1846 (2008)

    Article  Google Scholar 

  42. J. Matos, J. Laine, J.M. Herrmann, Carbon 37, 1870 (1999)

    Article  CAS  Google Scholar 

  43. W. Wang, J.L. Faria, C.G. Silva, Appl. Catal. B Environ. 70, 470 (2007)

    Article  CAS  Google Scholar 

  44. J. Mato, J. Laine, J.M. Herrmann, J. Catal. 200, 10 (2001)

    Article  Google Scholar 

  45. T. Liu, Y. Li, Q. Du, J. Sun, Y. Jiao, G. Yang, Z. Wang, Y. Xia, W. Zhang, K. Wang, H. Zhu, D. Wu, Colloids Surf. B 90, 197 (2012)

    Article  CAS  Google Scholar 

  46. T. Yang, A.C. Lua, Microporous Mesoporous Mater. 63, 113 (2003)

    Article  CAS  Google Scholar 

  47. M.A. Karimi, S. Haghdar Roozbahani, R. Asadiniya, A. Hatefi-Mehrjardi, M.H. Mashhadizadeh, R. Behjatmanesh Ardakani, M. Mazloum Ardakani, H. Kargar, S.M. Zebarjad, Int. Nano Lett. 1, 43 (2011)

    CAS  Google Scholar 

  48. J. Bandara, C.C. Hadapangoa, W.G. Jayasekera, Appl. Catal. B Environ. 50, 83 (2004)

    Article  CAS  Google Scholar 

  49. Y. Yamada, J. Mater. Res. 28, 431 (2013)

    Article  Google Scholar 

  50. E. Bizani, K. Fytianos, I. Poulios, V. Tsiridis, J. Hazard. Mater. 136, 85 (2006)

    Article  CAS  Google Scholar 

  51. S. Senthilkumaar, K. Porkodi, J. Colloid Interface Sci. 288, 184 (2005)

    Article  CAS  Google Scholar 

  52. M.A. Hasnat, I.A. Siddiquey, A. Nuruddin, Dyes Pigm. 66, 185 (2005)

    Article  CAS  Google Scholar 

  53. M. Zanjanchi, S. Sohrabnezhad, Sens. Actuators B 105, 502 (2005)

    Article  CAS  Google Scholar 

  54. S.K. Kansal, M. Singh, D. Sud, J. Hazard. Mater. 141, 581 (2007)

    Article  CAS  Google Scholar 

  55. C.G. Silva, W.D. Wang, J.L. Faria, J. Photochem. Photobiol. A 181, 314 (2006)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors would like to express their appreciation to Professor Afsaneh Safavi for her valuable discussion and useful suggestions. This research was supported by the Nanoscience and Nanotechnology Research Laboratory (NNRL) of Payame Noor University of Sirjan.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, 19395-4697, Tehran, Iran

    Mohammad Ali Karimi & Abdolhamid Hatefi-Mehrjardi

  2. Nanoscience and Nanotechnology Research Laboratory (NNRL), Department of Chemistry, Payame Noor University, PO Box 78185-347, Sirjan, Iran

    Mohammad Ali Karimi, Abdolhamid Hatefi-Mehrjardi, Asghar Askarpour Kabir & Mahdieh Zaydabadi

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  1. Mohammad Ali Karimi
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  2. Abdolhamid Hatefi-Mehrjardi
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  3. Asghar Askarpour Kabir
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Correspondence to Mohammad Ali Karimi or Abdolhamid Hatefi-Mehrjardi.

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Karimi, M.A., Hatefi-Mehrjardi, A., Askarpour Kabir, A. et al. Synthesis, characterization, and application of MgO/ZnO nanocomposite supported on activated carbon for photocatalytic degradation of methylene blue. Res Chem Intermed 41, 6157–6168 (2015). https://doi.org/10.1007/s11164-014-1729-z

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