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Silica-coated Fe3O4 nanoparticle@silylpropyl triethylammonium heteropoly acid as a nanomagnetic inorganic–organic hybrid catalyst for the green synthesis of xanthene derivatives under solvent-free conditions

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Abstract

A magnetic nanocatalyst, silica-coated Fe3O4 nanoparticle@silylpropyl triethylammonium heteropoly acid (Fe3O4@SiO2-TEA-HPA), was successfully prepared by modifying and reacting of silica coated iron oxide nanoparticles with triethylamine and H7PMo10Ti2O40. The novel and nanomagnetic catalyst was identified by XRD, FT-IR, VSM, TGA and FESEM techniques. The catalytic activity of Fe3O4@SiO2-TEA-HPA was evaluated in the preparation of 14-aryl-14H-dibenzo [a, j] xanthene and 9-aryl-1, 8-dioxo-octahydroxanthene derivatives under solvent free conditions with high yields. Furthermore, the catalyst could be efficiently recycled by a permanent magnet without significant loss of activity after five runs.

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Acknowledgements

We are grateful to the Islamic Azad University, Arak Branch for its laboratory supplies.

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Authors and Affiliations

  1. Department of Chemistry, Arak Branch, Islamic Azad University, Arak, Iran

    Farzaneh Moradi & Masumeh Abdoli-Senejani

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  1. Farzaneh Moradi
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  2. Masumeh Abdoli-Senejani
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Correspondence to Masumeh Abdoli-Senejani.

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Moradi, F., Abdoli-Senejani, M. Silica-coated Fe3O4 nanoparticle@silylpropyl triethylammonium heteropoly acid as a nanomagnetic inorganic–organic hybrid catalyst for the green synthesis of xanthene derivatives under solvent-free conditions. Reac Kinet Mech Cat 136, 1357–1369 (2023). https://doi.org/10.1007/s11144-023-02403-1

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