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Trihydrazinotriazine-grafting Fe3O4/SiO2 core-shell nanoparticles with expanded porous structure for organic reactions

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Abstract

This study focuses on the synthesis and characterization of a novel magnetic nanocomposite 2,4,6-trihydrazino-1,3,5-triazine (THDT)-functionalized with silica-coated iron oxide magnetic nanoparticles (MNPs). This nanocomposite has porous morphology decorated with the spherical MNPs. Through co-precipitation of iron salts, MNPs were obtained. The prepared THDT was placed on the chlorine surface-modified MNPs. The present environment-friendly nanocatalyst intensely accelerated the synthesis of highly functionalized tetrahydrobenzo[b]pyran derivatives as well as reduced the reaction times and increased yields of the products.

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Acknowledgements

This work was partially supported by the research council of the Iran University of Science and Technology. We also would like to thank Maryam Niksefat, Ehsan Morshedloo and Peyman Hanifenejad for their help in graphic drawing.

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  1. These authors contributed equally to this work.

Authors and Affiliations

  1. Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran, 16846-13114, Iran

    Jamal Rahimi, Seyedeh Shadi Mirmohammadi & Ali Maleki

Authors
  1. Jamal Rahimi
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  2. Seyedeh Shadi Mirmohammadi
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  3. Ali Maleki
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Correspondence to Ali Maleki.

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Rahimi, J., Mirmohammadi, S.S. & Maleki, A. Trihydrazinotriazine-grafting Fe3O4/SiO2 core-shell nanoparticles with expanded porous structure for organic reactions. Front. Chem. Sci. Eng. 15, 1008–1020 (2021). https://doi.org/10.1007/s11705-020-1996-8

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  • DOI: https://doi.org/10.1007/s11705-020-1996-8

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